New Polymer Electrolyte Membranes for Fuel Cells

A special issue of Batteries (ISSN 2313-0105).

Deadline for manuscript submissions: closed (31 March 2025) | Viewed by 691

Special Issue Editors


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Guest Editor
Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, China
Interests: polymer electrolyte membrane; anion exchange membrane; high-temperature proton exchange membrane fuel cell; flow battery; water electrolyser
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China
Interests: polymer electrolyte membrane; anion exchange membrane; proton exchange membrane; gas separation membrane; fuel cell; water electrolyser

Special Issue Information

Dear Colleagues,

This Special Issue focuses on the latest advancements in the field of polymer electrolyte membranes for fuel cells, highlighting their crucial role in the development of sustainable energy technologies. This issue will cover a broad range of topics related to the design, synthesis, and structure–property relationships of various types of polymer membranes, including proton exchange membranes (PEMs), anion exchange membranes (AEMs), and high-temperature proton exchange membranes (HT-PEMs). These membranes are essential for the efficient operation of fuel cells, influencing both their performance and durability. As the demand for clean energy solutions increases, the development of novel polymer electrolyte membranes with enhanced conductivity, mechanical strength, and chemical stability is of paramount importance. Contributions to this Special Issue will provide insights into the latest innovations in polymer electrolyte membranes, explore new synthetic strategies, and discuss their applications in next-generation fuel cells. By bringing together leading research in this area, this Special Issue aims to advance our understanding of the relationship between membrane properties and fuel cell performance, driving the field toward more efficient and commercially viable energy solutions.

The topics of interest include but are not limited to the following:

  • proton exchange membrane;
  • anion exchange membrane;
  • high-temperature proton exchange membrane;
  • synthesis, structure–property relationship;
  • fuel cell

Dr. Jingshuai Yang
Prof. Dr. Zhe Wang
Guest Editors

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Keywords

  • polymer electrolyte membrane
  • proton exchange membrane
  • anion exchange membrane
  • high-temperature proton exchange membrane
  • fuel cell

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Published Papers (1 paper)

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Review

27 pages, 3909 KiB  
Review
Styrene and Its Derivatives Used in Proton Exchange Membranes and Anion Exchange Membranes for Fuel Cell Applications: A Review
by Muhammad Rehman Asghar, Ayesha Zahid, Huaneng Su, Kumar Divya, Muhammad Tuoqeer Anwar and Qian Xu
Batteries 2025, 11(4), 134; https://doi.org/10.3390/batteries11040134 - 29 Mar 2025
Viewed by 435
Abstract
The proton exchange membrane (PEM) is a critical component of fuel cells, responsible for controlling the flow of protons while minimizing fuel crossover through its channels. The commercial membrane commonly used in fuel cells is made of Nafion, which is expensive and prone [...] Read more.
The proton exchange membrane (PEM) is a critical component of fuel cells, responsible for controlling the flow of protons while minimizing fuel crossover through its channels. The commercial membrane commonly used in fuel cells is made of Nafion, which is expensive and prone to swelling when in contact with water. To address these limitations, various polymers have been explored as alternatives to replace the costly Nafion membrane. Styrene, a versatile and cost-effective material, has emerged as a promising candidate. It can be modified into different forms to meet the requirements of a fuel cell membrane. The aromatic rings in styrene can copolymerize with hydrophilic functional groups, enhancing water (H2O) uptake, proton conductivity, and ion exchange capacity (IEC) of the membrane. Additionally, the hydrophobic nature of styrene helps maintain the structural integrity of the membrane’s channels, reducing excessive swelling and minimizing fuel crossover. The flexible aromatic chains in styrene facilitate the attachment of hydrophilic functional groups, such as sulfonic groups, further improving the membrane’s ion conductivity, IEC, thermal stability, mechanical strength, and oxidative stability. This review article explores the application of styrene and its derivatives in fuel cell membranes, with a focus on proton exchange membrane fuel cells (PEMFCs), direct methanol fuel cells (DMFCs), and anion exchange membrane fuel cells (AEMFCs). Full article
(This article belongs to the Special Issue New Polymer Electrolyte Membranes for Fuel Cells)
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