J. Compos. Sci., Volume 5, Issue 12 (December 2021) – 21 articles

There has been a great tendency toward using resin composite in dentistry and exploring nano-hardness, elastic modulus, and effect of polishing on its mechanical properties after its artificial ageing. This study aimed to evaluate the effect of surface polishing of four different resin composites on their nano-hardness and elastic modulus. This effect was tested right after light curing of composite resin and after its artificial ageing (immersion in alcoholic medium). Nanoindentation test preparations, surface roughness, surface hardness, and scanning electron microscope were conducted across the four different resin composites: Clearfil AP-X (APX), Estelite Sigma Quick (ESQ), Beautifil II (BE2), and FiltekTM Supreme Ultra Universal restorative (FSU). We found that difference in fillers load and particle size are amongst the factors influencing hardness and modulus of elasticity. The APX is the highest in term of hardness due to fillers load and size while the ESQ is the lowest because all fillers in nano size and distributed homogenously. The significance of surface polishing of the studied resin composite restorations was highlighted. Future research may focus on exploring survival rate of polished and non-polished composite surfaces with emphasis on measuring degree of conversion and impacts of polished and non-polished surfaces on the individuals’ oral health quality of life. Full article

Saffron extract was encapsulated into a gelatin matrix by means of electrospinning and freeze drying techniques and the degradation kinetics of bioactive compounds were evaluated during their storage at 4, 24, and 35 °C as compared to non-encapsulated control. The encapsulation efficiency, thermal properties, storage stability, morphology, and diameter distribution of the encapsulated saffron extract were evaluated as output parameters. In general, both encapsulation techniques demonstrated superior retention of bioactive compounds compared to samples without encapsulation during the entire storage period. Electrospinning and freeze drying techniques were able to retain at least 96.2 and 93.7% of crocin, respectively, after 42 days of storage at 35 °C with the 15% saffron extract. The half-life (t_1/2) time parameter for the control sample (with 15% saffron extract without encapsulation) was 22 days at 4 °C temperature, while that encapsulated by electrospinning was 138 days and that obtained for freeze drying was 77 days, The half-lives were longer at lower temperatures. The encapsulation efficiency of crocin, picrocrocin, and safranal associated with the electro-spun gelatin fibers were 76.3, 86.0, and 74.2%, respectively, and in comparison, the freeze drying encapsulation efficiencies were relatively lower, at 69.0, 74.7, and 65.8%, respectively. Electro-spun gelatin fibers also had higher melting and denaturation temperatures of 78.3 °C and 108.1 °C, respectively, as compared to 65.4 °C and 93.2 °C, respectively, for freeze-dried samples. Thus, from all respects, it was concluded that electrospinning was a better and more effective technique than freeze drying in terms of preserving saffron bioactive compounds. Full article

The additive manufacturing (AM) of carbon fiber reinforced plastic (CFRP) composites continue to grow due to the attractive strength-to-weight and modulus-to-weight ratios afforded by the composites combined with the ease of processibility achievable through the AM technique. Short fiber design factors such as fiber content effects have been shown to play determinant roles in the mechanical performance of AM fabricated CFRP composites. However, this has only been investigated for tensile and flexural properties, with no investigations to date on compressive properties effects of fiber content. This study examined the axial and transverse compressive properties of AM fabricated CFRP composites by testing CF-ABS with fiber contents from 0%, 10%, 20%, and 30% for samples printed in the axial and transverse build orientations, and for axial tensile in comparison to the axial compression properties. The results were that increasing carbon fiber content for the short-fiber thermoplastic CFRP composites slightly reduced compressive strength and modulus. However, it increased ductility and toughness. The 20% carbon fiber content provided the overall content with the most decent compressive properties for the 0–30% content studied. The AM fabricated composite demonstrates a generally higher compressive property than tensile property because of the higher plastic deformation ability which characterizes compression loaded parts, which were observed from the different failure modes. Full article

Automated Fiber Placement (AFP) machines can manufacture composite panels with curvilinear fibers. In this article, the critical buckling load of grid-stiffened curvilinear fiber composite panels is maximized using a genetic algorithm. The skin is composed of layers in which the fiber orientation varies along one spatial direction. The design variables are the fiber orientation of the panel for each layer and the stiffener layout. Manufacturing constraints in terms of maximum curvature allowable by the AFP machine are imposed for both skin and stiffener fibers. The effect of manufacturing-induced gaps in the laminates is also incorporated. The finite element method is used to perform the buckling analyses. The panels are subjected to in-plane compressive and shear loads under several boundary conditions. Optimization results show that the percentage difference in the buckling load between curvilinear and straight fiber panels depends on the load case and boundary conditions. Full article

FSP (friction stir processing) technology is a modern grain refinement method that is setting new trends in surface engineering. This technology is used not only to modify the microstructure of the surface layer of engineering materials, but increasingly more often also to produce surface composites. The application potential of FSP technology lies in its simplicity and speed of processing and in the wide range of materials that can be used as reinforcement in the composite. There are a number of solutions enabling the effective and controlled introduction of the reinforcing phase into the plasticized matrix and the production of the composite microstructure in it. The most important of them are the groove and hole methods, as well as direct friction stir processing. This review article discusses the main and less frequently used methods of producing surface composites using friction stir processing, indicates the main advantages, disadvantages and application limitations of the individual solutions, in addition to potential difficulties in effective processing. This information can be helpful in choosing a solution for a specific application. Full article

Objectives: To characterize the mechanical properties of different resin-composites for dental application. Methods: Thirteen universal dentin shade composites (n = 10) from different manufacturers were evaluated (4 Seasons, Grandio, Venus, Amelogen Plus, P90, Z350, Esthet-X, Amaris, Vita-l-escence, Natural-Look, Charisma, Z250 and Opallis). The polymerization shrinkage percentage was calculated using a video-image recording device (ACUVOL—Bisco Dental) and the hygroscopic expansion was measured after thermocycling aging in the same equipment. Equal volumes of material were used and, after 5 min of relaxation, baseline measurements were calculated with 18 J of energy delivered from the light-curing unit. Specimens were stored in a dry-dark environment for 24 h then thermocycled in distilled water (5–55 °C for 20,000 cycles) with volume measurement at each 5000 cycles. In addition, the pulse-excitatory method was applied to calculate the elastic modulus and Poisson ratio for each resin material and the degree of conversion was evaluated using Fourier transform infrared spectroscopy. Results: The ANOVA showed that all composite volumes were influenced by the number of cycles (α = 0.05). Volumes at 5 min post-polymerization (12.47 ± 0.08 cm³) were significantly lower than those at baseline (12.80 ± 0.09 cm³). With regard to the impact of aging, all resin materials showed a statistically significant increase in volume after 5000 cycles (13.04 ± 0.22 cm³). There was no statistical difference between volumes measured at the other cycle steps. The elastic modulus ranged from 22.15 to 10.06 GPa and the Poisson ratio from 0.54 to 0.22 with a significant difference between the evaluated materials (α = 0.05). The degree of conversion was higher than 60% for all evaluated resin composites. Full article

In this study, nanocomposites based on polycaprolactone (PCL) and two types of mesoporous silicas, MCM-41 and SBA-15, were attained by melt extrusion. The effect of the silica incorporated within the PCL matrix was observed, firstly, in the morphological characteristics and degradation behavior of the resultant composites. DSC experiments provided information on the existence of confinement in the PCL–SBA-15 materials through the appearance of an additional small endotherm, located at about 25–50 °C, and attributed to the melting of constrained crystallites. Displacement to a slightly lower temperature of this endothermic event was observed in the first heating run of PCL–MCM-41 composites, attributed to the inferior pore size in the MCM-41 particles. Thus, this indicates variations in the inclusion of PCL chains within these two mesostructures with different pore sizes. Real-time variable-temperature small-angle X-ray scattering (SAXS) experiments with synchrotron radiation were crucial to confirm the presence of PCL within MCM-41 and SBA-15 pores. Accurate information was also deduced from these measurements regarding the influence of these two mesoporous MCM-41 and SBA-15 silicas on PCL long spacing. The differences found in these morphological and structural features were responsible for the ultimate mechanical response exhibited by the two sets of PCL nanocomposites, with a considerably higher increase of mechanical parameters in the SBA-15 family. Full article

Despite the fact that total hip replacement is one of the most successful surgical procedures for treatment of a variety of end-stage hip diseases, the process of osteolysis and implant loosening remains a significant problem, especially in young and high-demand patients. More than 40 years ago, ceramic bearings were introduced due to their mechanical advantage in order to obtain a reduction in wear debris, and due to the conviction that it was possible to minimize friction and wear owing to their mechanical hardness, high chemical stability, surface lubrication by fluids and low friction coefficient. Together with excellent mechanical properties, ceramics have a biological inertness: eventual ceramic debris will lead to a reactive response with a high predominance of fibrocystic cells, rather than macrophagic cells, and absence of giant cells, which is ideal from a biological perspective. As a consequence, they will not trigger the granulomatous reaction necessary to induce periprosthetic osteolysis, and this clearly appears to be of great clinical relevance. In recent years, tribology in manufacturing ceramic components has progressed with significant improvements, owing to the development of the latest generation of ceramic composites that allow for an increased material density and reduced grain size. Currently, ceramic-on-ceramic bearings are considered the attractive counterparts of ceramic- or metal-on-polyethylene ones for patients with a long life expectancy. The aim of this paper is to report the results of total hip replacements performed with a ceramic-on-ceramic articulation made from a ceramic composite in a single center, focusing on its usefulness in specific preoperative diagnosis. Full article

The growing demand and diversity in the application of industrial composites and the current inability of present non-destructive evaluation (NDE) methods to perform detailed inspection of these composites has motivated this comprehensive review of sensing technologies. NDE has the potential to be a versatile tool for maintaining composite structures deployed in hazardous and inaccessible areas, such as offshore wind farms and nuclear power plants. Therefore, the future composite solutions need to take into consideration the niche requirements of these high-value/critical applications. Composite materials are intrinsically complex due to their anisotropic and non-homogeneous characteristics. This presents a significant challenge for evaluation and the associated data analysis for NDEs. For example, the quality assurance, certification of composite structures, and early detection of the failure is complex due to the variability and tolerances involved in the composite manufacturing. Adapting existing NDE methods to detect and locate the defects at multiple length scales in the complex materials represents a significant challenge, resulting in a delayed and incorrect diagnosis of the structural health. This paper presents a comprehensive review of the NDE techniques, that includes a detailed discussion of their working principles, setup, advantages, limitations, and usage level for the structural composites. A comparison between these techniques is also presented, providing an insight into the future trends for composites’ prognostic and health management (PHM). Current research trends show the emergence of the non-contact-type NDE (including digital image correlation, infrared tomography, as well as disruptive frequency-modulated continuous wave techniques) for structural composites, and the reasons for their choice over the most popular contact-type (ultrasonic, acoustic, and piezoelectric testing) NDE methods is also discussed. The analysis of this new sensing modality for composites’ is presented within the context of the state-of-the-art and projected future requirements. Full article

Understanding of the decisive role of non-isothermal treatment on the interaction mechanism and kinetics of the MoO₃-CuO-Mg-C system is highly relevant for the elaboration of optimal conditions at obtaining Mo-Cu composite powder in the combustion processes. The reduction pathway of copper and molybdenum oxides with combined Mg + C reducing agents at high heating rates from 100 to 5200 K min⁻¹ was delivered. In particular the sequence of the reactions in all the studied binary, ternary and quaternary systems contemporaneously demonstrating the effect of the heating rate on products’ phase composition and microstructure was elucidated. The combination of two highly exothermic and speedy reactions (MoO₃ + 3Mg and CuO + Mg vs. MoO₃ + CuO + 4Mg) led to a slow interaction with weak self-heating (dysynergistic effect) due to a change in the reaction mechanism. Furthermore, it has been shown that upon the simultaneous utilization of the Mg and C reducing agents, the process initiates exclusively with carbothermic reduction, and at relatively high temperatures it continues with magnesiothermic reaction. The effective activation energy values of the magnesiothermic stages of the studied reactions were determined by Kissinger isoconversional method. Full article

Biomaterials attract a lot of attention as next-generation materials. Especially in the energy field, fuel cells based on biomaterials can further develop clean next-generation energy and are focused on with great interest. In this study, solid-state hydrogen fuel (PSII–chitin composite) composed of the photosystem II (PSII) and hydrated chitin composite was successfully created. Moreover, a biofuel cell consisting of the electrolyte of chitin and the hydrogen fuel using the PSII–chitin composite was fabricated, and its characteristic feature was investigated. We found that proton conductivity in the PSII–chitin composite increases by light irradiation. This result indicates that protons generate in the PSII–chitin composite by light irradiation. It was also found that the biofuel cell using the PSII–chitin composite hydrogen fuel and the chitin electrolyte exhibits the maximum power density of 0.19 mW/cm². In addition, this biofuel cell can drive an LED lamp. These results indicate that the solid-state biofuel cell based on the bioelectrolyte “chitin” and biofuel “the PSII–chitin composite” can be realized. This novel solid-state fuel cell will be helpful to the fabrication of next-generation energy. Full article

Wood fiber reinforcement of plastics is almost limited to polypropylene, polyethylene, polyvinyl chloride and polystyrene. Wood fiber reinforcement of thermoplastic polyurethanes (TPU) is a new research field and paltry studied scientifically. Wood fiber reinforcement can carry out synergistic effects between sustainability, material or product price reduction, improved mechanical properties at high elongation, and brilliant appearance and haptics. In order to evaluate to what extent the improvement of mechanical properties depend on material-specific parameters (fiber type, fiber content) and on process-specific parameters (holding pressure, temperature control and injection speed), differently filled compounds were injection molded according to a partial factorial test plan and subjected to characterizing test procedures (tensile test, Shore hardness and notched impact test). Tensile strength showed significant dependence on barrel temperature, fiber type and interaction between holding pressure and barrel temperature in the region of interest. Young’s modulus can be influenced by fiber content but not by fiber type. Notched impact strength showed a significant influence of cylinder temperature, fiber content, fiber type and the interaction between cylinder temperature and fiber content in the region of interest. Shore hardness is related to fiber content and the interaction between mold temperature and injection flow rate. Our results show not only that wood-filled TPU can be processed very well by injection molding, but also that the mechanical properties depend significantly on temperature control in the injection-molding process. Moreover, considering the significant reinforcing effect of the wood fibers, a good fiber-matrix adhesion can be assumed. Full article

Alkali-activated binders (AABs) are developed using a dry mixing method under ambient curing incorporating powder-form reagents/activators and industrial waste-based supplementary cementitious materials (SCMs) as precursors. The effects of binary and ternary combinations/proportions of SCMs, two types of powder-form reagents, fundamental chemical ratios (SiO₂/Al₂O₃, Na₂O/SiO₂, CaO/SiO₂, and Na₂O/Al₂O₃), and incorporation of polyvinyl alcohol (PVA) fibers on fresh state and hardened characteristics of 16 AABs were investigated to assess their performance for finding suitable mix compositions. The mix composed of ternary SCM combination (25% fly-ash class C, 35% fly-ash class F, and 40% ground granulated blast furnace slag) with multi-component reagent combination (calcium hydroxide and sodium metasilicate = 1:2.5) was found to be the most optimum binder considering all properties with a 56 day compressive strength of 54 MPa. The addition of 2% v/v PVA fibers to binder compositions did not significantly impact the compressive strengths. However, it facilitated mitigating shrinkage/expansion strains through micro-confinement in both binary and ternary binders. This research bolsters the feasibility of producing ambient cured powder-based cement-free binders and fiber-reinforced, strain-hardening composites incorporating binary/ternary combinations of SCMs with desired fresh and hardened properties. Full article

Carbon-Encapsulated NiFe Nanofiber Ni_xFe_y@C-CNFs have been demonstrated to be promising candidates to replace conventional nobel metals-based catalysts for oxygen evolution reaction. Here, we developed a facile method of electrospinning and high temperature carbonization to synthesize Ni_xFe_y@C-CNFs catalysts. It is proved that Ni₃Fe₇@C-CNFs exhibited low overpotential (245 mV) and excellent stability in alkaline electrolyte for OER. This work provides a good platform for the synthesis and design of graphene-encapsulated alloy catalysts. Full article

The main objective of this study was to investigate the mechanical behavior of 3D printed fiberglass-reinforced nylon honeycomb structures. A Continuous Fiber Fabrication (CFF) 3D printer was used since it makes it possible to lay continuous strands of fibers inside the 3D printed geometries at selected locations across the width in order to optimize the bending behavior. Nylon and nylon/fiberglass honeycomb structures were tested under a three-point bending regime. The microstructure of the filaments and the 3D printed fractured surfaces following bending tests were examined with Scanning Electron Microscopy (SEM). The modulus of the materials was also evaluated using the nanoindentation technique. The behavior of the 3D printed structures was simulated with a Finite Element Model (FEM). The experimental and simulation results demonstrated that 3D printed continuous fiberglass reinforcement is possible to selectively adjust the bending strength of the honeycombs. When glass fibers are located near the top and bottom faces of honeycombs, the bending strength is maximized. Full article

The discovery of an innovative class of inorganic polymers has brought forth a revolution in the history of construction technology. Now, no energy-intensive reactions at elevated temperatures are essential, as found in the case of contemporary cement production. In addition to their attributes of low energy and a mitigated carbon footprint, geopolymeric composites can incorporate diversely originated and profound wastes in their manufacturing. As of today, profoundly accessible landfills of rubber tyre waste negatively impact the environment, water, and soil, with many health hazards. Their nonbiodegradable complex chemical structure supports recycling, and toxic gases are emitted by burning them, leading to aesthetic issues. These, altogether, create great concern for well-thought-out disposal methods. One of the achievable solutions is processing this waste into alternative aggregates to thus generate increased economic value whilst reducing primary aggregate consumption through the incorporation of these vast automobile solid wastes in the manufacturing of geopolymer construction composites, e.g., binders, mortar, concrete, etc., produced through the process of geopolymerization as a replacement for natural aggregates, providing relief to the crisis of the degradation of restricted natural aggregate resources. Currently, tyre rubber is one of the most outstanding materials, extensively employed in scores of engineering applications. This manuscript presents a state-of-the-art review of value-added applications in the context of rubberized geopolymer building composites and a review of past investigations. More significantly, this paper reviews rubberized geopolymer composites for their value-added applications. Full article

High entropy oxides are entropy-stabilised oxides that adopt specific disordered structures due to entropy stabilisation. They are a new class of materials that utilises the high-entropy concept first discovered in metallic alloys. They can have interesting properties due to the interactions at the electronic level and can be combined with other materials to make composite structures. The design of new meta-materials that utilise this concept to solve real-world problems may be a possibility but further understanding of how their phase stabilisation is required. In this work, biplots of the composition’s mean electronegativity are plotted against the electron-per-atom ratio of the compounds. The test dataset accuracy in the resulting biplots improves from 78% to 100% when using atomic-number-per-atom Z/a ratios as a biplot parameter. Phase stability maps were constructed using a Voronoi tessellation. This can be of use in determining stability at composite material interfaces. Full article

This work evaluates the effectiveness of commonly adopted local damage evolution methods and failure criteria in finite element analysis for the simulation of intralaminar damage propagation in composites under static loading conditions. The proposed numerical model is based on a User Defined Material subroutine (USERMAT) implemented in Ansys. This model is used to predict the evolution of damage within each specific lamina of a composite laminate by introducing both sudden and gradual degradation rules. The main purpose of the simulations is to quantitatively assess the influence of the adopted failure criteria in conjunction with degradation laws on the accuracy of the numerical predictions in terms of damage evolution and failure load. The mechanical behavior of an open hole tension specimen and of a notched stiffened composite panel under shear loading conditions have been numerically simulated by Progressive Damage Models (PDM). Different failure criteria have been implemented in the developed Ansys USERMAT, together with sudden and gradual degradation rules based on the Continuum Damage Mechanics (CDM) approach. Numerical results have been validated against experimental data to assess the effects of the different failure criteria and damage evolution law on the global mechanical response and local damage predictions in composite laminates. Full article

This paper deals with the design, preparation, and characterization of conductive and flexible nanopapers based on graphite nanoplates (GNP) and polydimethylsiloxane (PDMS). Highly porous GNP nanopapers were first prepared by filtration from a GNP suspension in a solvent. Subsequently, PDMS impregnation was carried out to obtain a composite material. By varying the concentration of the polymer solution and the deposition time, PDMS/GNP nanopapers were produced with a wide range of PDMS contents, porosities, and densities. Thermal diffusivity of the composite films (both in-plane and cross-plane) were measured and correlated with the structure of the nanopapers. Selected formulations were investigated in detail for their physical, thermal, and mechanical properties, exhibiting high flexibility and resistance to more than 50 repeated bendings, stiffness of up to 1.3 MPa, and thermal conductivity of up to 25 W/m∙K. Based on the properties obtained, the materials presented in this paper may find applications in modern lightweight and flexible electronic devices. Full article

Bismuth based quaternary glasses with compositions BiBLM: 50Bi₂O₃–20B₂O₃–15Li₂O–15MO (where MO = ZnO, CdO, BaO, and PbO) were processed by conventional melt quenching. The effectiveness of various modifier oxides on the optical and structural properties of the developed glasses was studied systematically by XRD, DSC, FTIR, Raman, and optical absorption (OA) measurements. The synthesized glass specimens were characterized by XRD and the patterns demonstrated an amorphous nature. The physical characteristics such as molar mass, density, and OPD values were found to increase with an increase in the molar mass of the modifier oxides, while there was a decrement in oxygen molar volume, thus resulting in decrement of complete molar volume of the prepared glasses. From DSC analysis, incorrigible reduction and enhancement of T_g and thermal stability among various modifier oxides in the glass network was noticed. Optical absorption data for glass specimens have confirmed the decrease in both direct and indirect optical band gap values among various modifier oxides incorporation. These investigations support the obtained Urbach energy (UE) and metallization criteria of synthesized glasses. The ionic characteristic for the glass specimens were confirmed by the values of electronic polarizability and electronegativity. The Raman and FT-IR spectra of the glass specimens displayed the existence of BiO₃, BiO₆, ZnO₄, CdO₄, BaO₄, BO₃, PbO₄, and BO₄ structural units within the glass matrix. These structural results can support the applications of as-developed glasses in the area of photonics. Full article

A new fabrication process without preform manufacturing has been developed for carbon short fiber (CSF) reinforced various aluminum matrix composites. And their mechanical and thermal properties were evaluated. Electroless Ni plating was conducted on the CSF for improving wettability between the carbon fiber (CF) and aluminum. It was confirmed that pores in Ni plated CSF/Al and Al alloy matrix composites prepared by applied pressure, 0.8 MPa, had some imperfect infiltration regions between the CF/CF and CF/matrix in all composites. However, pores size in the region between the CF/CF and CF/matrix to use the A336 matrix was about 1 µm. This size is smaller than that of other aluminum-based composites. Vickers hardness of Ni plated CSF/A1070, A356 alloy, and A336 alloy composites were higher as compared to matrix. However, the A1070 pure aluminum matrix composite had the highest hardness improvement. The Ultimate tensile strength of the A1070 and A356 aluminum matrix composite was increased due to carbon fiber compared to only aluminum, but the Ultimate tensile strength of the A336 aluminum matrix composite was rather lowered due to the highest content of Si precipitate and large size of Al₃Ni compounds. The Thermal Conductivity of Ni plated CSF/A1070 composite has the highest value (167.1 W·m⁻¹·K⁻¹) as compared to composites. Full article