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Condensed Matter, Volume 4, Issue 1

2019 March - 34 articles

Cover Story: Realizing reversible reduction–oxidation (redox) reactions of lattice oxygen in batteries is a promising way to improve their energy and power density. While conventional oxygen absorption spectroscopy fails to distinguish the critical oxygen chemistry in oxide-based battery electrodes, high-efficiency full-range mapping of resonant inelastic X-ray scattering (mRIXS) has been developed as a reliable probe of oxygen redox reactions. Here, we provide a comprehensive analysis and an explicit interpretation of the five evolving components of O-K mRIXS of the typical battery electrode that involves lattice oxygen redox reaction upon cycling. This work is the first benchmark for a complete assignment of all the important mRIXS features collected from battery materials, and thus delivers guidelines for future studies on the characterization, analysis, and theoretical calculation for probing and understanding oxygen redox reactions. View this pape

Articles (34)

  • Article
  • Open Access
7 Citations
3,586 Views
16 Pages

It has been recently shown that fast oscillating control fields can be used to speed up an otherwise slow adiabatic process, making the system always follow an instantaneous eigenvector closely. In applying this method though, one typically assumes p...

  • Communication
  • Open Access
6 Citations
3,115 Views
7 Pages

In this short communication, we report a new carbon material prepared from meta-linked polyaniline that exhibits weak antiferromagnetic interactions at low temperature. The synthesis of poly(meta-aniline), abbreviated as m-PANI, was conducted using t...

  • Review
  • Open Access
17 Citations
3,789 Views
13 Pages

Out-of-equilibrium phenomena are attracting high interest in physics, materials science, chemistry and life sciences. In this state, the study of structural fluctuations at different length scales in time and space are necessary to achieve significan...

  • Article
  • Open Access
22 Citations
3,794 Views
8 Pages

Energy Response of Silicon Drift Detectors for Kaonic Atom Precision Measurements

  • Marco Miliucci,
  • Mihail Iliescu,
  • Aidin Amirkhani,
  • Massimiliano Bazzi,
  • Catalina Curceanu,
  • Carlo Fiorini,
  • Alessandro Scordo,
  • Florin Sirghi and
  • Johann Zmeskal

Novel, large-area silicon drift detectors (SDDs) have been developed to perform precision measurements of kaonic atom X-ray spectroscopy, for the study the K ¯ N strong interaction in the low-energy regime. These devices have special geom...

  • Article
  • Open Access
15 Citations
5,470 Views
19 Pages

The Potential of EuPRAXIA@SPARC_LAB for Radiation Based Techniques

  • Antonella Balerna,
  • Samanta Bartocci,
  • Giovanni Batignani,
  • Alessandro Cianchi,
  • Enrica Chiadroni,
  • Marcello Coreno,
  • Antonio Cricenti,
  • Sultan Dabagov,
  • Andrea Di Cicco and
  • Fabio Villa
  • + 25 authors

A proposal for building a Free Electron Laser, EuPRAXIA@SPARC_LAB, at the Laboratori Nazionali di Frascati, is at present under consideration. This FEL facility will provide a unique combination of a high brightness GeV-range electron beam generated...

  • Article
  • Open Access
8 Citations
7,820 Views
17 Pages

Impact of Surface Roughness on Ion-Surface Interactions Studied with Energetic Carbon Ions 13C+ on Tungsten Surfaces

  • Maren Hellwig,
  • Martin Köppen,
  • Albert Hiller,
  • Hans Rudolf Koslowski,
  • Andrey Litnovsky,
  • Klaus Schmid,
  • Christian Schwab and
  • Roger A. De Souza

The effect of surface roughness on angular distributions of reflected and physically sputtered particles is investigated by ultra-high vacuum (UHV) ion-surface interaction experiments. For this purpose, a smooth (Ra = 5.9 nm) and a rough (Ra = 20.5 n...

  • Article
  • Open Access
8 Citations
6,457 Views
22 Pages

Electronic Structure of Boron Flat Holeless Sheet

  • Levan Chkhartishvili,
  • Ivane Murusidze and
  • Rick Becker

The electronic band structure, namely energy band surfaces and densities-of-states (DoS), of a hypothetical flat and ideally perfect, i.e., without any type of holes, boron sheet with a triangular network is calculated within a quasi-classical approa...

  • Article
  • Open Access
6 Citations
3,886 Views
7 Pages

Experimental Observation of Temperature-Driven Topological Phase Transition in HgTe/CdHgTe Quantum Wells

  • Maksim S. Zholudev,
  • Aleksandr M. Kadykov,
  • Mikhail A. Fadeev,
  • Michal Marcinkiewicz,
  • Sandra Ruffenach,
  • Christophe Consejo,
  • Wojciech Knap,
  • Jeremie Torres,
  • Sergey V. Morozov and
  • Frederic Teppe
  • + 3 authors

We report on the comparison between temperature-dependent magneto-absorption and magnetotransport spectroscopy of HgTe/CdHgTe quantum wells in terms of the detection of the phase transition between the topological insulator and band insulator states....

  • Article
  • Open Access
1 Citations
3,824 Views
5 Pages

Model of Nano-Metal Electroplating Process in Trapezoid Profile Groove

  • Oksana Yu. Egorova,
  • Victor G. Kosushkin and
  • Leo V. Kozhitov

The principle of the electrodeposition method is to immerse the coated products in a water electrolyte solution, the main components of which are salts or other soluble compounds—metal coatings. The software COMSOL Multiphysics was allowed to p...

  • Article
  • Open Access
2 Citations
4,359 Views
10 Pages

Engineering Topological Nodal Line Semimetals in Rashba Spin-Orbit Coupled Atomic Chains

  • Paola Gentile,
  • Vittorio Benvenuto,
  • Carmine Ortix,
  • Canio Noce and
  • Mario Cuoco

In this paper, we study an atomic chain in the presence of modulated charge potential and modulated Rashba spin-orbit coupling (RSOC) of equal periods. We show that for commensurate periodicities, λ = 4 n with integer n, the three-dime...

  • Article
  • Open Access
14 Citations
5,013 Views
13 Pages

Scintillator Pixel Detectors for Measurement of Compton Scattering

  • Mihael Makek,
  • Damir Bosnar and
  • Luka Pavelić

The Compton scattering of gamma rays is commonly detected using two detector layers, the first for detection of the recoil electron and the second for the scattered gamma. We have assembled detector modules consisting of scintillation pixels, which a...

  • Article
  • Open Access
5 Citations
5,319 Views
6 Pages

Temperature Effects on the HOPG Intercalation Process

  • Gianlorenzo Bussetti,
  • Rossella Yivlialin,
  • Claudio Goletti,
  • Maurizio Zani and
  • Lamberto Duò

Graphite intercalation via chemical strategies is a common procedure to delaminate stratified crystals and obtain a suspension of graphene flakes. The intercalation mechanism at the molecular level is still under investigation in view of enhancing gr...

  • Review
  • Open Access
1 Citations
3,358 Views
22 Pages

We present a summary of some recent theoretical results for matter-wave patterns in Fermi and Bose–Fermi degenerate gases, obtained in the framework of the quasi-mean-field approximation. We perform a dimensional reduction from the three-dimens...

  • Article
  • Open Access
15 Citations
7,071 Views
7 Pages

Effect of High-Temperature Annealing on Graphene with Nickel Contacts

  • Tommi Kaplas,
  • Vytautas Jakstas,
  • Andrius Biciunas,
  • Algimantas Luksa,
  • Arunas Setkus,
  • Gediminas Niaura and
  • Irmantas Kasalynas

Graphene has shown great potential for ultra-high frequency electronics. However, using graphene in electronic devices creates a requirement for electrodes with low contact resistance. Thermal annealing is sometimes used to improve the performance of...

  • Article
  • Open Access
7 Citations
3,749 Views
11 Pages

We derive the two-dimensional equation of state for a bosonic system of ultracold atoms interacting with a finite-range effective interaction. Within a functional integration approach, we employ a hydrodynamic parameterization of the bosonic field to...

  • Brief Report
  • Open Access
1 Citations
3,313 Views
3 Pages

Simulation of the Process of Obtaining Nanoparticles by Thermal Decomposition

  • Anastasiya Kuzmicheva,
  • Victor Kosushkin and
  • Leo Kozhitov

In this work, the possibility of modeling the process of thermal decomposition in the COMSOL Multiphysics program for the preparation of nanoparticles of metals and their alloys was determined. To identify the most suitable pyrolysis medium, two envi...

  • Article
  • Open Access
18 Citations
6,345 Views
11 Pages

Graphite Optics—Current Opportunities, Properties and Limits

  • Inna Grigorieva,
  • Alexander Antonov and
  • Gennadi Gudi

X-ray graphite optics consists of thin layers of Pyrolytic Graphite (PG) attached to a substrate of focusing shape. Pyrolytic Graphite is a perfect artificial graphite obtained by annealing of carbon deposit at temperatures about 3000 °C under de...

  • Article
  • Open Access
2 Citations
3,808 Views
8 Pages

Crystallization is a generic phenomenon in classical and quantum mechanics arising in a variety of physical systems. In this work, we focus on a specific platform, ultracold dipolar bosons, which can be realized in experiments with dilute gases. We r...

  • Article
  • Open Access
9 Citations
3,982 Views
17 Pages

There is growing compelling experimental evidence that a quantum complex matter scenario made of multiple electronic components and competing quantum phases is needed to grab the key physics of high critical temperature (Tc) superconductivity in laye...

  • Article
  • Open Access
7 Citations
4,469 Views
8 Pages

X-Ray Absorption Spectroscopy Measurements of Cu-ProIAPP Complexes at Physiological Concentrations

  • Emiliano De Santis,
  • Emma Shardlow,
  • Francesco Stellato,
  • Olivier Proux,
  • Giancarlo Rossi,
  • Christopher Exley and
  • Silvia Morante

The amyloidogenic islet amyloid polypeptide (IAPP) and the associated pro-peptide ProIAPP1–48 are involved in cell death in type 2 diabetes mellitus. It has been observed that interactions of this peptide with metal ions have an impact on the c...

  • Article
  • Open Access
3 Citations
4,330 Views
9 Pages

A Novel Bulk-Optics Scheme for Quantum Walk with High Phase Stability

  • Andrea Geraldi,
  • Luís Diego Bonavena,
  • Carlo Liorni,
  • Paolo Mataloni and
  • Álvaro Cuevas

A novel bulk optics scheme for quantum walks is presented. It consists of a one-dimensional lattice built on two concatenated displaced Sagnac interferometers that make it possible to reproduce all the possible trajectories of an optical quantum walk...

  • Article
  • Open Access
17 Citations
4,343 Views
7 Pages

The New Beamline LISA at ESRF: Performances and Perspectives for Earth and Environmental Sciences

  • Alessandro Puri,
  • Giovanni Orazio Lepore and
  • Francesco d’Acapito

LISA (Linea Italiana per la Spettroscopia di Assorbimento di raggi X) is the new Italian Collaborating Research Group (CRG) beamline at the European Synchrotron Radiation Facility (ESRF) dedicated to X-ray absorption spectroscopy (XAS). The beamline...

  • Article
  • Open Access
5 Citations
3,899 Views
11 Pages

Impact of Lattice Vibrations on the Dynamics of a Spinor Atom-Optics Kicked Rotor

  • Caspar Groiseau,
  • Alexander Wagner,
  • Gil S. Summy and
  • Sandro Wimberger

We investigate the effect of amplitude and phase noise on the dynamics of a discrete-time quantum walk and its related evolution. Our findings underline the robustness of the motion with respect to these noise sources, and can explain the stability o...

  • Article
  • Open Access
10 Citations
4,730 Views
8 Pages

A partial substitution such as Ce in SmCo 5 could be a brilliant way to improve the magnetic performance, because it will introduce strain in the structure and breaks the lattice symmetry in a way that enhances the contribution of the Co atom...

  • Article
  • Open Access
8 Citations
5,221 Views
9 Pages

Proximity-Induced Superconducting States of Magnetically Doped 3D Topological Insulators with High Bulk Insulation

  • Rikizo Yano,
  • Hishiro T. Hirose,
  • Kohei Tsumura,
  • Shuhei Yamamoto,
  • Masao Koyanagi,
  • Manabu Kanou,
  • Hiromi Kashiwaya,
  • Takao Sasagawa and
  • Satoshi Kashiwaya

We studied magnetized topological insulator/superconductor junctions with the expectation of unconventional superconductive states holding Majorana fermions induced by superconductive proximity effects on the surface states of magnetized topological...

  • Article
  • Open Access
6 Citations
5,070 Views
12 Pages

X-ray Absorption Fine Structure Spectroscopy (XAFS) is a powerful technique to investigate the local atomic geometry and the chemical state of atoms in different types of materials, especially if lacking a long-range order, such as nanomaterials, liq...

  • Article
  • Open Access
11 Citations
4,661 Views
17 Pages

Polarization Analysis in Mössbauer Reflectometry with Synchrotron Mössbauer Source

  • Marina Andreeva,
  • Roman Baulin,
  • Aleksandr Chumakov,
  • Tatiyana Kiseleva and
  • Rudolf Rüffer

Polarization selection of the reflected radiation has been employed in Mössbauer reflectivity measurements with a synchrotron Mössbauer source (SMS). The polarization of resonantly scattered radiation differs from the polarization of an inc...

  • Article
  • Open Access
43 Citations
6,852 Views
11 Pages

Improved Single-Crystal Growth of Sr2RuO4

  • Jake S. Bobowski,
  • Naoki Kikugawa,
  • Takuto Miyoshi,
  • Haruki Suwa,
  • Han-shu Xu,
  • Shingo Yonezawa,
  • Dmitry A. Sokolov,
  • Andrew P. Mackenzie and
  • Yoshiteru Maeno

High-quality single crystals are essentially needed for the investigation of the novel bulk properties of unconventional superconductors. The availability of such crystals grown by the floating-zone method has helped to unveil the unconventional supe...

  • Article
  • Open Access
62 Citations
9,675 Views
12 Pages

Fingerprint Oxygen Redox Reactions in Batteries through High-Efficiency Mapping of Resonant Inelastic X-ray Scattering

  • Jinpeng Wu,
  • Qinghao Li,
  • Shawn Sallis,
  • Zengqing Zhuo,
  • William E. Gent,
  • William C. Chueh,
  • Shishen Yan,
  • Yi-de Chuang and
  • Wanli Yang

Realizing reversible reduction-oxidation (redox) reactions of lattice oxygen in batteries is a promising way to improve the energy and power density. However, conventional oxygen absorption spectroscopy fails to distinguish the critical oxygen chemis...

  • Article
  • Open Access
14 Citations
5,596 Views
8 Pages

Substrate-Induced Proximity Effect in Superconducting Niobium Nanofilms

  • S.J. Rezvani,
  • Andrea Perali,
  • Matteo Fretto,
  • Natascia De Leo,
  • Luca Flammia,
  • Milorad Milošević,
  • Stefano Nannarone and
  • Nicola Pinto

Structural and superconducting properties of high-quality niobium nanofilms with different thicknesses are investigated on silicon oxide (SiO2) and sapphire substrates. The role played by the different substrates and the superconducting properties of...

  • Article
  • Open Access
12 Citations
3,585 Views
11 Pages

Geometric Effects of a Quarter of Corrugated Torus

  • Run Cheng,
  • Yong-Long Wang,
  • Hua Jiang,
  • Xiao-Jun Liu and
  • Hong-Shi Zong

In the spirit of the thin-layer quantization scheme, we give the effective Shrödinger equation for a particle confined to a corrugated torus, in which the geometric potential is substantially changed by corrugation. We find the attractive wells...

  • Article
  • Open Access
4 Citations
4,212 Views
13 Pages

Tuning Nanoscale Friction by Applying Weak Magnetic Fields to Reorient Adsorbed Oxygen Molecules

  • Z. B. Fredricks,
  • K. M. Stevens,
  • S. G. Kenny,
  • B. Acharya and
  • J. Krim

Sliding friction levels of thin (1–2 monolayers) and thick (~10 monolayers) oxygen films adsorbed on nickel and gold at 47.5 K have been measured by means of a quartz crystal microbalance (QCM) technique. Friction levels for the thin (thick) fi...

  • Review
  • Open Access
94 Citations
13,498 Views
20 Pages

Nematic superconductivity is a novel class of superconductivity characterized by spontaneous rotational-symmetry breaking in the superconducting gap amplitude and/or Cooper-pair spins with respect to the underlying lattice symmetry. Doped Bi 2 ...

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Condens. Matter - ISSN 2410-3896