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Gels, Volume 4, Issue 2

2018 June - 31 articles

Cover Story: The simulated fiber network gel formed by the dispersion of semi-flexible polymers that have a lateral attractive interaction. Simulation evidence suggests that the regularity in the fiber diameter in this type of self-assembled fiber gel network is controlled by an interplay between the twisting of the chains within the bundle, which creates more contacts between the chains and rigidification upon chain bundling, which increases the energetic cost of bundling. View the paper here.
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Articles (31)

  • Article
  • Open Access
19 Citations
6,308 Views
9 Pages

19 June 2018

Nanogold is widely used in many areas of physics and chemistry due to its environment-sensitive plasmon resonance absorption. The immobilization of gold nanoparticles in highly porous silica aerogel offers an attractive alternative to liquid gold sol...

  • Review
  • Open Access
178 Citations
16,366 Views
37 Pages

Functional Stimuli-Responsive Gels: Hydrogels and Microgels

  • Coro Echeverria,
  • Susete N. Fernandes,
  • Maria H. Godinho,
  • João Paulo Borges and
  • Paula I. P. Soares

12 June 2018

One strategy that has gained much attention in the last decades is the understanding and further mimicking of structures and behaviours found in nature, as inspiration to develop materials with additional functionalities. This review presents recent...

  • Feature Paper
  • Article
  • Open Access
12 Citations
6,762 Views
13 Pages

Propagation of Fatigue Cracks in Friction of Brittle Hydrogels

  • Tetsuo Yamaguchi,
  • Ryuichiro Sato and
  • Yoshinori Sawae

8 June 2018

In order to understand fatigue crack propagation behavior in the friction of brittle hydrogels, we conducted reciprocating friction experiments between a hemi-cylindrical indenter and an agarose hydrogel block. We found that the fatigue life is great...

  • Review
  • Open Access
44 Citations
6,149 Views
13 Pages

30 May 2018

The development of biomaterials for the restoration of the normal tissue structure–function relationship in pathological conditions as well as acute and chronic injury is an area of intense investigation. More recently, the use of tailored or c...

  • Review
  • Open Access
40 Citations
9,201 Views
34 Pages

30 May 2018

Owing to their multifarious applicability, studies of molecular and supramolecular gelators and their corresponding gels have gained momentum, particularly in the last two decades. Hydrophobic–hydrophilic balance, different solvent parameters, gelato...

  • Feature Paper
  • Article
  • Open Access
73 Citations
10,258 Views
12 Pages

25 May 2018

The structure and mechanical properties of model polymer networks consisting of alternating tetra-functional poly(ethylene glycol)s (PEGs) and bis-functional linear PEGs were investigated by dynamic light scattering and rheological measurements. The...

  • Communication
  • Open Access
14 Citations
4,796 Views
8 Pages

Effect of Sonication Time on Magnetorheological Effect for Monomodal Magnetic Elastomers

  • Mayuko Watanabe,
  • Junko Ikeda,
  • Yoshihiro Takeda,
  • Mika Kawai and
  • Tetsu Mitsumata

23 May 2018

The effect of sonication time on the storage modulus and particle morphology for magnetic elastomers was investigated by dynamic viscoelastic measurements and morphological studies. An ultrasonic wave using a homogenizer was irradiated to magnetic li...

  • Feature Paper
  • Review
  • Open Access
106 Citations
16,384 Views
30 Pages

Recent Developments in Tough Hydrogels for Biomedical Applications

  • Yuan Liu,
  • Weilue He,
  • Zhongtian Zhang and
  • Bruce P. Lee

22 May 2018

A hydrogel is a three-dimensional polymer network with high water content and has been attractive for many biomedical applications due to its excellent biocompatibility. However, classic hydrogels are mechanically weak and unsuitable for most physiol...

  • Review
  • Open Access
121 Citations
13,134 Views
15 Pages

22 May 2018

Polysaccharide hydrogels have been increasingly utilized in various fields. In this review, we focus on polysaccharide-based hydrogels used as probiotic delivery systems. Probiotics are microorganisms with a positive influence on our health that live...

  • Article
  • Open Access
28 Citations
7,969 Views
15 Pages

Ultrashort Self-Assembling Peptide Hydrogel for the Treatment of Fungal Infections

  • Alyaa A. Albadr,
  • Sophie M. Coulter,
  • Simon L. Porter,
  • Raghu Raj Singh Thakur and
  • Garry Laverty

22 May 2018

The threat of antimicrobial resistance to society is compounded by a relative lack of new clinically effective licensed therapies reaching patients over the past three decades. This has been particularly problematic within antifungal drug development...

  • Article
  • Open Access
10 Citations
4,999 Views
9 Pages

21 May 2018

We report the swelling properties of chemically crosslinked poly(vinyl alcohol) (PVA) gels with high degrees of polymerization and hydrolysis. Physical crosslinking by microcrystallites was introduced in this chemical PVA gel by a simple dehydration...

  • Article
  • Open Access
3 Citations
5,396 Views
12 Pages

Frozen State of Sephadex® Gels of Different Crosslink Density Analyzed by X-ray Computed Tomography and X-ray Diffraction

  • Norio Murase,
  • Yuki Uetake,
  • Yuki Sato,
  • Kentaro Irie,
  • Yohei Ueno,
  • Toru Hirauchi,
  • Toshio Kawahara and
  • Mitsuhiro Hirai

18 May 2018

Water in Sephadex® (crosslinked dextran) gels is known to indicate different freezing behavior which is dependent on the density of the crosslinks, and water in a Sephadex® G25 gel remains partially unfrozen during cooling and crystallizes du...

  • Article
  • Open Access
84 Citations
12,983 Views
13 Pages

Advanced Recycled Polyethylene Terephthalate Aerogels from Plastic Waste for Acoustic and Thermal Insulation Applications

  • Hong Wei Koh,
  • Duyen K. Le,
  • Gek Nian Ng,
  • Xiwen Zhang,
  • Nhan Phan-Thien,
  • Umeyr Kureemun and
  • Hai M. Duong

17 May 2018

This work presents for the first time, a simple, practical and scalable approach to fabricating recycled polyethylene terephthalate (rPET) aerogels for thermal and acoustic insulation applications. The rPET aerogels were successfully developed from r...

  • Article
  • Open Access
14 Citations
5,827 Views
15 Pages

Antibacterial Properties of Silver Nanoparticles Embedded on Polyelectrolyte Hydrogels Based on α-Amino Acid Residues

  • Mario Casolaro,
  • Ilaria Casolaro,
  • Jun Akimoto,
  • Motoki Ueda,
  • Masashi Ueki and
  • Yoshihiro Ito

4 May 2018

Polyelectrolyte hydrogels bearing l-phenylalanine (PHE), l-valine (AVA), and l-histidine (Hist) residues were used as scaffolds for the formation of silver nanoparticles by reduction of Ag+ ions with NaBH4. The interaction with the metal ion allowed...

  • Review
  • Open Access
73 Citations
12,470 Views
33 Pages

Beyond Covalent Crosslinks: Applications of Supramolecular Gels

  • Ty Christoff-Tempesta,
  • Andrew J. Lew and
  • Julia H. Ortony

3 May 2018

Traditionally, gels have been defined by their covalently cross-linked polymer networks. Supramolecular gels challenge this framework by relying on non-covalent interactions for self-organization into hierarchical structures. This class of materials...

  • Article
  • Open Access
9 Citations
5,539 Views
13 Pages

Emergence of Wrinkles during the Curing of Coatings

  • Michiko Shimokawa,
  • Hikaru Yoshida,
  • Takumi Komatsu,
  • Rena Omachi and
  • Kazue Kudo

3 May 2018

Wrinkles often emerge on a paint layer when a second coat of paint is applied on an already-coated substrate. Wrinkle formation occurs when the first layer absorbs organic solvent from the second layer. We set up experiments to mimic the double-coati...

  • Article
  • Open Access
37 Citations
9,269 Views
15 Pages

Physical Properties of the Extracellular Matrix of Decellularized Porcine Liver

  • Hiroyuki Ijima,
  • Shintaro Nakamura,
  • Ronald Bual,
  • Nana Shirakigawa and
  • Shuichi Tanoue

1 May 2018

The decellularization of organs has attracted attention as a new functional methodology for regenerative medicine based on tissue engineering. In previous work we developed an L-ECM (Extracellular Matrix) as a substrate-solubilized decellularized liv...

  • Review
  • Open Access
37 Citations
8,341 Views
11 Pages

Microfluidic Spun Alginate Hydrogel Microfibers and Their Application in Tissue Engineering

  • Tao Sun,
  • Xingfu Li,
  • Qing Shi,
  • Huaping Wang,
  • Qiang Huang and
  • Toshio Fukuda

23 April 2018

Tissue engineering is focusing on processing tissue micro-structures for a variety of applications in cell biology and the “bottom-up” construction of artificial tissue. Over the last decade, microfluidic devices have provided novel tools...

  • Article
  • Open Access
11 Citations
5,364 Views
9 Pages

20 April 2018

Electrostatic interactions in charged microgels, which are dominated by the microgel net charge, play a crucial role in colloidal stabilization and loading of small, charged molecules. In this study, the temperature dependences of electrophoretic mob...

  • Article
  • Open Access
22 Citations
6,511 Views
14 Pages

Process Variable Optimization in the Manufacture of Resorcinol–Formaldehyde Gel Materials

  • Martin Prostredný,
  • Mohammed G. M. Abduljalil,
  • Paul A. Mulheran and
  • Ashleigh J. Fletcher

17 April 2018

Influence of process parameters of resorcinol–formaldehyde xerogel manufacture on final gel structure was studied, including solids content, preparation/drying temperature, solvent exchange, and drying method. Xerogels produced using a range of...

  • Article
  • Open Access
1 Citations
4,847 Views
15 Pages

Non-Steroidal Biphenyl Gelators: Correlation of Xerogel Structure with Solid-State Structure and Circular Dichroism Spectroscopy

  • H. Cristina Geiger,
  • David K. Geiger,
  • William R. Roberts,
  • Dominic L. Morell,
  • Paul Huttunen,
  • Jennifer L. Schulman,
  • Melanie Tran and
  • Dori Farthing

16 April 2018

Because the factors favoring the formation of well-formed single crystals are dissimilar to those conducive to gel formation, few examples of single-crystal structural characterizations of organogelators are found in the literature. A series of biphe...

  • Review
  • Open Access
9 Citations
5,564 Views
14 Pages

16 April 2018

In recent years, the synthesis of novel organic molecules that spontaneously self-assemble into a large variety of molecular architecture, particularly the formation of organogels, has yielded new opportunities in the preparation of functional materi...

  • Article
  • Open Access
42 Citations
8,343 Views
10 Pages

9 April 2018

A series of low density, highly porous clay/poly(vinyl alcohol) composite aerogels, incorporating ammonium alginate, were fabricated via a convenient and eco-friendly freeze drying method. It is significant to understand rheological properties of pre...

  • Article
  • Open Access
13 Citations
5,433 Views
8 Pages

Effect of Gamma Ray Irradiation on Friction Property of Poly(vinyl alcohol) Cast-Drying on Freeze-Thawed Hybrid Gel

  • Saori Sasaki,
  • Seiji Omata,
  • Teruo Murakami,
  • Naotsugu Nagasawa,
  • Mitsumasa Taguchi and
  • Atsushi Suzuki

29 March 2018

Poly(vinyl alcohol) (PVA) is a biocompatible polymer with low toxicity. It is possible to prepare physically cross-linked PVA gels having hydrogen bonds without using a cross-linking agent. The newly reported physically cross-linked PVA cast-drying (...

  • Article
  • Open Access
17 Citations
6,346 Views
17 Pages

29 March 2018

The impact of chirality on the self-assembly of supramolecular gels is of considerable importance, as molecular-scale programming can be translated into nanostructuring and ultimately affect macroscopic performance. This paper explores the effect of...

  • Review
  • Open Access
15 Citations
6,312 Views
11 Pages

28 March 2018

Microgels—small gels of submicron to micron size—are widely used in food, cosmetics and biomedical applications because of their biocompatibility and/or fast response to external environments. However, the properties of “single” microgels have not be...

  • Article
  • Open Access
22 Citations
7,199 Views
15 Pages

Temperature-Responsive Hydrogel-Coated Gold Nanoshells

  • Hye Hun Park,
  • La-ongnuan Srisombat,
  • Andrew C. Jamison,
  • Tingting Liu,
  • Maria D. Marquez,
  • Hansoo Park,
  • Sungbae Lee,
  • Tai-Chou Lee and
  • T. Randall Lee

26 March 2018

Gold nanoshells (~160 nm in diameter) were encapsulated within a shell of temperature-responsive poly(N-isopropylacrylamide-co-acrylic acid) (P(NIPAM-co-AA)) using a surface-bound rationally-designed free radical initiator in water for the developmen...

  • Article
  • Open Access
23 Citations
4,937 Views
11 Pages

22 March 2018

The formation of gels through the bundling of semi-flexible polymer chains into fiber networks is ubiquitous in diverse manufactured and natural materials, and, accordingly, we perform exploratory molecular dynamics simulations of a coarse-grained mo...

  • Concept Paper
  • Open Access
30 Citations
4,539 Views
9 Pages

22 March 2018

By design, no references are included in this article. It is intended to be a series of recommendations in which the focus is on lab practices for investigating substances rather than on the substances being investigated. Thus, it discusses some spec...

  • Article
  • Open Access
6 Citations
6,046 Views
13 Pages

Dynamics of Spinodal Decomposition in a Ternary Gelling System

  • Yutaro Yamashita,
  • Miho Yanagisawa and
  • Masayuki Tokita

22 March 2018

The phase diagram and phase transitions of the ternary system of gelatin, water and poly(ethylene glycol) oligomers were studied as a function of the weight fraction of gelatin and the weight fraction and molecular weight of poly(ethylene glycol) oli...

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Gels - ISSN 2310-2861