Inorganics, Volume 5, Issue 3 (September 2017) – 22 articles
Cover Story (view full-size image): Spin crossover (SCO) materials reversibly switch spin states in response to external stimuli, leading to potential applications in future molecular electronic devices. Here, we show that the magnetic properties of a cationic SCO-active complex can be altered by a crystal engineering approach, where polyoxometalates (POMs) are employed as the anions. The cover picture shows how the the crystal structure and physical properties of the hybrid systems can be altered by the nature of the POM counteraction. By Hiroki Oshio. View the paper.
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