You are currently viewing a new version of our website. To view the old version click .

Inorganics, Volume 10, Issue 7

July 2022 - 17 articles

Cover Story: A mono-nuclear “two wall” aryl-extended caxli[4]pyrrole receptor decorated with an acetylide–gold(I)–PTA complex at its upper rim is synthesized. The binding properties of the unprecedented receptor and their synthetic precursors (R= I and ethynyl) towards chloride are studied in dichloromethane and acetone. The calculated ESP values at the centers of the aromatic ring and at the para‐substituent (R) of the differently substituted aromatic walls were not enough to explain the dissimilar free energies of binding of the 1:1 chloride complexes exclusively in terms of repulsive anion–π interactions. The calix[4]pyrrole acetylide gold(I) receptor binds chloride exclusively in the cone conformation, and the presence of free chloride in solution induces the formation of a gold(I)–anionic calix[4]pyrrole dimer. View this paper
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
  • You may sign up for email alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.

Articles (17)

  • Article
  • Open Access
4 Citations
3,098 Views
12 Pages

Purification and Characterization of High Purity Nano Zirconia by Liquid-Liquid Extraction Using D2EHPA/p-Xylenes

  • Manh Nhuong Chu,
  • Mai Xuan Truong,
  • Thi Hien Lan Nguyen,
  • Tra Huong Do,
  • Thi Tu Anh Duong,
  • Thi Kim Ngan Tran,
  • Thi Cam Quyen Ngo,
  • Thi To Loan Nguyen,
  • Thi Hau Vu and
  • Mai An Pham

In this paper, Zr(IV) nitrate solution decomposed from Viet Nam zircon concentrate was the source of zirconium extraction by liquid-liquid extraction (L.L.E). The FT-IR and UV-Vis spectra confirmed the extraction of Zr(IV) by D2EHPA/p-xylenes. There...

  • Article
  • Open Access
2 Citations
3,268 Views
14 Pages

Electrochemical Redox In-Situ Welding of Silver Nanowire Films with High Transparency and Conductivity

  • Wang Zhang,
  • Jiashuan Bao,
  • Chenhui Xu,
  • Pengfeng Zhu,
  • Xiangliang Pan and
  • Rui Li

Silver nanowire (AgNW) networks with high transparency and conductivity are crucial to developing transparent conductive films (TCFs) for flexible optoelectronic devices. However, AgNW-based TCFs still suffer from the high contact resistance of AgNW...

  • Communication
  • Open Access
2 Citations
3,410 Views
8 Pages

Magnetocaloric Effect of Two Gd-Based Frameworks

  • Bo-Liang Liu,
  • Qiao-Fei Xu,
  • La-Sheng Long and
  • Lan-Sun Zheng

Magnetic refrigeration material is the key to adiabatic demagnetization refrigeration technology. In this work, two magnetic refrigerants, Gd5(C4O4)(HCOO)3(CO3)2(OH)6·2.5H2O (1) and Gd2(OH)4SO4 (2), were prepared through hydrothermal reaction....

  • Article
  • Open Access
4 Citations
2,366 Views
17 Pages

To develop the structural and functional modeling chemistry of [NiFe]-H2ases, we have carried out a study regarding the synthesis, structural characterization and reactivity of a new series of [NiFe]-H2ase model complexes. Thus, treatment of diphosph...

  • Article
  • Open Access
11 Citations
3,145 Views
14 Pages

Enhanced Photocatalytic Degradation of Rhodamine-B under Led Light Using CuZnAl Hydrotalcite Synthesized by Co-Precipitation Technique

  • Van Nhuong Vu,
  • Thi Ha Thanh Pham,
  • Maiboun Chanthavong,
  • Tra Huong Do,
  • Thi Hien Lan Nguyen,
  • Quoc Dung Nguyen and
  • Thi Kim Ngan Tran

The co-precipitation method was employed to synthesize a set of ZnAl hydrotalcite materials modified by Cu2+. The synthesized materials have a similar lamellar structure to that of hydrotalcite. The distance between layers is in the range of 7.73&nda...

  • Review
  • Open Access
10 Citations
4,497 Views
18 Pages

Due to its highly conjugated panel-like structure and unique photophysical and chemical features, anthracene has been widely used for fabricating attractive and functional supramolecular assemblies, including two-dimensional metallacycles and three-d...

  • Article
  • Open Access
15 Citations
3,261 Views
14 Pages

Hierarchically ordered porous silica materials (HSMs) with a micro/mesoporous structure were successfully prepared with the sol-gel method using dextran, dextran/CTAB, and CTAB as templates. The obtained hierarchically structured silica was successfu...

of 2

Get Alerted

Add your email address to receive forthcoming issues of this journal.

XFacebookLinkedIn
Inorganics - ISSN 2304-6740