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Inorganics, Volume 10, Issue 3

2022 March - 14 articles

Cover Story: Introduction: Iron–sulfur clusters (Fe–S or ISC) are essential inorganic cofactors that are required for a number of biological pathways. In mammals, the synthesis of Fe–S relies on mitochondrial function and a group of evolutionarily conserved mitochondrial proteins constituting the ISC pathway. The first step of the ISC pathway requires the de novo assembly of Fe–S within a dynamic core complex. Here, we review recent data on the function and association of different Fe–S core complex components and provide a model of the Fe–S assembly. We also briefly describe the genetic diseases that result from mutations in the Fe–S core complex components, including Friedreich’s ataxia. View this paper
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Articles (14)

  • Review
  • Open Access
23 Citations
6,183 Views
20 Pages

In recent years, a great interest has arisen around the integration of naturally occurring clays into a plethora of advanced technological applications, quite far from the typical fabrication of traditional ceramics. This “second (technological...

  • Article
  • Open Access
8 Citations
6,634 Views
21 Pages

Improved Electrochemical Behavior and Thermal Stability of Li and Mn-Rich Cathode Materials Modified by Lithium Sulfate Surface Treatment

  • Hadar Sclar,
  • Sandipan Maiti,
  • Rosy Sharma,
  • Evan M. Erickson,
  • Judith Grinblat,
  • Ravikumar Raman,
  • Michael Talianker,
  • Malachi Noked,
  • Aleksandr Kondrakov and
  • Doron Aurbach
  • + 1 author

High-energy cathode materials that are Li- and Mn-rich lithiated oxides—for instance, 0.35Li2MnO3.0.65LiNi0.35Mn0.45Co0.20O2 (HE-NCM)—are promising for advanced lithium-ion batteries. However, HE-NCM cathodes suffer from severe degradatio...

  • Project Report
  • Open Access
22 Citations
6,845 Views
12 Pages

The design and use of new potent and specific antimicrobial systems are of crucial importance in the medical field. This will help relieve, fight, and eradicate infections and thus improve human health. The use of metals in various forms as antimicro...

  • Article
  • Open Access
5 Citations
3,969 Views
24 Pages

Binuclear Heteroleptic Ru(III) Dithiocarbamate Complexes: A Step towards Tunable Antiproliferative Agents

  • Andrea E. Gallio,
  • Leonardo Brustolin,
  • Nicolò Pettenuzzo and
  • Dolores Fregona

Binuclear dithiocarbamate complexes of Ru(III) are promising candidates in the search for outstanding metal-based anticancer agents. While different dithiocarbamates have shown ligand-dependent cytotoxicity in homoleptic binuclear Ru(III) complexes,...

  • Article
  • Open Access
4 Citations
6,271 Views
17 Pages

It was recently reported that a (2-hydroxybenzyl)phosphine oxide (2-HOBPO) can serve as a phosphorus-centered catalyst for the stereo-invertive coupling of aliphatic alcohols and acidic pronucleophiles (akin to a Mitsunobu reaction, but without addit...

  • Article
  • Open Access
5 Citations
2,953 Views
9 Pages

Carbon-based nanocomposites have been attracting extensive attention as high-performance catalysts in alkaline media towards the electrochemical reduction of oxygen. Herein, polyacrylonitrile nanoflowers are synthesized via a free-radical polymerizat...

  • Article
  • Open Access
8 Citations
3,189 Views
18 Pages

Bimetallic Copper-Silver Systems Supported on Natural Clinoptilolite: Long-Term Changes in Nanospecies’ Composition and Stability

  • Inocente Rodríguez-Iznaga,
  • Vitalii Petranovskii,
  • Fernando Chávez-Rivas and
  • Marina G. Shelyapina

Long-term changes in species of copper-silver bimetallic systems on natural clinoptilolite obtained by ion exchange of Cu2+ and Ag+ and then reduced at different temperatures were studied. Even after storage under ambient conditions, XRD and UV-Vis d...

  • Article
  • Open Access
13 Citations
5,080 Views
12 Pages

Low-Temperature and Additive-Free Synthesis of Spherical MIL-101(Cr) with Enhanced Dye Adsorption Performance

  • Tian Zhao,
  • Hexin Zhu,
  • Ming Dong,
  • Minmin Zou,
  • Songfan Tang,
  • Mingliang Luo and
  • Xianggang Li

The chromium-benzenedicarboxylate metal–organic framework (MOF), MIL-101(Cr), is one of the most well-investigated and widely used prototypical MOFs. Regarding its synthesis, the use of a toxic modulator (usually HF) and high reaction temperatu...

  • Article
  • Open Access
12 Citations
3,993 Views
12 Pages

One-Dimensional Gadolinium (III) Complexes Based on Alpha- and Beta-Amino Acids Exhibiting Field-Induced Slow Relaxation of Magnetization

  • Marta Orts-Arroyo,
  • Adrián Sanchis-Perucho,
  • Nicolas Moliner,
  • Isabel Castro,
  • Francesc Lloret and
  • José Martínez-Lillo

Gadolinium (III) complexes exhibiting slow relaxation of magnetization are uncommon and have been much less studied than other compounds based on anisotropic lanthanide (III) ions. We prepared two one-dimensional gadolinium (III) complexes based on &...

  • Review
  • Open Access
6 Citations
7,595 Views
18 Pages

26 February 2022

Iron–sulfur clusters (Fe–S or ISC) are essential cofactors that function in a wide range of biological pathways. In mammalian cells, Fe–S biosynthesis primarily relies on mitochondria and involves a concerted group of evolutionary-c...

  • Article
  • Open Access
12 Citations
4,013 Views
13 Pages

25 February 2022

The burning of fossil fuels to meet energy demands has increased carbon dioxide (CO2) in the atmosphere, causing global warming and associated climate change. Therefore, new materials are being developed to capture CO2 effectively, limit its impact o...

  • Article
  • Open Access
17 Citations
4,695 Views
14 Pages

A High-Performing Nanostructured Ir Doped-TiO2 for Efficient Photocatalytic Degradation of Gaseous Toluene

  • Van Thi Thanh Ho,
  • Dung Hung Chau,
  • Khang Quang Bui,
  • Ngan Thi Thanh Nguyen,
  • Thi Kim Ngan Tran,
  • Long Giang Bach and
  • Son Nguyen Truong

25 February 2022

TiO2-based photocatalysts still have some limitations such as large bandgap and low surface area, leading to low efficiency in the photocatalytic degradation of VOCs and limiting it to use in sunlight. Here we report that the nanostructured Ir-doped...

  • Article
  • Open Access
3,824 Views
10 Pages

Trigonal Bipyramidal Rhodium(I) Methyl and Phenyl Complexes: Precursors of Oxidative Methyl and Phenyl Radical Generation

  • Urs Fischbach,
  • Matthias Vogt,
  • Peter Coburger,
  • Monica Trincado and
  • Hansjörg Grützmacher

24 February 2022

The new complexes [Rh(Me)(trop3P)] (2) and [Rh(Ph)(trop3P)] (3) (trop = 5H-dibenzo[a,d]cyclohepten-5-yl) were synthesised by addition of organolithium reagents (MeLi and PhLi) to the parent pentacoordinated chloride complex [RhCl(trop3P)]. The compou...

  • Article
  • Open Access
38 Citations
4,055 Views
10 Pages

Synthesis of MOFs for RhB Adsorption from Wastewater

  • Qinhui Ren,
  • Meng Nie,
  • Lili Yang,
  • Fuhua Wei,
  • Bo Ding,
  • Hongliang Chen,
  • Zhengjun Liu and
  • Zhao Liang

24 February 2022

Fe-MOFs were prepared using a solvothermal method, and were characterized by scanning electron microscopy. We explored the application of Fe-MOFs as an adsorbing material for the removal of Rhodamine B (RhB) from aqueous solutions. The experimental d...

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Inorganics - ISSN 2304-6740