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Coatings

Coatings is an international, peer-reviewed, open access journal on coatings and surface engineering, published monthly online by MDPI.
The Korean Tribology Society (KTS) and Chinese Society of Micro-Nano Technology (CSMNT) are affiliated with Coatings and their members receive discounts on the article processing charges.
Quartile Ranking JCR - Q2 (Physics, Applied)

All Articles (11,866)

Research Progress on Transparent Conductive Properties of SnO2 Thin Films

  • Xuezhi Li,
  • Fuyueyang Tan and
  • Chi Zhang
  • + 10 authors

As a core candidate material for indium-free transparent conductive oxides, tin dioxide (SnO2) thin films are gradually replacing indium tin oxide (ITO) and becoming a research focus in the field of optoelectronic devices, thanks to their excellent physicochemical stability, wide bandgap characteristics, and abundant tin resource reserves. This review focuses on SnO2 thin films. Firstly, it elaborates on the tetragonal rutile crystal structure characteristics of SnO2 and the transparent conductive mechanism based on oxygen vacancies and doping elements to regulate free electron concentration, while clarifying the key parameters for evaluating their transparent conductive properties. Subsequently, it systematically summarizes the research progress in preparing SnO2 transparent conductive thin films via physical methods and chemical methods in recent years. It compares the microstructure and transparent conductive properties of thin films prepared by different methods, and analyzes the regulatory laws of preparation processes, doping types, and film thickness on their optoelectronic properties. Furthermore, this work supplements the current application status of SnO2 thin films in devices. Meanwhile, the core performance differences between indium-free tin-based thin film devices and ITO-based devices are compared. Finally, we have summarized the advantages and challenges of physical and chemical methods in the preparation of SnO2 thin films. It also forecasts the application potential of interdisciplinary integration of physical–chemical methods and the development of new doping systems in the preparation of high-performance SnO2 transparent conductive thin films. This review aims to provide theoretical guidance and technical references for the selection and process optimization of SnO2 transparent conductive thin films in fields such as photovoltaic devices and flexible optoelectronic equipment.

24 December 2025

The unit cell of the SnO2 crystal structure. The large red circles represent oxygen atoms, and the small blue circles represent tin atoms.

The efficiencies of additive manufacturing (AM) over conventional processes have enabled the rapid production of aluminum (Al) alloys with AM. Because laser beam powder bed fusion (LB-PBF) parts do not offer the surface quality and geometrical accuracy for direct use, the functional surfaces of LB-PBF parts are usually machined by subtractive machining. The machinability of LB-PBF AlSi10Mg was studied in dry, MQL (used corn oil), and cryo-LN2 cutting environments across distinct speed–feed combinations using CVD-AlTiN-coated carbide inserts, and surface integrity and tool life were quantified in terms of surface roughness (Ra) and flank wear (Vb), respectively. The lowest Ra (0.98–1.107 μm) was obtained with cryo-LN2, followed by MQL and dry cutting environments, because the trends observed were consistent with the surface mechanisms observed in 3D topography and bearing curves. Similarly, the tool wear results mirrored the Ra results, lowest with LN2 (0.087–0.110 mm), due to improved thermal management, reduced adhesion and abrasion, and shorter contact length. Cryo-LN2 provided the best surface finish and tool life among all tested environments. To enable data-driven prediction, the limited dataset was augmented using SMOTE, and machine learning (ML) models were trained to predict Ra and Vb. CatBoost was found to yield the best Ra predictions (R2 = 0.9090), while Random Forest and XGBoost yielded the best Vb predictions (R2 ≈ 0.878).

24 December 2025

Schematic representation of investigation flow.

This article proposes a novel transparent conductive film structure to solve the problem of electrostatic accumulation in traditional nanoimprint lithography processes. This structure is formed by spin-coating a layer of silver nanowire (AgNWs) transparent conductive films on a graphic substrate, followed by coating a layer of polydimethylsiloxane (PDMS) on the surface of the film. After the PDMS is cured, it is peeled off from the substrate to form a free-standing elastic three-dimensional structured surface. These transparent conductive films are not only designed to mitigate static electricity generated during the nanoimprint lithography process, but also have excellent UV transparency, with a 325 nm UV transmittance of up to 90%. At the same time, it exhibits good conductivity with a sheet resistance of 20 Ω/sq. In addition, the films have excellent elasticity and can maintain stable conductivity during repeated stretching, providing a novel solution for flexible optoelectronic devices and nanoimprint technology.

24 December 2025

Schematic illustration of the fabrication process for AgNWs/PDMS composite films.

The fabrication of undoped and aluminium-doped zinc oxide thin films on quartz glass substrates through the aqueous spray method is reported. The prepared aqueous precursor solutions containing Zn2+ and varying mole percentages (0, 2, 4, and 8%) of Al3+ complexes were spray-coated onto quartz glass substrates preheated at 180 °C. The as-sprayed films obtained were then heat-treated at 450 °C for 30 min in a furnace to produce the various thin films. The structural and optical properties of the resultant thin films were analysed using the X-ray diffractometer (XRD) and ultraviolet–visible (UV-Vis) spectrophotometer. The XRD results revealed that the fabricated thin films have a prominent peak correlating to the (002) Miller index, which is the preferred orientation of the zinc oxide hexagonal wurtzite phase. The fabricated thin films with a film thickness of approximately 189 nm absorb light in the visible region and have a transmittance of over 80% even after being doped with aluminium. The photocatalytic activities of the thin films were evaluated via visible light irradiation of an aqueous methyl orange solution, and the Al-doped ZnO thin films exhibited good photocatalytic activities, which resulted in an increase in the doping mole percentages of aluminium.

24 December 2025

FT-IR transmittance spectra of oxalic acid, ammonium oxalate, and the synthesised ammonium aluminium oxalate.

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Coatings - ISSN 2079-6412