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Polymers, Volume 13, Issue 9

2021 May-1 - 185 articles

Cover Story: In 2D correlation spectra, it was demonstrated that the phase transition mechanisms of P(NiPAAm-co-AAc) hydrogel at pH 2 and 4 during the heating and cooling processes are completely different. This clearly indicates that the phase transition of P(NiPAAm-co-AAc) hydrogel is an irreversible process. View this paper.
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Articles (185)

  • Article
  • Open Access
6 Citations
3,851 Views
14 Pages

Tailored Adhesion Properties of Acrylate Adhesives on Al Alloys by the Addition of Mn-Al–LDH

  • Natasa Z. Tomić,
  • Mohamed Nasr Saleh,
  • Marija M. Vuksanović,
  • Adela Egelja,
  • Vera Obradović,
  • Aleksandar Marinković and
  • Radmila Jančić Heinemann

10 May 2021

The goal of this study was to investigate the effect of the structure of Mn-Al layered double hydroxide (LDH) on the adhesion behavior of composite adhesives on two Al alloys (L3005 and L8079). The composite adhesives were made out of the UV-curing B...

  • Article
  • Open Access
10 Citations
4,786 Views
18 Pages

10 May 2021

We synthesized a biodegradable, elastomeric, and functionalizable polyurethane (PU) that can be electrospun for use as a scaffold in soft tissue engineering. The PU was synthesized from polycaprolactone diol, hexamethylene diisocyanate, and dimethylo...

  • Article
  • Open Access
28 Citations
9,605 Views
28 Pages

Dual Graded Lattice Structures: Generation Framework and Mechanical Properties Characterization

  • Khaled G. Mostafa,
  • Guilherme A. Momesso,
  • Xiuhui Li,
  • David S. Nobes and
  • Ahmed J. Qureshi

10 May 2021

Additive manufacturing (AM) enables the production of complex structured parts with tailored properties. Instead of manufacturing parts as fully solid, they can be infilled with lattice structures to optimize mechanical, thermal, and other functional...

  • Article
  • Open Access
18 Citations
5,497 Views
22 Pages

Fabrication and Characterization of Chitosan—Tamarind Seed Polysaccharide Composite Film for Transdermal Delivery of Protein/Peptide

  • Rishabha Malviya,
  • Anchal Tyagi,
  • Shivkanya Fuloria,
  • Vetriselvan Subramaniyan,
  • Kathiresan Sathasivam,
  • Sonali Sundram,
  • Sundram Karupiah,
  • Srikumar Chakravarthi,
  • Dhanalekshmi Unnikrishnan Meenakshi and
  • Neeraj Kumar Fuloria
  • + 3 authors

10 May 2021

Transdermal drug delivery is used to deliver a drug by eliminating the first-pass metabolism, which increases the bioavailability of the drug. The present study aims to formulate the chitosan—tamarind seed polysaccharide composite films and evaluate...

  • Review
  • Open Access
42 Citations
8,470 Views
38 Pages

Bonded CFRP/Steel Systems, Remedies of Bond Degradation and Behaviour of CFRP Repaired Steel: An Overview

  • Daniel Borrie,
  • Saad Al-Saadi,
  • Xiao-Ling Zhao,
  • R. K. Singh Raman and
  • Yu Bai

10 May 2021

This literature review has examined the use of FRP composite materials as a potential retrofitting technique for civil structures. Importantly, the various material properties, bond mechanisms, durability issues and fatigue resistance have been discu...

  • Article
  • Open Access
9 Citations
3,647 Views
12 Pages

Synergistic Antibacterial Effect of Casein-AgNPs Combined with Tigecycline against Acinetobacter baumannii

  • Yu-Hsuan Chen,
  • Wei-Hsun Wang,
  • Sheng-Hui Lin,
  • Yuan-Ting Yang-Wang,
  • Sung-Pin Tseng,
  • Chi-Sheng Chien and
  • Chi-Jen Shih

10 May 2021

Acinetobacter baumannii (A. baumannii) is a common and challenging pathogen of nosocomial infections, due to its ability to survive on inanimate objects, desiccation tolerance, and resistance to disinfectants. In this study, we investigated an antiba...

  • Article
  • Open Access
66 Citations
7,087 Views
18 Pages

Kenaf Fiber/Pet Yarn Reinforced Epoxy Hybrid Polymer Composites: Morphological, Tensile, and Flammability Properties

  • M. J. Suriani,
  • Hasliana Asyikin Zainudin,
  • R. A. Ilyas,
  • Michal Petrů,
  • S. M. Sapuan,
  • C. M. Ruzaidi and
  • Rohani Mustapha

10 May 2021

The application of natural fibers is rapidly growing in many sectors, such as construction, automobile, and furniture. Kenaf fiber (KF) is a natural fiber that is in demand owing to its eco-friendly and renewable nature. Nowadays, there are various n...

  • Review
  • Open Access
54 Citations
11,809 Views
26 Pages

UV-Curable Bio-Based Polymers Derived from Industrial Pulp and Paper Processes

  • Lorenzo Pezzana,
  • Eva Malmström,
  • Mats Johansson and
  • Marco Sangermano

10 May 2021

Bio-based monomers represent the future market for polymer chemistry, since the political economics of different states promote green ventures toward more sustainable materials and processes. Industrial pulp and paper processing represent a large mar...

  • Article
  • Open Access
21 Citations
4,695 Views
13 Pages

Engineering of Optimized Hydrogel Formulations for Cartilage Repair

  • Yao Fu,
  • Bram Zoetebier,
  • Sanne Both,
  • Pieter J. Dijkstra and
  • Marcel Karperien

10 May 2021

The ideal scaffold for cartilage regeneration is expected to provide adequate mechanical strength, controlled degradability, adhesion, and integration with the surrounding native tissue. As it does this, it mimics natural ECMs functions, which allow...

  • Review
  • Open Access
32 Citations
8,002 Views
33 Pages

9 May 2021

The barrier performance of organic coatings is a direct function of mass transport and long-term stability of the polymeric structure. A predictive assessment of the protective coating cannot be conducted a priori of degradation effects on transport....

  • Article
  • Open Access
29 Citations
4,984 Views
11 Pages

9 May 2021

Herein, Sb2Se3 and β-Cu2Se nanowires are synthesized via hydrothermal reaction and water evaporation-induced self-assembly methods, respectively. The successful syntheses and morphologies of the Sb2Se3 and β-Cu2Se nanowires are confirmed via X-ray po...

  • Article
  • Open Access
7 Citations
3,419 Views
20 Pages

9 May 2021

The aim of this work is to improve the heat-treated wood coating performance using experimental design methodology and air–plasma treatment. Firstly, two different heat treatment processes were applied to the wood samples. In the second stage of the...

  • Article
  • Open Access
6 Citations
3,758 Views
13 Pages

9 May 2021

It has been recently reported that, in a rat calvarial defect model, adding endothelial cells (ECs) to a culture of bone marrow stromal cells (BMSCs) significantly enhanced bone formation. The aim of this study is to further investigate the ossificat...

  • Article
  • Open Access
12 Citations
4,615 Views
14 Pages

Synergistic Antimicrobial Activities of Thai Household Essential Oils in Chitosan Film

  • Juthamas Tantala,
  • Pornchai Rachtanapun and
  • Chitsiri Rachtanapun

9 May 2021

Foodborne pathogens mostly contaminate ready-to-eat (RTE) meat products by post-process contamination and cause foodborne disease outbreaks. Preventing post-process contamination and controlling microbial growth during storage by packing the RTE meat...

  • Review
  • Open Access
41 Citations
5,316 Views
19 Pages

9 May 2021

Antimicrobial materials produced by 3D Printing technology are very beneficial, especially for biomedical applications. Antimicrobial surfaces specifically with enhanced antibacterial property have been prepared using several quaternary salt-based ag...

  • Article
  • Open Access
9 Citations
3,973 Views
20 Pages

9 May 2021

We investigate structural and dynamical properties of Janus nanodimers (NDs) dispersed in lamellar phases of a diblock copolymer. By performing molecular dynamics simulations, we show that an accurate tuning of the interactions between NDs and copoly...

  • Article
  • Open Access
29 Citations
4,462 Views
21 Pages

Synthesis of a New Phosphonate-Based Sorbent and Characterization of Its Interactions with Lanthanum (III) and Terbium (III)

  • Yuezhou Wei,
  • Khalid A. M. Salih,
  • Mohammed F. Hamza,
  • Toyohisa Fujita,
  • Enrique Rodríguez-Castellón and
  • Eric Guibal

8 May 2021

High-tech applications require increasing amounts of rare earth elements (REE). Their recovery from low-grade minerals and their recycling from secondary sources (as waste materials) are of critical importance. There is increasing attention paid to t...

  • Article
  • Open Access
23 Citations
3,937 Views
12 Pages

Development and Evaluation of Rifampicin Loaded Alginate–Gelatin Biocomposite Microfibers

  • Ameya Sharma,
  • Vivek Puri,
  • Pradeep Kumar,
  • Inderbir Singh and
  • Kampanart Huanbutta

8 May 2021

Various systematic phases such as inflammation, tissue proliferation, and phases of remodeling characterize the process of wound healing. The natural matrix system is suggested to maintain and escalate these phases, and for that, microfibers were fab...

  • Article
  • Open Access
17 Citations
4,367 Views
17 Pages

8 May 2021

Polymeric prodrugs, synthesized by conjugating chemotherapeutic agents to functional polymers, have been extensively investigated and employed for safer and more efficacious cancer therapy. By rational design, a pH and reduction dual-sensitive dextra...

  • Article
  • Open Access
17 Citations
3,426 Views
14 Pages

8 May 2021

We investigated the interfacial properties of symmetric ternary An/AmBm/Bn and An/Am/2BmAm/2/Bn polymeric blends by means of dissipative particle dynamics (DPD) simulations. We systematically analyzed the effects of composition, chain length, and con...

  • Article
  • Open Access
20 Citations
3,666 Views
12 Pages

Effect of Organic Modifier Types on the Physical–Mechanical Properties and Overall Migration of Post-Consumer Polypropylene/Clay Nanocomposites for Food Packaging

  • Eliezer Velásquez,
  • Sebastián Espinoza,
  • Ximena Valenzuela,
  • Luan Garrido,
  • María José Galotto,
  • Abel Guarda and
  • Carol López de Dicastillo

7 May 2021

The deterioration of the physical–mechanical properties and loss of the chemical safety of plastics after consumption are topics of concern for food packaging applications. Incorporating nanoclays is an alternative to improve the performance of recyc...

  • Article
  • Open Access
12 Citations
3,477 Views
22 Pages

7 May 2021

Composite films based on conducting polymers and carbon nanomaterials have attracted much attention for applications in various devices, such as chemical sensors, light-emitting diodes (LEDs), organic solar cells (OSCs), among others. Graphene oxide...

  • Article
  • Open Access
7 Citations
3,503 Views
10 Pages

Focused Patterning of Electrospun Nanofibers Using a Dielectric Guide Structure

  • Byeongjun Lee,
  • Younghyeon Song,
  • Chan Park,
  • Jungmin Kim,
  • Jeongbeom Kang,
  • Haran Lee,
  • Jongwon Yoon and
  • Seongjin Cho

7 May 2021

The patterning of electrospun fibers is a key technology applicable to various fields. This study reports a novel focused patterning method for electrospun nanofibers that uses a cylindrical dielectric guide. The finite elements method (FEM) was used...

  • Article
  • Open Access
31 Citations
5,017 Views
19 Pages

Films Based on Mater-Bi® Compatibilized with Pine Resin Derivatives: Optical, Barrier, and Disintegration Properties

  • Miguel Aldas,
  • Cristina Pavon,
  • José Miguel Ferri,
  • Marina Patricia Arrieta and
  • Juan López-Martínez

7 May 2021

Mater-Bi® NF866 (MB) was blended with gum rosin and two pentaerythritol esters of gum rosin (labeled as LF and UT), as additives, to produce biobased and compostable films for food packaging or agricultural mulch films. The films were prepared by ble...

  • Article
  • Open Access
14 Citations
5,142 Views
17 Pages

Effect of Deterpenated Origanum majorana L. Essential Oil on the Physicochemical and Biological Properties of Chitosan/β-Chitin Nanofibers Nanocomposite Films

  • Rut Fernández-Marín,
  • Muhammad Mujtaba,
  • Demet Cansaran-Duman,
  • Ghada Ben Salha,
  • Mª Ángeles Andrés Sánchez,
  • Jalel Labidi and
  • Susana C. M. Fernandes

7 May 2021

Herein, the effect of three deterpenated fractions from Origanum majorana L. essential oil on the physicochemical, mechanical and biological properties of chitosan/β-chitin nanofibers-based nanocomposite films were investigated. In general, the incor...

  • Article
  • Open Access
6 Citations
4,675 Views
22 Pages

Production of Cyclic Anhydride-Modified Starches

  • Ryan C. Amos,
  • Julien Mesnager,
  • Michael Kuska and
  • Mario Gauthier

7 May 2021

Modified starches offer a biodegradable, readily available, and cost-effective alternative to petroleum-based products. The reaction of alkenylsuccinic anhydrides (ASAs), in particular, is an efficient method to produce amphiphilic starches with nume...

  • Article
  • Open Access
28 Citations
3,794 Views
18 Pages

On the Structural Performance of Recycled Aggregate Concrete Columns with Glass Fiber-Reinforced Composite Bars and Hoops

  • Ali Raza,
  • Ahmad Rashedi,
  • Umer Rafique,
  • Nazia Hossain,
  • Banjo Akinyemi and
  • Jesuarockiam Naveen

7 May 2021

Structural members comprising geopolymer recycled aggregate concrete (RAC) reinforced with glass fiber-reinforced polymer (GFRP) bars have not been investigated appropriately for axial compressive loading cases. The present study addresses this knowl...

  • Article
  • Open Access
18 Citations
5,825 Views
11 Pages

7 May 2021

The rheometer curing curves of neat natural rubber (NR) and neat chloroprene rubber (CR) with maleide F (MF) exhibit considerable crosslinking torque at 180 °C. This indicates that MF can crosslink both these rubbers via Alder-ene reactions. Based on...

  • Article
  • Open Access
7 Citations
3,142 Views
15 Pages

Synthesis and Characterization of Block Copolymers of Poly(silylene diethynylbenzen) and Poly(silylene dipropargyl aryl ether)

  • Man Gao,
  • Chengyuan Shang,
  • Jixian Li,
  • Gang Han,
  • Junkun Tang,
  • Qiaolong Yuan and
  • Farong Huang

7 May 2021

Poly(silylene diethynylbenzene)–b–poly(silylene dipropargyloxy diphenyl propane) copolymer (ABA-A), poly(silylene diethynylbenzene)–b–poly(silylene dipropargyloxy diphenyl ether) copolymer (ABA-O), and a contrast poly(silylene diethynylbenzene) with...

  • Article
  • Open Access
9 Citations
3,451 Views
12 Pages

Influence of the Presence of Choline Chloride on the Classical Mechanism of “Gelatinization” of Starch

  • Doina Crucean,
  • Bruno Pontoire,
  • Gervaise Debucquet,
  • Alain Le-Bail and
  • Patricia Le-Bail

7 May 2021

The aim of this research is to contribute to a better understanding the destructuration of three native starches and a wheat flour in mixtures of water and choline chloride. Model systems have thus been defined to allow a better approach to hydrother...

  • Article
  • Open Access
12 Citations
3,269 Views
15 Pages

7 May 2021

Recently, a new generation of polymerised ionic liquids with high thermal stability and good mechanical performances has been designed through novel and versatile cycloaliphatic epoxy-functionalised ionic liquids (CEILs). From these first promising r...

  • Article
  • Open Access
20 Citations
4,276 Views
17 Pages

6 May 2021

Dopamine (DA) is an important neurotransmitter which indicates the risk of several neurological diseases. The selective determination with low detection limit is necessary for early diagnosis and prevention of neurological diseases associated with ab...

  • Article
  • Open Access
32 Citations
6,296 Views
15 Pages

Hydrophobically-Modified PEG Hydrogels with Controllable Hydrophilic/Hydrophobic Balance

  • Fabio Bignotti,
  • Francesco Baldi,
  • Mario Grassi,
  • Michela Abrami and
  • Gloria Spagnoli

6 May 2021

This work reports on a novel method to synthesize hydrophobically-modified hydrogels by curing epoxy monomers with amines. The resulting networks contain hydrophilic poly(ethylene glycol) (PEG) segments, poly(propylene glycol) (PPG) segments, and C18...

  • Article
  • Open Access
43 Citations
6,172 Views
17 Pages

Effects of SiO2 and ZnO Nanoparticles on Epoxy Coatings and Its Performance Investigation Using Thermal and Nanoindentation Technique

  • Mohammad Asif Alam,
  • Ubair Abdus Samad,
  • Arfat Anis,
  • Manawwer Alam,
  • Mohd Ubaidullah and
  • Saeed M. Al-Zahrani

6 May 2021

Synergistic formulations were developed with nano-pigments, and their effects on the mechanical properties on steel substrates and structures were evaluated. This paper provides a complete analysis of the epoxy coating, focusing on the incorporation...

  • Article
  • Open Access
15 Citations
3,760 Views
17 Pages

6 May 2021

The increasing use of functional aramids in a wide array of applications and the inert nature of aramids against conventional dye and print methods requires developing new dyeing methods. This study aims to use environmentally friendly method with a...

  • Article
  • Open Access
28 Citations
3,067 Views
18 Pages

Efficient Addition of Waste Glass in MK-Based Geopolymers: Microstructure, Antibacterial and Cytotoxicity Investigation

  • Giovanni Dal Poggetto,
  • Michelina Catauro,
  • Giuseppina Crescente and
  • Cristina Leonelli

6 May 2021

Reuse of waste glass can significantly decrease the quantity of waste to be treated or disposed of in landfills, allowing to both diminish the ecological damage and to reduce the costs of transportation for removal. Geopolymer mixes with diverse perc...

  • Article
  • Open Access
11 Citations
3,164 Views
17 Pages

6 May 2021

The application of microwave heating facilitated efficient two-step liquefaction of acetone-soluble lignin obtained from saccharification residue of Miscanthus sacchariflorus (silvergrass), which was prepared by enzymatic hydrolysis, to produce biopo...

  • Article
  • Open Access
30 Citations
5,197 Views
19 Pages

6 May 2021

Poly(ethylene-co-octene) (POE) elastomers with different copolymer compositions and molecular weight exhibit quite distinctive foaming behaviors and dimensional stability using supercritical carbon dioxide (CO2) as a blowing agent. As the octene cont...

  • Article
  • Open Access
17 Citations
4,387 Views
17 Pages

6 May 2021

On an industrial scale, it is a challenge to achieve cellulose based nanocomposites due to dispersion issues and high process temperatures sensitivity. The current study describes methods to develop mechanically strong and thermally stable polyamide...

  • Article
  • Open Access
18 Citations
4,419 Views
20 Pages

Poly (Lactic Acid)/Ground Tire Rubber Blends Using Peroxide Vulcanization

  • Nicolas Candau,
  • Oguzhan Oguz,
  • Noel León Albiter,
  • Gero Förster and
  • Maria Lluïsa Maspoch

6 May 2021

Poly (Lactic Acid) (PLA)/Ground Tire Rubber (GTR) blends using Dicumyl peroxide (DCP) as a crosslinking agent were prepared with the following aims: propose a new route to recycle wastes rubber from the automotive industry and improve the toughness a...

  • Article
  • Open Access
11 Citations
2,607 Views
10 Pages

Compressive Fatigue Behavior of Gum and Filled SBR Vulcanizates

  • Liu Yang,
  • Lin Wang,
  • Huaiqing Guo and
  • Aihua Du

6 May 2021

The influence of carbon black on physical mechanical properties, compressive fatigue life, and the temperature changes during compression fatigue process of styrene-butadiene rubber (SBR) vulcanizates were explored. A series of unfilled and filled SB...

  • Article
  • Open Access
33 Citations
6,543 Views
11 Pages

6 May 2021

Thermoplastic polyurethanes (TPUs) and other elastomers are widely used in many applications for the advantages they provide in terms of high elasticity, lightness, resistance to breakage, and impact resistance. These materials exhibit strong hystere...

  • Review
  • Open Access
291 Citations
47,934 Views
24 Pages

Polymer 3D Printing Review: Materials, Process, and Design Strategies for Medical Applications

  • Amit M. E. Arefin,
  • Nava Raj Khatri,
  • Nitin Kulkarni and
  • Paul F. Egan

6 May 2021

Polymer 3D printing is an emerging technology with recent research translating towards increased use in industry, particularly in medical fields. Polymer printing is advantageous because it enables printing low-cost functional parts with diverse prop...

  • Article
  • Open Access
20 Citations
3,727 Views
10 Pages

Incorporation of Elastin to Improve Polycaprolactone-Based Scaffolds for Skeletal Muscle via Electrospinning

  • Victor Perez-Puyana,
  • Paula Villanueva,
  • Mercedes Jiménez-Rosado,
  • Fernando de la Portilla and
  • Alberto Romero

6 May 2021

Skeletal muscle regeneration is increasingly necessary, which is reflected in the increasing number of studies that are focused on improving the scaffolds used for such regeneration, as well as the incubation protocol. The main objective of this work...

  • Article
  • Open Access
2,734 Views
22 Pages

Design of Kinematic Connectors for Microstructured Materials Produced by Additive Manufacturing

  • Miguel R. Silva,
  • João A. Dias-de-Oliveira,
  • António M. Pereira,
  • Nuno M. Alves,
  • Álvaro M. Sampaio and
  • António J. Pontes

6 May 2021

The main characteristic of materials with a functional gradient is the progressive composition or the structure variation across its geometry. This results in the properties variation in one or more specific directions, according to the functional ap...

  • Article
  • Open Access
10 Citations
3,910 Views
20 Pages

Waste Fiber-Based Poly(hydroxamic acid) Ligand for Toxic Metals Removal from Industrial Wastewater

  • Md. Lutfor Rahman,
  • Zhi-Jian Wong,
  • Mohd Sani Sarjadi,
  • Collin G. Joseph,
  • Sazmal E. Arshad,
  • Baba Musta and
  • Mohd Harun Abdullah

6 May 2021

Toxic metals in the industrial wastewaters have been liable for drastic pollution hence a powerful and economical treatment technology is needed for water purification. For this reason, some pure cellulosic materials were derived from waste fiber to...

  • Article
  • Open Access
78 Citations
6,989 Views
14 Pages

6 May 2021

Fused deposition modelling (FDM) is a popular but complex additive manufacturing process that works with many process parameters which are crucial to investigate. In this study, 3D parts were fabricated by placing each filament layer in opposite dire...

  • Article
  • Open Access
15 Citations
3,287 Views
19 Pages

Polyacrylamide Grafted Xanthan: Microwave-Assisted Synthesis and Rheological Behavior for Polymer Flooding

  • Souheyla Chami,
  • Nicolas Joly,
  • Patrizia Bocchetta,
  • Patrick Martin and
  • Djamel Aliouche

5 May 2021

Application of polymer-flooding systems in secondary and tertiary oil recovery represents a real challenge for oil industry. In this work, our main objective is to explore possibilities of making use of xanthan-g-polyacrylamide for polymer flooding i...

  • Article
  • Open Access
15 Citations
3,402 Views
15 Pages

5 May 2021

To avoid the delamination of the traditional three-dimensional (3-D) honeycomb electromagnetic (EM) absorbing composites and improving the defects of low mechanical properties, the 3-D honeycomb woven fabrics were woven on the ordinary loom by practi...

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Polymers - ISSN 2073-4360