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Review

Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications

1
Key Laboratory for Advanced Materials and Shanghai Key Laboratory of Functional Materials Chemistry, Institute of Applied Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China
2
The State Key Laboratory of Metal Matrix Composites & Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Dongchuan Road 800, Shanghai 200240, China
3
Center for Advancing Electronics Dresden (CFAED) & Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany
*
Authors to whom correspondence should be addressed.
Polymers 2018, 10(3), 318; https://doi.org/10.3390/polym10030318
Submission received: 24 February 2018 / Revised: 9 March 2018 / Accepted: 12 March 2018 / Published: 14 March 2018
(This article belongs to the Special Issue RAFT Living Radical Polymerization and Self-Assembly)

Abstract

Reversible addition-fragmentation chain transfer (RAFT) is considered to be one of most famous reversible deactivation radical polymerization protocols. Benefiting from its living or controlled polymerization process, complex polymeric architectures with controlled molecular weight, low dispersity, as well as various functionality have been constructed, which could be applied in wide fields, including materials, biology, and electrology. Under the continuous research improvement, main achievements have focused on the development of new RAFT techniques, containing fancy initiation methods (e.g., photo, metal, enzyme, redox and acid), sulfur-free RAFT system and their applications in many fields. This review summarizes the current advances in major bright spot of novel RAFT techniques as well as their potential applications in the optoelectronic field, especially in the past a few years.
Keywords: RAFT polymerization; chain transfer agent; initiation method; optoelectronic applications RAFT polymerization; chain transfer agent; initiation method; optoelectronic applications
Graphical Abstract

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MDPI and ACS Style

Tian, X.; Ding, J.; Zhang, B.; Qiu, F.; Zhuang, X.; Chen, Y. Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications. Polymers 2018, 10, 318. https://doi.org/10.3390/polym10030318

AMA Style

Tian X, Ding J, Zhang B, Qiu F, Zhuang X, Chen Y. Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications. Polymers. 2018; 10(3):318. https://doi.org/10.3390/polym10030318

Chicago/Turabian Style

Tian, Xiangyu, Junjie Ding, Bin Zhang, Feng Qiu, Xiaodong Zhuang, and Yu Chen. 2018. "Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications" Polymers 10, no. 3: 318. https://doi.org/10.3390/polym10030318

APA Style

Tian, X., Ding, J., Zhang, B., Qiu, F., Zhuang, X., & Chen, Y. (2018). Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications. Polymers, 10(3), 318. https://doi.org/10.3390/polym10030318

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