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Polymers, Volume 10, Issue 3

2018 March - 116 articles

Cover Story: A key step in the manufacture of bioresorbable vascular scaffolds (BVSs) for treatment of coronary heart disease is "stretch blow molding", which expands a nearly amorphous poly L-lactide (PLLA)-extruded tube from an outer diameter (OD) of 1.5 mm to an OD of 3.6 mm with a final wall thickness of ~150 µm. A new instrument probes the rate and morphology of PLLA crystallization during (center pattern, 45% OD-strain, t=70 s) and after (lower right, 350 s; after elongation ceases at 150% OD-strain, 100 s) azimuthal elongation using in situ X-ray scattering. Control of crystallinity may enable thinner scaffolds (~80 µm instead of ~150 µm) to facilitate implantation and improve outcomes. View the paper
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Articles (116)

  • Article
  • Open Access
39 Citations
7,557 Views
25 Pages

Optimization of Mechanical Properties for Polyoxymethylene/Glass Fiber/Polytetrafluoroethylene Composites Using Response Surface Methodology

  • Jasbir Singh Kunnan Singh,
  • Yern Chee Ching,
  • Luqman Chuah Abdullah,
  • Kuan Yong Ching,
  • Shaifulazuar Razali and
  • Seng Neon Gan

20 March 2018

This paper investigated the effects of polytetrafluoroethylene (PTFE) micro-particles on mechanical properties of polyoxymethylene (POM) composites. Since PTFE is immiscible with most polymers, the surface was etched using sodium naphthalene salt in...

  • Article
  • Open Access
20 Citations
8,013 Views
17 Pages

20 March 2018

Poly(vinylidene fluoride) (PVDF) based ferroelectric polymers have attracted considerable attention both academically and industrially due to their tunable ferroelectric properties. By pinning the conformation of the polymer chain and the ferroelectr...

  • Article
  • Open Access
21 Citations
5,434 Views
18 Pages

20 March 2018

An epoxy-thiol system filled with boron nitride (BN), in the form of 80 µm agglomerates, has been investigated with a view to achieving enhanced thermal conductivity. The effect of BN content on the cure reaction kinetics has been studied by differen...

  • Article
  • Open Access
16 Citations
5,283 Views
14 Pages

20 March 2018

A novel composite composed of lignocellulose (LC), glutaraldehyde crosslinked chitosan (GC) and multiwalled carbon nanotube (MWCNT) was fabricated by the hot-pressing process. The effect of the additional GC and MWCNT on the mechanical strength, dime...

  • Review
  • Open Access
163 Citations
15,693 Views
33 Pages

Chitosan Derivatives: Introducing New Functionalities with a Controlled Molecular Architecture for Innovative Materials

  • Waldo M. Argüelles-Monal,
  • Jaime Lizardi-Mendoza,
  • Daniel Fernández-Quiroz,
  • Maricarmen T. Recillas-Mota and
  • Marcelino Montiel-Herrera

20 March 2018

The functionalization of polymeric substances is of great interest for the development of innovative materials for advanced applications. For many decades, the functionalization of chitosan has been a convenient way to improve its properties with the...

  • Article
  • Open Access
25 Citations
8,516 Views
14 Pages

19 March 2018

Tubuliform silk is one of the seven different types of spider silks, which is well known for its unique tensile behaviour with Flat Tensile Stress–Strain (FTSS) curve. It is found that anisotropic microstructure of β-sheets is responsible for this pr...

  • Article
  • Open Access
28 Citations
4,110 Views
26 Pages

Numerical Investigation of Masonry Strengthened with Composites

  • Giancarlo Ramaglia,
  • Gian Piero Lignola,
  • Francesco Fabbrocino and
  • Andrea Prota

19 March 2018

In this work, two main fiber strengthening systems typically applied in masonry structures have been investigated: composites made of basalt and hemp fibers, coupled with inorganic matrix. Starting from the experimental results on composites, the out...

  • Article
  • Open Access
15 Citations
6,773 Views
13 Pages

19 March 2018

Hydrogel microcapsules are improved transplantation delivery vehicles for pharmaceuticals by effectively segregating the active ingredients from the surroundings and delivering them to a certain target site. Layer-by-layer (LbL) assembly is an attrac...

  • Article
  • Open Access
9 Citations
5,680 Views
18 Pages

Cargo Release from Polymeric Vesicles under Shear

  • Yingying Guo,
  • Luca Di Mare,
  • Robert K. Y. Li and
  • Janet S. S. Wong

19 March 2018

In this paper we study the release of cargo from polymeric nano-carriers under shear. Vesicles formed by two star block polymers— A 12 B 6 C 2 ( A B C ) and A 12 B 6 A 2 ( A B A )—and one linear block copoly...

  • Article
  • Open Access
5 Citations
8,204 Views
14 Pages

19 March 2018

Three different polyfunctional acrylate monomers—trimethylolpropantriacrylate (TMPTA), pentaerythritol triacrylate (PETA) and di(trimethylolpropane) tetraacrylate (DTTA)—have been used as comonomers in combination with a reactive resin consisting of...

  • Article
  • Open Access
11 Citations
4,900 Views
12 Pages

18 March 2018

Two new low bandgap conjugated polymers, PBDTS-ID and PBDTS-DTNT, containing isoindigo (ID) and naphtho[1,2-c:5,6-c′]bis[1,2,5]thiadiazole (NT), respectively, as an electron-deficient unit and alkylthiothienyl-substituted benzodithiophene (BDTS) as a...

  • Article
  • Open Access
15 Citations
7,240 Views
12 Pages

Appropriate Donor-Acceptor Phase Separation Structure for the Enhancement of Charge Generation and Transport in Polymer Solar Cells

  • Dayong Zhang,
  • Rong Hu,
  • Jiang Cheng,
  • Yuqiang Chang,
  • Mingming Huo,
  • Junsheng Yu,
  • Lu Li and
  • Jian-Ping Zhang

18 March 2018

The morphology of active layer for polymer solar cells is critical to enhance the performance especially for fill factor of the devices. To investigate the relationship between active layer morphology and performance of polymer solar cells (PSCs), 1,...

  • Article
  • Open Access
6 Citations
6,850 Views
14 Pages

16 March 2018

A mixed micelle approach is used to produce amphiphilic brush nanoparticles (ABNPs) with cadmium sulfide quantum dot (QD) cores and surface layers of densely grafted (σ = ~1 chain/nm2) and asymmetric (fPS = 0.9) mixed polymer brushes that contain hyd...

  • Article
  • Open Access
41 Citations
5,652 Views
15 Pages

Antibacterial Capability, Physicochemical Properties, and Biocompatibility of nTiO2 Incorporated Polymeric Scaffolds

  • Cijun Shuai,
  • Chenying Shuai,
  • Pei Feng,
  • Chengde Gao,
  • Shuping Peng and
  • Youwen Yang

16 March 2018

Postoperative infection is a common risk which brings about failure in bone transplantation. In this study, nano titanium dioxide (nTiO2) was incorporated into Polyetheretherketone/polyglycolicacid (PEEK/PGA) blends to construct antibacterial scaffol...

  • Article
  • Open Access
6 Citations
5,002 Views
18 Pages

16 March 2018

We have recently solved the tumbling-snake model for concentrated polymer solutions and entangled melts in the presence of both steady-state and transient shear and uniaxial elongational flows, supplemented by a variable link tension coefficient. Her...

  • Article
  • Open Access
11 Citations
6,246 Views
11 Pages

16 March 2018

Recently, high-resolution patterning techniques of stretchable electronics advanced extensively. An important trend is to fabricate complex circuits with varied sizes in a small area, which is a technical challenge to current conductive ink printing...

  • Article
  • Open Access
6 Citations
6,054 Views
12 Pages

15 March 2018

Selenium-containing monomer monophenyl maleimide selenide (MSM) was synthesized and copolymerized with styrene (St) using reversible addition-fragmentation chain transfer (RAFT) polymerization. Copolymers with controlled molecular weight and narrow m...

  • Article
  • Open Access
16 Citations
5,402 Views
15 Pages

Hydrophobicity Tuning by the Fast Evolution of Mold Temperature during Injection Molding

  • Sara Liparoti,
  • Roberto Pantani,
  • Andrea Sorrentino,
  • Vito Speranza and
  • Giuseppe Titomanlio

15 March 2018

The surface topography of a molded part strongly affects its functional properties, such as hydrophobicity, cleaning capabilities, adhesion, biological defense and frictional resistance. In this paper, the possibility to tune and increase the hydroph...

  • Article
  • Open Access
14 Citations
6,941 Views
14 Pages

A Simple, Green Method to Fabricate Composite Membranes for Effective Oil-in-Water Emulsion Separation

  • Qianqian Yu,
  • Wenbo Zhang,
  • Xinyue Zhao,
  • Guoliang Cao,
  • Feng Liu,
  • Xin Di,
  • Haiyue Yang,
  • Yazhou Wang and
  • Chengyu Wang

15 March 2018

Most factories discharge untreated wastewater to reduce costs, causing serious environmental problems. Low-cost, biological, environmentally friendly and highly effective materials for the separation of emulsified oil/water mixtures are thus in great...

  • Article
  • Open Access
10 Citations
4,552 Views
16 Pages

15 March 2018

We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, w...

  • Article
  • Open Access
36 Citations
9,096 Views
22 Pages

15 March 2018

Nonionic-zwitterionic diblock copolymers are designed to feature a coil-to-globule collapse transition with an upper critical solution temperature (UCST) in aqueous media, including physiological saline solution. The block copolymers that combine pre...

  • Article
  • Open Access
33 Citations
9,084 Views
17 Pages

Engineering Polyzwitterion and Polydopamine Decorated Doxorubicin-Loaded Mesoporous Silica Nanoparticles as a pH-Sensitive Drug Delivery

  • Feng Ji,
  • Hong Sun,
  • Zhihui Qin,
  • Ershuai Zhang,
  • Jing Cui,
  • Jinmei Wang,
  • Shuofeng Li and
  • Fanglian Yao

15 March 2018

Multifunctional drug carriers have great applications in biomedical field. In this study, we introduced both polydopamine (PDA) and zwitterionic polymer of poly(3-(3-methacrylamidopropyl-(dimethyl)-ammonio)propane-1-sulfonate) (PSPP) onto the surface...

  • Article
  • Open Access
2 Citations
5,614 Views
14 Pages

14 March 2018

Small liquid crystal domains with random director distributions were obtained to show novel optical isotropy using a holographic exposure processes to treat chiral dopant liquid crystal cells in the isotropic phase (i.e., polymer-stabilized isotropic...

  • Article
  • Open Access
42 Citations
6,606 Views
13 Pages

Comparative Study of Ex Vivo Transmucosal Permeation of Pioglitazone Nanoparticles for the Treatment of Alzheimer’s Disease

  • Marcelle Silva-Abreu,
  • Lupe Carolina Espinoza,
  • Lyda Halbaut,
  • Marta Espina,
  • María Luisa García and
  • Ana Cristina Calpena

14 March 2018

Pioglitazone has been reported in the literature to have a substantial role in the improvement of overall cognition in a mouse model. With this in mind, the aim of this study was to determine the most efficacious route for the administration of Piogl...

  • Article
  • Open Access
23 Citations
6,197 Views
16 Pages

Preparation and Application of Phosphorylated Xylan as a Flocculant for Cationic Ethyl Violet Dye

  • Zhongming Liu,
  • Dingding Xu,
  • Nannan Xia,
  • Xin Zhao,
  • Fangong Kong,
  • Shoujuan Wang and
  • Pedram Fatehi

14 March 2018

In this study, phosphorylated birchwood xylan was produced under alkali conditions using trisodium trimetaphosphate. Three single-factor experiments were used to explore the influences of time, temperature, and the molar ratio of trisodium trimetapho...

  • Article
  • Open Access
51 Citations
7,395 Views
16 Pages

14 March 2018

Dual component microencapsulated hydrophobic amine and microencapsulated isocyanate were designed and fabricated for self-healing anti-corrosion coating. In this system, novel hydrophobic polyaspartic acid ester (PAE) and isophorone diisocyanate (IPD...

  • Review
  • Open Access
104 Citations
28,710 Views
26 Pages

Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications

  • Xiangyu Tian,
  • Junjie Ding,
  • Bin Zhang,
  • Feng Qiu,
  • Xiaodong Zhuang and
  • Yu Chen

14 March 2018

Reversible addition-fragmentation chain transfer (RAFT) is considered to be one of most famous reversible deactivation radical polymerization protocols. Benefiting from its living or controlled polymerization process, complex polymeric architectures...

  • Article
  • Open Access
19 Citations
5,672 Views
12 Pages

14 March 2018

In this report, the isolation and rheological characterization of cellulose nanofibrils from coir (CNFs-1) were studied and compared with the CNFs from wood (CNFs-2) and cotton (CNFs-3). Cellulose nanofibrils were isolated successfully from coir fibe...

  • Article
  • Open Access
64 Citations
6,970 Views
15 Pages

13 March 2018

The utilization of four types of biomass particles, including hardwood (poplar), softwood (radiata pine), crop (wheat straw) and bamboo (moso bamboo), as reinforcing fillers in preparing high density polyethylene (HDPE) based composites was studied....

  • Article
  • Open Access
23 Citations
8,011 Views
14 Pages

Synthesis, Characterization and Drug Loading of Multiresponsive p[NIPAm-co-PEGMA] (core)/p[NIPAm-co-AAc] (Shell) Nanogels with Monodisperse Size Distributions

  • Rajesh Raju,
  • Sulalit Bandyopadhyay,
  • Anuvansh Sharma,
  • Susana Villa Gonzalez,
  • Per Henning Carlsen,
  • Odd Reidar Gautun and
  • Wilhelm Robert Glomm

13 March 2018

We report the synthesis and properties of temperature- and pH-responsive p([NIPAm-co-PEGMA] (core)/[NIPAm-co-AAc] (shell)) nanogels with narrow size distributions, tunable sizes and increased drug loading efficiencies. The core-shell nanogels were sy...

  • Article
  • Open Access
10 Citations
8,041 Views
14 Pages

Reusable Xerogel Containing Quantum Dots with High Fluorescence Retention

  • Xiang-Yong Liang,
  • Lu Wang,
  • Zhi-Yi Chang,
  • Li-Sheng Ding,
  • Bang-Jing Li and
  • Sheng Zhang

13 March 2018

Although various analytical methods have been established based on quantum dots (QDs), most were conducted in solution, which is inadequate for storage/transportation and rapid analysis. Moreover, the potential environmental problems caused by abando...

  • Article
  • Open Access
6 Citations
5,599 Views
11 Pages

Enantiopure Chiral Coordination Polymers Based on Polynuclear Paddlewheel Helices and Arsenyl Tartrate

  • Ángela Valentín-Pérez,
  • Ahmad Naim,
  • Elizabeth A. Hillard,
  • Patrick Rosa and
  • Miguel Cortijo

13 March 2018

Herein, we report the preparation of chiral, one-dimensional coordination polymers based on trinuclear paddlewheel helices [M3(dpa)4]2+ (M = Co(II) and Ni(II); dpa = the anion of 2,2′-dipyridylamine). Enantiomeric resolution of a racemic mixture of [...

  • Article
  • Open Access
38 Citations
6,152 Views
20 Pages

13 March 2018

Two different types of organic montmorillonite, namely quaternary ammonium salt intercalated MMT (CMMT) and quaternary phosphonium salt intercalated MMT (PMMT) were used as fillers in the flame-retardant polyamide (PA6) based on aluminium salts of di...

  • Article
  • Open Access
280 Citations
22,574 Views
11 Pages

13 March 2018

The current paper studies the influence of geometrical parameters of the fused deposition modeling (FDM)—fused filament fabrication (FFF) 3D printing process on printed part strength for open source desktop 3D printers and the most popular material u...

  • Article
  • Open Access
75 Citations
9,029 Views
15 Pages

3D Printable Filaments Made of Biobased Polyethylene Biocomposites

  • Daniel Filgueira,
  • Solveig Holmen,
  • Johnny K. Melbø,
  • Diego Moldes,
  • Andreas T. Echtermeyer and
  • Gary Chinga-Carrasco

13 March 2018

Two different series of biobased polyethylene (BioPE) were used for the manufacturing of biocomposites, complemented with thermomechanical pulp (TMP) fibers. The intrinsic hydrophilic character of the TMP fibers was previously modified by grafting hy...

  • Article
  • Open Access
48 Citations
10,041 Views
15 Pages

12 March 2018

Although poly vinyl alcohol-poly acrylic acid (PVA-PAA) composites have been widely used for biomedical applications, their incorporation into double-layer assembled thin films has been limited because the interfacial binding materials negatively inf...

  • Review
  • Open Access
117 Citations
11,203 Views
27 Pages

Green Strategies for Molecularly Imprinted Polymer Development

  • Raquel Viveiros,
  • Sílvia Rebocho and
  • Teresa Casimiro

12 March 2018

Molecular imprinting is a powerful technology to create artificial receptors within polymeric matrices. Although it was reported for the first time by Polyakov, eighty-four years ago, it remains, nowadays, a very challenging research area. Molecularl...

  • Review
  • Open Access
14 Citations
9,913 Views
33 Pages

Polymeric Materials for Conversion of Electromagnetic Waves from the Sun to Electric Power

  • SK Manirul Haque,
  • Jorge Alfredo Ardila-Rey,
  • Yunusa Umar,
  • Habibur Rahman,
  • Abdullahi Abubakar Mas’ud,
  • Firdaus Muhammad-Sukki and
  • Ricardo Albarracín

12 March 2018

Solar photoelectric energy converted into electricity requires large surface areas with incident light and flexible materials to capture these light emissions. Currently, sunlight rays are converted to electrical energy using silicon polymeric materi...

  • Article
  • Open Access
2 Citations
4,686 Views
11 Pages

11 March 2018

The crystal growth of poly(ε-caprolactone) can be very effectively directed through the use of small amounts of dibenzylidene sorbitol in conjunction with modest flow fields to yield extremely high levels of the preferred polymer crystal orientation....

  • Article
  • Open Access
7 Citations
5,367 Views
12 Pages

Ultrasound- and Thermo-Responsive Ionic Liquid Polymers

  • Kohei Itsuki,
  • Yuuki Kawata,
  • Komol Kanta Sharker and
  • Shin-ichi Yusa

11 March 2018

Poly(sodium 2-acrylamido-2-methylpropanesulfonate) (PAMPSNa) was prepared via reversible addition-fragmentation chain transfer (RAFT) radical polymerization. An ionic liquid polymer (PAMPSP4448) was then prepared by exchanging the pendant counter cat...

  • Article
  • Open Access
28 Citations
5,937 Views
13 Pages

Holographic Lenses in an Environment-Friendly Photopolymer

  • Tomás Lloret,
  • Víctor Navarro-Fuster,
  • Manuel G. Ramírez,
  • Manuel Ortuño,
  • Cristian Neipp,
  • Augusto Beléndez and
  • Inmaculada Pascual

11 March 2018

In this paper, we theoretically and experimentally evaluated the quality of volume phase transmission lenses stored in an environmentally friendly photopolymer. Holographic lenses (HLs) were obtained using symmetrical and asymmetrical experimental se...

  • Feature Paper
  • Article
  • Open Access
19 Citations
4,572 Views
13 Pages

11 March 2018

A series of poly(vinylphenol-co-methacryisobutyl polyhedral oligomeric silsesquioxane) (PVPh-co-PMAPOSS) random copolymers have been synthesized through free radical copolymerizations of acetoxystyrene with methacryisobutyl POSS monomer and subsequen...

  • Article
  • Open Access
26 Citations
5,391 Views
14 Pages

Preparation of Molecularly Imprinted Mesoporous Materials for Highly Enhancing Adsorption Performance of Cytochrome C

  • Zhiling Li,
  • Ping Guan,
  • Xiaoling Hu,
  • Shichao Ding,
  • Yuan Tian,
  • Yarong Xu and
  • Liwei Qian

10 March 2018

Molecularly imprinted mesoporous materials (MIMs) were synthesized to improve the adsorption performance of Cytochrome c (Cyt c) by using an imidazolium-based amphiphilic ionic liquid 1-octadecyl-3-methylimidazolium chloride (C18MIMCl) as surfactant...

  • Review
  • Open Access
24 Citations
10,777 Views
32 Pages

10 March 2018

Functional core-shell-structured particles have attracted considerable attention recently. This paper reviews the synthetic methods and morphologies of various electro-stimuli responsive polyaniline (PANI)-coated core-shell-type microspheres, includi...

  • Article
  • Open Access
93 Citations
10,467 Views
18 Pages

9 March 2018

The arctic strain of Chlorella sp. (Chlorella-Arc) exists in the coldest and driest arctic ecosystems, and it is a new resource of active polysaccharides. The extraction of crude polysaccharide from Chlorella-Arc was optimized using the response surf...

  • Article
  • Open Access
9 Citations
4,196 Views
16 Pages

9 March 2018

Continuing efforts to develop novel smart materials are anticipated to upgrade the quality of life of humans. Thermo-responsive poly(N-isopropylacrylamide) and glucose-responsive phenylboronic acid—typical representatives—are often integrated as mult...

  • Article
  • Open Access
49 Citations
6,241 Views
14 Pages

9 March 2018

In this paper, chitosan (CS)/graphene oxide (GO) composite films were prepared, and the effect of γ-ray irradiation on the properties of composite films was investigated. The irradiation crosslinking reaction occurred in composite films with the exis...

  • Article
  • Open Access
39 Citations
8,222 Views
18 Pages

Computer Modeling for Single-Screw Extrusion of Wood–Plastic Composites

  • Krzysztof Wilczyński,
  • Kamila Buziak,
  • Krzysztof J. Wilczyński,
  • Adrian Lewandowski and
  • Andrzej Nastaj

9 March 2018

Experimental and theoretical studies have been performed on the single-screw extrusion of wood–plastics composites. Experimental research has been carried out on the flow and melting of polypropylene (PP)-based composites with different wood flour (W...

  • Article
  • Open Access
70 Citations
7,581 Views
9 Pages

Structural Investigation of Poly(ethylene furanoate) Polymorphs

  • Lucia Maini,
  • Matteo Gigli,
  • Massimo Gazzano,
  • Nadia Lotti,
  • Dimitrios N. Bikiaris and
  • George Z. Papageorgiou

9 March 2018

α and β crystalline phases of poly(ethylene furanoate) (PEF) were determined using X-ray powder diffraction by structure resolution in direct space and Rietveld refinement. Moreover, the α’ structure of a PEF sample was refined from data previously r...

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Polymers - ISSN 2073-4360