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  • Article
  • Open Access

29 April 2024

17 Pages

Modification and Stabilization of Collapsible Loess Using Diammonium Phosphate Solution

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1
School of Earth and Environment, Anhui University of Science and Technology, Huainan 232001, China
2
College of Civil Engineering, Fuzhou University, Fuzhou 350025, China
3
Engineering Research Center of Underground Mine Construction, Ministry of Education, Anhui University of Science and Technology, Huainan 232001, China
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Authors to whom correspondence should be addressed.
This article belongs to the Section Inorganic Crystalline Materials

Abstract

The collapsible loess will rapidly soften and lose its bearing capacity when soaked in water. Under a mild condition (20 °C), the biomimetic inorganic agent, diammonium phosphate (DAP), reacts with calcite in the collapsible loess, producing a stronger bonding material, hydroxyapatite (HAP), to modify and stabilize the soil. Uniaxial compression, permeability tests, and morphological analysis using X-ray diffraction and scanning electron microscopy equipped with an energy X-ray dispersive system were used to assess the effectiveness of DAP stabilization on the collapsible loess. The results indicated that HAP improved the inter-particle bonding within the loess, filled the pores within particles, reduced the permeability, and consequently mitigated the collapsibility of the loess. The compressive strength of the DAP-treated loess increased as DAP concentration increased. Following 28 days of curing, the compressive strength of the loess treated with a 3.0 mol/L DAP solution was six times greater than that of the untreated group. DAP’s reinforcement effect on the loess was superior to that of cement. The compressive strength of the DAP-treated loess was about double that of the cement-treated loess and the permeability coefficient was reduced by more than 50% at equivalent solid content. Furthermore, DAP generated 82% fewer carbon emissions compared to Portland cement. Considering eco-friendly and sustainable development, DAP offers a more competitive alternative for modification and stabilization of loess.

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