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Catalysts, Volume 8, Issue 4 (April 2018)
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Cover Story (view full-size image) Under Sonogashira cross-coupling conditions the base (triethylamine molecule) as a circular saw [...] Read more. Under Sonogashira cross-coupling conditions the base (triethylamine molecule) as a circular saw cuts both N-H bonds in diaminocarbene fragment of immobilized polystyrene-supported acyclic diaminocarbene palladium(II) complex (are shown as PS balls with the molecular structure of complexes) causing a subsequent β-elimination and releasing catalytically active Pd(0) into the solution to feed “starving” aryliodides with a catalytic “cocktail”. View this paper.