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Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites

1
Department of Chemistry, Sidho-Kanho-Birsha University, Purulia 723104, West Bengal, India
2
Department of Chemistry, Shiv Nadar University, Gautam Buddha Nagar 201314, Uttar Pradesh, India
*
Authors to whom correspondence should be addressed.
Academic Editors: Bartolo Gabriele, Raffaella Mancuso and Zhengguo Cai
Molbank 2022, 2022(3), M1447; https://doi.org/10.3390/M1447
Received: 23 July 2022 / Revised: 10 September 2022 / Accepted: 13 September 2022 / Published: 16 September 2022
A mononuclear octahedral mixed-ligand cobalt (II) complex [Co(H2L)(PhCOO)2] (1) has been prepared by using H2L (N,N′-dimethyl-N,N′-bi(2-hydroxy-3,5-di methyl benzyl)-ethylenediamine) as a facially coordinating tetradentate ligand with a N2O2 donor center along with sodium benzoate as an ancillary ligand. Complex 1 has been characterized by a single-crystal X-ray diffraction study, as well as by other spectroscopic tools. The complex crystallizes in the monoclinic space group C2 with a = 31.73(3) Å, b = 7.868(3) Å, c = 19.131(15) Å, and β = 125.25(3)°. The single-crystal X-ray diffraction study shows that in the mononuclear cobalt (II) complex [Co(H2L)(PhCOO)2] (1), the metal center adopts an octahedral environment. View Full-Text
Keywords: mixed-ligand complex; crystal structure; hydrogen interaction; Hirshfeld surface analysis mixed-ligand complex; crystal structure; hydrogen interaction; Hirshfeld surface analysis
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MDPI and ACS Style

Mandal, D.; Haldar, A.; Chakraborty, P.; Ganguly, R. Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites. Molbank 2022, 2022, M1447. https://doi.org/10.3390/M1447

AMA Style

Mandal D, Haldar A, Chakraborty P, Ganguly R. Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites. Molbank. 2022; 2022(3):M1447. https://doi.org/10.3390/M1447

Chicago/Turabian Style

Mandal, Debdas, Anwesha Haldar, Priyanka Chakraborty, and Rakesh Ganguly. 2022. "Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites" Molbank 2022, no. 3: M1447. https://doi.org/10.3390/M1447

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