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Short Note

3-Phenyl-3H-naphtho[1,2-e][1,2,3]oxadiazine

Section of Organic Chemistry and Biochemistry, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece
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Academic Editors: Panayiotis A. Koutentis and Andreas S. Kalogirou
Molbank 2022, 2022(3), M1432; https://doi.org/10.3390/M1432
Received: 30 June 2022 / Revised: 8 August 2022 / Accepted: 14 August 2022 / Published: 24 August 2022
(This article belongs to the Special Issue Heteroatom Rich Organic Heterocycles)
In this study, we considered the reaction of (E)-1-[(2-phenylhydrazono)methyl]naphthalen-2-ol with iodobenzene diacetate in dichloromethane-produced novel 3-phenyl-3H-naphtho[1,2-e][1,2,3]oxadiazine in 11% yield. By analogy to previously published work, we suggested that the reaction proceeds via the intermediacy of an o-naphthoquinone azomethide that undergoes conjugated 6π-electrocylization to produce the product. 1D, 2D NMR, HRMS, IR, and UV-VIS spectra provided information that supported the structure of the product. View Full-Text
Keywords: heterocycle; oxadiazine; naphtho[1,2-e][1,2,3]oxadiazine; o-naphthoquinone azomethide; hydrazone heterocycle; oxadiazine; naphtho[1,2-e][1,2,3]oxadiazine; o-naphthoquinone azomethide; hydrazone
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MDPI and ACS Style

Aouant, A.D.; Varvounis, G. 3-Phenyl-3H-naphtho[1,2-e][1,2,3]oxadiazine. Molbank 2022, 2022, M1432. https://doi.org/10.3390/M1432

AMA Style

Aouant AD, Varvounis G. 3-Phenyl-3H-naphtho[1,2-e][1,2,3]oxadiazine. Molbank. 2022; 2022(3):M1432. https://doi.org/10.3390/M1432

Chicago/Turabian Style

Aouant, Alia D., and George Varvounis. 2022. "3-Phenyl-3H-naphtho[1,2-e][1,2,3]oxadiazine" Molbank 2022, no. 3: M1432. https://doi.org/10.3390/M1432

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