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[N,N′-Di-tert-butyl-P,P-diphenylphosphinimidic Amidato-κNN′]chlorosilicon-κSi-tetracarbonyliron

Department of Chemistry, Graduate School of Science and Engineering, Saitama University, 255 Shimo-okubo, Sakura-ku, Saitama 338-8570, Japan
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Molbank 2022, 2022(3), M1433; https://doi.org/10.3390/M1433
Received: 1 August 2022 / Revised: 14 August 2022 / Accepted: 20 August 2022 / Published: 25 August 2022
(This article belongs to the Section Structure Determination)
The title complex {[Ph2P(tBuN)2](Cl)Si:->Fe(CO)4} (2) was synthesized via the reaction of chlorosilylene [Ph2P(tBuN)2]SiCl (1), supported by an iminophosphonamide ligand with Fe(CO)5 in THF. The molecular structure of 2 was fully characterized by NMR (1H, 13C, 29Si, and 31P) and IR spectroscopies, as well as single-crystal X-ray diffraction (SCXRD) analysis. In the SCXRD analysis of 2, the silylene ligand was located in the axial positions of the coordination sphere of the central iron atom and other sites were occupied by carbonyl ligands. View Full-Text
Keywords: iron; silylene; iminophosphonamide; carbonyl complex; single-crystal X-ray diffraction analysis iron; silylene; iminophosphonamide; carbonyl complex; single-crystal X-ray diffraction analysis
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MDPI and ACS Style

Takahashi, S.; Nakaya, K.; Ishii, A.; Nakata, N. [N,N′-Di-tert-butyl-P,P-diphenylphosphinimidic Amidato-κNN′]chlorosilicon-κSi-tetracarbonyliron. Molbank 2022, 2022, M1433. https://doi.org/10.3390/M1433

AMA Style

Takahashi S, Nakaya K, Ishii A, Nakata N. [N,N′-Di-tert-butyl-P,P-diphenylphosphinimidic Amidato-κNN′]chlorosilicon-κSi-tetracarbonyliron. Molbank. 2022; 2022(3):M1433. https://doi.org/10.3390/M1433

Chicago/Turabian Style

Takahashi, Shintaro, Kazuki Nakaya, Akihiko Ishii, and Norio Nakata. 2022. "[N,N′-Di-tert-butyl-P,P-diphenylphosphinimidic Amidato-κNN′]chlorosilicon-κSi-tetracarbonyliron" Molbank 2022, no. 3: M1433. https://doi.org/10.3390/M1433

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