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Short Note

2,6-Bis[bis(1,1-dimethylethyl)phosphinito-κP]phenyl-κC]-trans-chlorohydro(phenylphosphine)iridium(III)

Department of Chemistry, University of Vermont, Burlington, VT 05405, USA
*
Author to whom correspondence should be addressed.
Current address: Department of Chemistry and Biochemistry, Rowan University, Glassboro, NJ 08028, USA.
Academic Editor: Kristof Van Hecke
Molbank 2022, 2022(2), M1388; https://doi.org/10.3390/M1388
Received: 25 May 2022 / Revised: 15 June 2022 / Accepted: 16 June 2022 / Published: 17 June 2022
(This article belongs to the Section Structure Determination)
The molecular structure of an iridium complex featuring a phenylphosphine ligand is described. The reaction of (POCOP)IrHCl (1, POCOP = 2,6-(tBu2PO)2C6H3) with phenylphosphine gives (POCOP)IrHCl(PH2Ph) (2) under mild conditions. The structural features are consistent with a classic pseudo-octahedral iridium compound with three neutral phosphine donors. Compound 1 is unreactive at elevated temperatures and is unreactive toward excess phenylphosphine under the sampled conditions. View Full-Text
Keywords: iridium; phosphine; dehydrocoupling; pincer iridium; phosphine; dehydrocoupling; pincer
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MDPI and ACS Style

Mucha, N.T.; Waterman, R. 2,6-Bis[bis(1,1-dimethylethyl)phosphinito-κP]phenyl-κC]-trans-chlorohydro(phenylphosphine)iridium(III). Molbank 2022, 2022, M1388. https://doi.org/10.3390/M1388

AMA Style

Mucha NT, Waterman R. 2,6-Bis[bis(1,1-dimethylethyl)phosphinito-κP]phenyl-κC]-trans-chlorohydro(phenylphosphine)iridium(III). Molbank. 2022; 2022(2):M1388. https://doi.org/10.3390/M1388

Chicago/Turabian Style

Mucha, Neil T., and Rory Waterman. 2022. "2,6-Bis[bis(1,1-dimethylethyl)phosphinito-κP]phenyl-κC]-trans-chlorohydro(phenylphosphine)iridium(III)" Molbank 2022, no. 2: M1388. https://doi.org/10.3390/M1388

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