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Molecules, Volume 23, Issue 5

May 2018 - 253 articles

Cover Story: The image shows the disproportionation reaction of Sn(I)Cl yields in the presence of LiGe(SiMe3)3; the metalloid tin clusters Sn10[Ge(SiMe3)3]6, {Sn10[Ge(SiMe3)3]5} and {Sn10[Ge(SiMe3)3]4}2−. All clusters are structurally similar to their Si(SiMe3)3 derivatives, but show different stabilities in solution and different electronic situations for the tin atoms, as shown by 119mSn Mössbauer spectroscopy, giving a first insight into the influence of the substituent on the properties of metalloid tin cluster compounds. View this paper
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Articles (253)

  • Feature Paper
  • Article
  • Open Access
28 Citations
5,789 Views
12 Pages

The photothermal effect of nanoparticles has proven efficient for driving diverse physical and chemical processes; however, we know of no study addressing the dependence of efficacy on nanoparticle size. Herein, we report on the photothermal effect o...

  • Article
  • Open Access
53 Citations
5,671 Views
10 Pages

Citri reticulatae pericarpium (CRP), the dried pericarps of Citrus reticulata Blanco and its cultivars, has been widely used in drugs and foods in China for centuries. In this study, an accurate and feasible analytical method based on HS-SPME-GC-MS c...

  • Article
  • Open Access
27 Citations
5,912 Views
14 Pages

The aim of this study was to analyze the impact of osmotic solutions and temperature on the osmotic dehydration (OD) of two cultivars of kiwiberry. OD was carried out in sucrose, xylitol and maltitol solutions at 30 °C and 50 °C, respectively...

  • Article
  • Open Access
10 Citations
5,419 Views
9 Pages

MS/MS-Guided Isolation of Clarinoside, a New Anti-Inflammatory Pentalogin Derivative

  • Coralie Audoin,
  • Adam Zampalégré,
  • Natacha Blanchet,
  • Alexandre Giuliani,
  • Emmanuel Roulland,
  • Olivier Laprévote and
  • Grégory Genta-Jouve

Re-investigation of the chemical composition of the annual plant Mitracarpus scaber Zucc. led to the identification of clarinoside, a new pentalogin derivative containing a rare quinovose moiety, and the known compound harounoside. While the planar s...

  • Article
  • Open Access
11 Citations
5,975 Views
23 Pages

This study tested the effect of lactic acid bacteria (LAB) inhibition on Vibrio parahaemolyticus BCRC (Bioresource Collection and Research Center) 10806 and BCRC 12865 in a food model. MTT [3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide...

  • Article
  • Open Access
17 Citations
6,183 Views
14 Pages

Density Functional Theory Applied to Excited State Intramolecular Proton Transfer in Imidazole-, Oxazole-, and Thiazole-Based Systems

  • Fabricio De Carvalho,
  • Maurício D. Coutinho Neto,
  • Fernando H. Bartoloni and
  • Paula Homem-de-Mello

Excited state intramolecular proton transfer (ESIPT) is a photoinduced process strongly associated to hydrogen bonding within a molecular framework. In this manuscript, we computed potential energy data using Time Dependent Density Functional Theory...

  • Article
  • Open Access
45 Citations
5,966 Views
18 Pages

Evaluation of Transition Metal Complexes of Benzimidazole-Derived Scaffold as Promising Anticancer Chemotherapeutics

  • Afzal Hussain,
  • Mohamed F. AlAjmi,
  • Md. Tabish Rehman,
  • Azmat Ali Khan,
  • Perwez Alam Shaikh and
  • Rais Ahmad Khan

Three new transition metal complexes, Cu(II) 1, Co(II) 2, and Zn(II) 3 with ligand “bimnap” derived from 1-methyl-2-aminobenzimidazole and 2-hydroxynapthaldehyde were synthesized and characterized. The structure of the ligand was determin...

  • Review
  • Open Access
46 Citations
9,852 Views
16 Pages

Currently, millions of people are living with human immunodeficiency virus type 1 (HIV-1), which causes acquired immunodeficiency syndrome. However, the spread of the HIV-1 resistance to antiviral agents is the major problem in the antiretroviral the...

  • Article
  • Open Access
52 Citations
6,885 Views
12 Pages

Isolation and Antimicrobial Activity of Coumarin Derivatives from Fruits of Peucedanum luxurians Tamamsch

  • Jarosław Widelski,
  • Simon Vlad Luca,
  • Adrianna Skiba,
  • Ioanna Chinou,
  • Laurence Marcourt,
  • Jean-Luc Wolfender and
  • Krystyna Skalicka-Wozniak

As a continuation of searching for phytoconstituents that act as promising agents for antimicrobial therapy, rare coumarins were isolated from fruits of Peucedanum luxurians and tested. In a first step, the content of major compounds in the aerial pa...

  • Article
  • Open Access
7 Citations
4,139 Views
18 Pages

d-Amino Acid Peptide Residualizing Agents for Protein Radioiodination: Effect of Aspartate for Glutamate Substitution

  • Marek Pruszynski,
  • Choong Mo Kang,
  • Eftychia Koumarianou,
  • Ganesan Vaidyanathan and
  • Michael R. Zalutsky

The residualizing prosthetic agent Nε-(3-[*I]iodobenzoyl)-Lys5-Nα-maleimido-Gly1-d-GEEEK ([*I]IB-Mal-d-GEEEK) showed promise for the radioiodination of monoclonal antibodies (mAbs) that bind to internalizing molecular targets. Although...

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Molecules - ISSN 1420-3049