Search Results (15)

With the acceleration of construction industrialization and carbon reduction goals, prefabricated steel structures are widely used for their efficiency and strength. However, steel’s poor fire resistance limits its use. At high temperatures, steel weakens, leading to collapse risks. Common fire protection methods like rock wool, fire-resistant boards, and coatings focus on single materials, leaving composite systems for modular steel columns understudied. This study systematically examines the fire resistance of modular steel columns with composite protective layers through tests and simulations. It finds that rock wool shrinks under heat, reducing its effectiveness by approximately 66.7%, and suggests construction improvements to mitigate this issue. A simplified fire resistance formula is proposed, showing that the total fire resistance of multi-layer systems approximates the sum of each layer’s resistance. These insights offer practical design guidance and fill a key research gap in composite fire protection for modular steel structures. Full article

The kinetics of the dissolution of Estonian phosphate rock and the governing reaction mechanisms in hydrochloric acid in technological processes were investigated. The influences of particle size and acid concentrations of 0.5–1.5 M on the reaction rate and the pH variation during the process were studied at a dosage of 2.1 moles of HCl per mole of calcium for 60 min. The results indicated that the solubility of phosphorus reached 94%–100% for the fine samples and 82%–99% for the coarse samples. The time required to achieve an apparent steady-state pH reduced with the increasing acid concentrations and decreasing particle sizes. It was determined that the CaF₂ precipitation in solutions starting at 1 M was faster at higher concentrations. The SEM surface analysis of the insoluble particles proved the existence of etch pit formation. The XPS and EDX analyses affirmed that the dissolution was incongruent. The surface composition of the unreacted particles gave a stoichiometry of CaF_1.8, showing the formation of CaF₂ on the surface. The dissolution kinetics were analyzed using the shrinking core model and showed a combination of chemical reaction, diffusion or interfacial transfer, and diffusion, sequentially for coarse particles or simultaneously for fine fractions. Full article

During the development of a sand-conglomerate reservoir, there is a huge variation in rock grain size and different åmineral compositions of different-sized sand grains. The mineral composition and microstructure of the rock both have an impact on the characteristics of the remaining oil in the reservoir. The stripping mechanism of a surfactant system on sand-conglomerate surface crude oil with varied grain size minerals was explored in this paper. Sand-conglomerate was classified and analyzed to determine their wettability and stripping oil effects. The optimization of the surfactant solution system and molecular dynamics simulation revealed the surfactant stripping mechanism on crude oil on distinct sandstone minerals. The results of the study showed that montmorillonite minerals are more readily adsorbed by surfactants. The crude oil within them is more likely to compete for adsorption and to be stripped off, and then extracted with the recovery fluid. The surfactant solution system can increase the hydrophilicity of the rock surface, make the crude oil on the rock surface shrink and gather, and enhance the transportation ability of the displacement fluid. And the emulsification seals part of the pore in the reservoir, increases the displacement pressure, and improves the overall wave volume. The results of this paper are of great significance for the efficient development of sand-conglomerate reservoirs. Full article

Dalinor Lake, the second-largest endorheic salt lake in Inner Mongolia, has shown a shrinking trend given the lack of a significant decrease in precipitation (PRE). Based on high-spatial-resolution datasets, we employed a linear regression model, Theil–Sen median trend analysis, the Mann–Kendall test, and a land use transfer matrix to identify the spatio-temporal distribution and trends of PRE and actual evapotranspiration (AET) at the watershed scale during 2001–2019; then, the water deficit (WD) caused by land use changes in different surface lithology zones was analyzed. The results showed that the annual PRE and WD of the Dalinor Lake watershed showed insignificant upward trends, while the annual AET showed a significant upward trend. Spatially, about 89% of the watershed showed a significant upward trend for AET, while 12% showed a weak significant upward trend for PRE. The WDs of the aeolian sand zone and the sand, gravel, and silt accumulation zone were most heavily affected by the new increased land use from 2001 to 2019, accounting for 43.14% and 25.56% of the total WD of the watershed, respectively. Specifically, the WD of the aeolian sand zone caused by the new increased grassland and farmland in 2019 accounted for 41.92% and 18.52% of the total WD of the zone, respectively. The WD of the sand, gravel, and silt accumulation zone caused by the new increased grassland and farmland in 2019 accounted for 37.07% and 35.59% of the total WD of the zone, respectively. The WD caused by the new increased land use was increased by 7.78 million m³ in 2019 compared with the corresponding land use type in 2001, which would decrease the water yield. It is necessary to strengthen the protection of regional forest ecosystems in the granite and terrigenous clastic rock zone; standardize pasture management and reduce farmland reclamation in the sand, gravel, and silt accumulation zone, the aeolian sand zone, and the basalt platform zone; and reduce unnecessary impervious land construction in the aeolian sand zone. Full article

In order to study the freezing front characteristics of alpine tunnels under the condition of wind flow field and relying on the Osaka Mountain tunnel in Qinghai Province, the physical model test of an alpine tunnel was built. By using the Surfer software combined with the laboratory test data, the radial and longitudinal temperature variation trends of the tunnel were obtained, and the overall temperature vector graph of the tunnel was simulated; the radial and longitudinal evolutionary laws of a freezing front in an alpine tunnel under airflow conditions were systematically analyzed, and the radial and longitudinal governing equations of a freezing front in the tunnel model under airflow conditions were proposed. The results show that: With the decrease of the test air temperature, the thermonuclear area in the surrounding rock gradually shrinks, the frozen area of surrounding rock at the bottom of the arch gradually increases, and the frozen area of surrounding rock at the top of the arch gradually expands to the interior of the mountain. The influence degree of ventilation on the longitudinal and radial temperature distribution of the tunnel is obvious, and the greater the wind speed, the greater the influence degree. In particular, the fluctuation range of the longitudinal temperature distribution of the tunnel is more extensive under the influence of ventilation. The freezing front distance in the inverted arch area is the largest, and the expansion distance of the freezing front in the wall foot area is obviously higher than that in the vault; the variation of the longitudinal freezing front at different positions of the tunnel shows parabolic attenuation and with an increase in tunnel depth, the trend of freezing front gradually eases and becomes stable and disappears; the three radial regions of the freezing front and the longitudinal quadratic parabola governing equations can predict the specific distribution characteristics of the freezing front at different depths of the tunnel. Full article

The backfill mining method transports treated tailings to the mined-out area, which not only improves the surrounding environment of the mine but also enables the mined-out area to continue mining and production under the support of the filling body. However, with the growth in the depth and scale of mining, ground subsidence, and backfill deformation are becoming increasingly serious problems. As an example, in the Jinchuan mine, a typical multi-stage filling mining mine in China, the deformation law of surface rock mass and backfill are studied through a method combining field monitoring and numerical simulation. The major findings are as follows: (a) A settlement funnel is formed on the ground, and its radius gradually expands with continuous mining and filling. The location of the settlement center moves toward the surface above the footwall of the ore body, and the maximum subsidence reaches 739 mm in 14.5 years. (b) Three-section mining significantly affects the surface deformation, and the single subsidence center on the upper wall develops into the double subsidence center with the mining and filling. When the three-section mining is finished, the maximum value of the surface subsidence reaches about 1.35 m and the mining area is still in a relatively stable state. (c) The whole filling body presents obvious subsidence, with the development of the multi-stage mining and filling. Bed separation phenomena are found between the filling layers, and the closer to the interior, the more obvious it becomes. The backfill’s subsidence characteristics are similar to the surface’s; that is, both the subsidence amount and speed are higher on the hanging wall than on the footwall. (d) The backfill mainly shrinks inward in the horizontal direction, and the deformation is mainly manifested as an internal uplift and an external subsidence in the vertical direction. The mass instability of the backfill is difficult because of the insufficient deformation space, and the influence of large-scale deformation on the mining and overlying strata needs to be considered, as well as the local deformation near the rock contact zone surrounding the backfill. The results provide technical support for filling mining in the Jinchuan mine and provide a reference for other projects with similar engineering conditions. Full article

The closure time of the Shangdan Ocean is critical for understanding the tectonic evolution of the Proto-Tethys Ocean. However, the proposed closure time was prolonged from Ordovician to Devonian. In the present study, detrital zircon from the metasedimentary rocks of the Liba Group in the West Qinling Belt was analyzed to constrain the closure time of the Shangdan Ocean. The three youngest grains from the Liba Group yield a maximum deposition age of 418 ± 13 Ma, indicating the Middle Devonian deposition. Detrital zircon grains show two main U–Pb age peaks of 810 Ma and 440 Ma with εHf_(t) values spanning from −24.3 to +8.8 and −6.3 to +4.1, respectively, suggesting that the sediments of the Liba Group were derived from both the North and South Qinling Belts. The Lower Devonian in the South Qinling Belt shows similar provenance to the Liba Group, whereas sediments from the North Qinling Belt are absent in the Silurian strata of the South Qinling Belt. From Late Silurian to Early Devonian, the tectonic setting changed from subduction to collision. This evidence consistently suggests the disappearance of the Shangdan Ocean. The noticeable decrease in magmatism from 510–420 Ma to 420–390 Ma and the shrinking of εHf_(t) values from −15.5–+12.8 to −8.4–+4.2 reveal that the Shangdan Ocean, as the eastmost embranchment of the Proto-Tethys Ocean, was closed at ca. 420 Ma. Full article

Rock swelling and rock disintegration in the presence of drilling, stimulation and completion fluids are considered to be the main reasons for operational and production problems for wells in clay-rich formations. The impact of these fluids on rock properties shall be established for the effective treatment design. This paper describes the development of the experimental setup for studying rock swelling in reservoir conditions and the application of this setup for the evaluation of swelling mechanisms of shale rock samples. Swelling quantification was performed using measuring piston displacement that was caused by rock swelling in a piston accumulator during pressure maintenance. We studied the interaction of the disintegrated rock samples with water-based and hydrocarbon-based fluids and supercritical CO₂. It was found that alkaline water solution in reservoir conditions causes swelling of the used rock samples in the amount of 1–3% vol. with a direct correlation between the rock swelling magnitude and the total clay content. The change in the rock volume in the presence of the used hydrocarbon-based fluid depends on the content of organic matter, its distribution in the rock, and the clay content. The observed swelling degree in the hydrocarbon fluid and CO₂ was significantly lower (0–0.5% vol.) than in water. The proposed methodology and obtained results can further be used for the optimization of various operations in clay-rich formations. Full article

Strong earthquakes could serve as a trigger for glacier detachment and associated ice–rock avalanches. The 1988 Tsambagarav earthquake (M = 6.4) initiated collapse of part of the glacier tongue and a further ice–rock avalanche with an abnormal 5 km long path in Zuslan valley, Tsambagarav ridge (Mongolian Altai). Early documentation of surface effects in 1988, remote sensing and field data gathered 16 and 30 years after this event allowed for the assessment of the seismic impact on a reduction of “damaged” glacier under conditions of global warming as well as estimating topography changes in this arid and seismically active area. Because of the earthquake, the glacier immediately lost 10.4 % of its area (0.1 km² of tongue surface). Additionally, 56% of its area was lost during 1988–2015, shrinking much faster than neighboring glaciers of similar size and exposition. Collapse of snow–ice cornice in the accumulation zone could play a key role in rapid acceleration of the detached ice block and abnormally long path of the ice–rock avalanche. A large amount of debris material provided more than 16 years of ice melting. Downstream, the valley avalanche debris cover repeats the topography of underlying Pleistocene moraines, which should be considered in regional paleogeographical reconstructions. Full article

Phosphate rock has been considered as one of the most significant secondary rare-earth resource, and the utilization of rare earth elements (REEs) in phosphate rock has attracted increasing attention. In this study, the leaching kinetics of REEs from a phosphate ore from China was studied with the variation of temperature and phosphoric acid concentration under the conditions: ratio of liquid to solid of 12 mL/g, stirring speed of 120 r/min, and phosphate particle size of −0.074 mm amounts 61.1%. The results suggest that there were two distinct stages in leaching process and kinetics of both stages followed shrinking core model. At fast reaction stage, the semi-empirical equation describing the kinetics was 1 − 3(1 − α)^2/3 + 2(1 − α) = 1.885C_H3PO4^0.89exp(−11220/8.31T)t. The semi-empirical equation for slow reaction stage was 1 − 3(1 − α)^2/3 + 2(1 − α) = 0.299C_H3PO4^2.50exp(−18720/8.31T)t. Using shrinking core model and time-to-a-given-fraction method, we found that leaching rate of fast reaction stage was controlled by solid product layer diffusion, and both solid product layer diffusion and chemical reaction determined slow reaction stage. Full article

Extreme climate change due to heat-trapping gases, especially carbon dioxide, necessitates its mitigation. In this context, the carbon dioxide sequestration technology of enhanced weathering has for years been investigated, with a possible implementation strategy via alkaline mineral soil amendment being more recently proposed. Candidate materials for enhanced weathering include calcium and magnesium silicates, most notably those belonging to the olivine, pyroxene and serpentine groups of minerals, given their reactivity with CO₂ and global availability. When these finely crushed silicate rocks are applied to the soil, the alkaline earth metal cations released during mineral weathering gradually react with carbonate anions and results in the formation of pedogenic carbonates, which, over time, and under the right conditions, can accumulate in the soil. This review paper critically reviews the available literature on alkaline mineral soil amendments and its potential to sequester enough CO₂ to be considered a climate change ‘stabilization wedge’. Firstly, evidence of how agricultural soil can serve as a carbon sink in discussed, based on the observed accumulation of inorganic carbon in alkaline mineral-amended soils. Secondly, the impact of alkaline minerals on agricultural soil and crops, and the factors determining the rate of the weathering process are assessed. Lastly, the CO₂ sequestration potential via alkaline mineral soil amendment is quantified according to an idealized shrinking core model, which shows that it has the potential to serve as a climate change stabilization wedge. Full article

The surfaces of saline lakes are shrinking at a threatening rate worldwide. Likewise, the Uchhali complex (formed by three saltwater lakes located in the Salt Range, Pakistan) that serves as a major regional source of water for humans and as a habitat for water birds must be monitored. With this objective in mind, we conducted a study coupling hydrochemistry and stable isotope compositions (δ³⁷Cl, δ¹⁸O and δD) in order to characterize its hydrochemical properties and the main processes controlling them. Results showed that the Uchhali complex salinity has dramatically increased compared to other similar lakes in the world. While the Uchhali (UL) and Khabbeki (KL) lakes present a sodium-chloride hydrofacies, the Jahlar (JL) is of a sodium-bicarbonate type. Hydrochemistry parameters indicate that the weathering of surrounding rocks is the major vector for the increase of total dissolved solids in the water. On the other hand, the observed enrichment in heavy isotopes of the water stable isotope compositions implies that the different lakes are undergoing a long history of intense evaporation. The study of the corresponding δ³⁷Cl isotope compositions supports the conclusion that evaporation, along with weathering, are the main driving processes. Besides climate effects that result in the decrease of annual precipitation and the increase of evaporation, water consumption for domestic purposes (household and agriculture) aggravates the rise of the lakes’ salinity. Full article

Middle-sized earth- and rock-filled dams with clay cores continue to settle by approximately 0.5–1.5% of their height for approximately 1–3 years after their construction phase. This paper investigates the use of high-resolution spaceborne Synthetic aperture Radar (SAR) interferometry to monitor this settlement process, with the case of the Gongming dam in China. The varieties of slope foreshortening and stretching in the radar coordinates are attributed to the radar’s local incidence angle and the dam’s slope heading, which are analysed in detail. Focusing on the embankment slope settlement analysis, the equations for calculating foreshortening and the line-of-sight deformation decomposition are derived in detail for the adjustment and data fusing. The scattering characteristics of different materials on the dam surface are analysed, including the grass slope, concrete slope, top road (crest), top wall, step, and ditch. According to the analysis of the precipitation data from a local meteorological station, the coherence losses on the slopes are mainly caused by surface moisture. Both the TerraSAR-X Spotlight (TSX-SL) data and the COSMO-SkyMed Strip Mode (CSK-SM) data are analysed by the stacking method to assess the slopes’ deformations. The TSX-SL data results show the highest rate of settlement as 2 cm/yr on the top of the dam slope, consistent with the clay core shrinking process. The CSK-SM data show a similar trend in the lower part of the dam slope but underestimate the deformation in the upper part of the slope. Full article

Population trends in rare alpine plant species in the high-mountain zone of the Ukrainian Carpathians are described with regard to the types of habitats where they occur. Populations of cold-adapted species confined to snowbeds, alpine screes, poorly vegetated rocks, and the highest ridges, as well as mires and springs, are very vulnerable to climate change, while their habitats tend to shrink. The direct impact of warming affects mainly the most cryophilic species. Another driver of changes is climate-induced succession that results in denser vegetation cover and encroachment of more thermophilic plants, which replace low-competitive rare alpine species. Their replacement is largely caused by the loss of open microsites suitable for seed recruitment. However, the climate-driven decrease of snow cover often leads to frost damage to vegetation that provides gaps appropriate for the establishment of many rare species. One of the groups of species that benefit from warming includes rather thermophilic tall herbs that are more common in the subalpine zone but have been actively spreading at higher altitudes lately. Full article

Post-entrapment modifications reduce the reliability of fluid inclusions to determine trapping conditions in rock. Processes that may modify fluid inclusion properties are experimentally identified in this study using synthetic fluid inclusions in quartz with a well-defined composition and density. Modifications are characterized with microthermometry (homogenization and dissolution temperatures) and Raman-spectroscopy in binary fluid systems H₂O-D₂O and H₂O-NaCl. Three distinct processes were identified in this study: (1) diffusion of H₂O and D₂O; (2) crystal-recovery, expulsion of H₂O and accumulation of quartz in inclusions (preferential H₂O loss); (3) irreversible total volume increase at the α-β quartz transition. Diffusion is caused by H₂O fugacity gradients and can be modelled according to classical diffusion models. The variability of re-equilibrated properties in fluid inclusion assemblages depends on time, temperature, diffusion distance and the size of fluid inclusions. Negative pressure gradients (internal under-pressure) induce the crystal-recovery process, in which H₂O is preferentially extracted from inclusions that simultaneously shrink by the inward growth of quartz. This process reduces the H₂O concentration and increases the fluid density by total volume loss. Temperature and time are also controlling factors of this process, which is able to transport H₂O against fugacity gradients. Full article