Search Results (41)

Amid increasing interest in enhanced oil recovery and carbon geological sequestration programs, improved static reservoir lithofacies models are emerging as a requirement for well-guided project management. Building reservoir models can leverage seismic attribute clustering for seismic facies mapping. One challenge is that machine learning (ML) seismic facies mapping is prone to a wide range of equally possible outcomes when traditional unsupervised ML classification is used. There is a need to constrain ML seismic facies outcomes to limit the predicted seismic facies to those that meet the requirements of geological plausibility for a given depositional setting. To this end, this study utilizes an unsupervised comparative hierarchical and K-means ML classification of the whole 3D seismic data spectrum and a suite of spectral bands to overcome the cluster “facies” number uncertainty in ML data partition algorithms. This comparative ML, which was leveraged with seismic resolution data preconditioning, predicted geologically plausible seismic facies, i.e., seismic facies with spatial continuity, consistent morphology across seismic bands, and two ML algorithms. Furthermore, the variation of seismic facies classes was validated against observed lithofacies at well locations for the Mississippian carbonates of Kansas. The study provides a benchmark for both unsupervised ML seismic facies clustering and an understanding of seismic facies implications for reservoir/saline-aquifer aspects in building reliable static reservoir models. Three-dimensional seismic reflection P-wave data and a suite of well logs and drilling reports constitute the data for predicting seismic facies based on seismic attribute input to hierarchical analysis and K-means clustering models. The results of seismic facies, six facies clusters, are analyzed in integration with the target-interval mineralogy and reservoir porosity. The study unravels the nature of the seismic (litho) facies interplay with porosity and sheds light on interpreting unsupervised machine learning facies in tandem with both reservoir porosity and estimated (Umaa-RHOmaa) mineralogy. Full article

The spatiotemporal heterogeneity of moisture distribution causes the coal pillar dams in underground water reservoirs to undergo long-term dry–wet cycles (DWCs) under varying moisture content increments (MCIs). Accurately measuring the pore damage and fractal dimensions (D_f) of coal rock by different MCIs under DWCs is a prerequisite for in-depth disclosure of the strength deterioration mechanism of underground reservoir coal pillar dams. This study employed low-field nuclear magnetic resonance (LF-NMR) to quantitatively characterize the pore structural evolution and fractal dimension with different MCI variations (Δw = 4%, 6%, 8%) after one to five DWCs. The results indicate that increasing MCIs at constant DWC numbers (N_DWC) induces significant increases in pore spectrum area, adsorption pore area, and seepage pore area. MRI visualization demonstrates a progressive migration of NMR signals from sample peripheries to internal regions, reflecting enhanced moisture infiltration with higher MCIs. Total porosity increases monotonically with MCIs across all tested cycles. Permeability, T₂ cutoff (T_2C), and D_f of free pores exhibit distinct response patterns. A porosity-based damage model further reveals that the promoting effect of cycle numbers on pore development and expansion outweighs that of MCIs at N_DWC = 5. This pore-scale analysis provides essential insights into the strength degradation mechanisms of coal pillar dams under hydro-mechanical coupling conditions. Full article

A tibial implant is necessary to provide mechanical support in open-wedge high tibial osteotomy (OWHTO) treatment of knee osteoarthritis. The pore structure and porosity of implants exert significant effect on tibia stress distribution and lower limb alignment stability. In this study, finite element (FE) analysis and in vitro biomechanical experiments were utilized to evaluate the impact of different tibial implants on postoperative tibial stress distribution. The biomechanical experimental results of experiments on tibial implants exhibit similar mechanical response patterns to the established finite element model, whose maximum displacement error is 1.18% under 1500 N compressive load. The hybrid porous implant developed in this study demonstrated significant stress reductions in both tibial bone (19.97% and 15.33% lower than mono-porous configurations at 73% porosity) and implant body (31.60% and 11.83% reductions, respectively), while exhibiting diminished micromotion tendencies. This consistent performance pattern was maintained across the entire porosity spectrum (53–83%) in implanted specimens. In summary, the finite element model established using authentic tibial CT data can effectively guide the structural design of tibial implants, and optimized pore structure design can provide enhanced mechanical support effects for tibial implants. Full article

This study investigates the microscopic structural changes and the evolution of physical properties in typical shale samples from three wells in southwestern China during water–rock interactions. Using scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), and other techniques, we analyzed the changes in pore structure, mineral dissolution behavior, and fracture propagation in shale samples of different types (organic-rich, mixed, and inorganic) during water immersion. The results show that water–rock interaction significantly affects the porosity, fracture width, and physical properties of shale. As the reaction time increases, the pore volume and number of pores generally increase in all shale types, with significant fracture propagation. Furthermore, fracture width changes exhibit varying trends depending on the reaction depth. NMR T2 spectrum analysis indicates that water–rock interaction not only influences the expansion of microfractures but also shows different responses in organic and inorganic pores. SEM images further reveal the impact of water–rock interaction on mineral dissolution, particularly during the early stages, where the dissolution of minerals significantly alters the pore structure. Overall, water–rock interaction plays a crucial role in the development of shale gas reservoirs, providing valuable data and theoretical support for future shale gas extraction. Full article

The pursuit of effective climate change mitigation strategies is driving research into geological carbon dioxide (CO₂) storage. The present work explores the interaction of CO₂ with carbonate rocks from the El Abra formation in the Tampico-Misantla basin, focusing on the comparative influence of organic matter (OM) content on mineralization processes, hypothesizing that variations in OM content significantly modulate the mineralization process affecting both the rate and type of carbonate formation. Expanding on a previous study, CO₂ is studied and injected under high-pressure (1350-2350 PSI) and high-temperature (60–110 °C) conditions into two contrasting samples: one with high OM content and another with low OM content. Structural, morphological, and physical adsorption changes were evaluated through Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET) analyses. The findings indicate that the mineralogy of El Abra promotes secondary carbonate precipitation, with rock–fluid interactions significantly enhanced by brine presence. Samples with high OM exhibited a dramatic reduction in average particle size from 13 μm to 2 μm, along with the formation of metastable phases, such as vaterite—evidenced by XRD peak shifting and modifications in the FT-IR spectrum of carbonate bands. Meanwhile, low-OM samples showed an increase in particle size from 1.6 μm to between 3.26 and 4.12 μm, indicating predominant recrystallization. BET analysis confirmed a significant porosity enhancement in high-OM samples (up to 2.918 m²/g). Therefore, OM content plays a critical role in modulating both the rate and type of mineralization, potentially enhancing physical storage capacity in low-OM samples. These integrated findings demonstrate that OM critically governs calcite dissolution, secondary carbonate formation, and microstructural evolution, providing key insights for optimizing CO₂ storage in complex carbonate reservoirs. Full article

Injecting liquid into the formation has an impact on the microstructure of the reservoir and formation fluids, and negative effects often lead to the failure of oil well stimulation measures to achieve the expected results. It is crucial to clarify the reasons for the decrease in the injection capability of low-permeability reservoirs in China and the mechanisms of the impact of on-site injection water quality. This study first conducted injection experiments with different water qualities. To study the micro factors that cause damage, clay mineral X-ray diffraction (XRD) analysis, high-pressure mercury injection experiments before and after damage, nuclear magnetic resonance (NMR) during the damage process, scanning electron microscopy (SEM) after damage, and energy dispersive spectroscopy elemental spectrum analysis (EDS) of incompatible sediment were carried out on the experimental core. In injection experiments with different water qualities, the permeability decreased by up to 65.35% when the injection volume reached 60 PV. The main causes of the decrease in injection capability are poor reservoir porosity and permeability and formation particle blockage. The particles mainly come from suspended particles, emulsified oil, migration of formation particles, and sediment formed by the injected water. This paper also proposes a reference for water quality index optimization in similar reservoirs. The new water quality index reduced permeability damage by at least 3.22%. Full article

In recent years, research on interfacial photothermal water evaporation has been thriving. Due to its inherent porosity, exceptional hydrophilicity, and renewable characteristics, wood has garnered significant attention as a material for interfacial photothermal evaporation absorbers. In order to enhance the cellular channels of poplar and improve its water migration capacity, Trichoderma spiralis was selected to inoculate and culture poplar specimens from different sections for 3, 5, and 7 weeks. Simultaneously, a solar radiation intensity of 1 kW·m⁻² was simulated to perform photothermal evaporation tests on the specimens. This validated the water migration capabilities of different sections of poplar treated with Trichoderma spiralis under light and heat exposure. The characteristic changes were analyzed using electron microscope scanning, infrared spectrum analysis, X-ray photoelectron spectroscopy analysis, surface infiltration performance, and automatic specific surface porosity. The results suggested that the moderate degradation of cellulose and hemicellulose in poplar by Trichoderma spiralis could dredge the cell channels and improve the permeability of poplar, particularly with regard to lateral permeability. The maximum photothermal evaporation rate of the poplar specimen reached 1.18 kg m⁻² h⁻¹, while the evaporation efficiency increased to 72.2%. Full article

The ultrasonic vibration rock-breaking method has been successfully applied to hard rock due to its high efficiency and controllable energy, providing a novel approach for the development of a more efficient, intelligent, safe, and environmentally friendly reconstruction method for coal and rock reservoirs. By subjecting the rock to ultra-high frequency (>15 kHz) vibration load, rapid fatigue damage can be induced within a short period of time, thereby enhancing the extent of cracking in hard rock. In order to investigate the impact of high-frequency vibration excitation on coal cracking, this study conducted exploratory tests using an independently designed ultrasonic vibration excitation system. These tests were combined with nuclear magnetic resonance (NMR) and permeability measurements to compare and analyze the pore fracture structure and permeability changes in coal samples under resonant and non-resonant conditions. Additionally, multifractal characteristics of the coal samples were investigated. The results demonstrate that high-frequency vibration excitation leads to significant expansion of micropores and mesopores in coal samples. Moreover, there is a strong exponential relationship between coal porosity/permeability and excitation time. After 40 s of stimulation, both porosity and permeability increase by 32.4% and over 8400%, respectively; these increases are five times higher for resonance-state compared to non-resonance-state conditions. Furthermore, water-saturated coal samples exhibit multifractal characteristics in their NMR T₂ spectrum distribution, and multifractal parameters ΔD(q)and Δα show positive correlations with the proportion of mesoporous/macropores but negative correlations with the proportion of micropores; conversely, Δf shows an opposite trend relative to pore proportions. The pore structure of coal exhibits intricate multi-scale characteristics, and the heterogeneity at various scales is quantified through multifractal analysis. This study confirms the feasibility of utilizing high-frequency vibration excitation for cracking coal rocks while also providing valuable insights for further expanding its application. Full article

Recent improvements in advanced technology for toxic chemical remediation have involved the application of titanium oxide nanoparticles as a photocatalyst. However, the large energy bandgap associated with titanium oxide nanoparticles (3.0–3.20 eV) is a limitation for their application as a photocatalyst within the solar spectrum. Various structural modification methods have led to significant reductions in the energy bandgap but not without their disadvantages, such as electron recombination. In the current investigation, biochar was made from the leaves of an invasive plant (Acacia saligna) and subsequently applied as a support in the synthesis of titanium oxide nanoparticles. The characterization of biochar-supported titanium oxide nanoparticles was performed using scanning electron microscopy, Fourier transformer infrared, X-ray diffraction, and Brunauer–Emmett–Teller analyses. The results showed that the titanium oxide was successfully immobilized on the biochar’s external surface. The synthesized biochar-supported titanium oxide nanoparticles exhibited the phenomenon of small hysteresis, which represents the typical type IV isotherm attributed to mesoporous materials with low porosity. Meanwhile, X-ray diffraction analysis revealed the presence of a mixture of rutile and anatase crystalline phase titanium oxide. The synthesis of biochar-supported titanium oxide nanoparticles was highly efficient in the degradation of Orange II Sodium dye under solar irradiation. Moreover, 83.5% degradation was achieved when the biochar-supported titanium oxide nanoparticles were used as photocatalysts in comparison with the reference titanium oxide, which only achieved 20% degradation. Full article

Kaolin-based graphitic carbon nitride (g-CNx) composite photocatalysts were synthesized from a urea precursor using a commercial kaolin. Structural characterization by X-ray diffraction and infrared spectroscopy (FTIR) verified the successful thermal polycondensation of g-CNx along the thermal dehydroxylation of kaolinite to metakaolin at 550 °C. The g-CNx content of the composites were estimated by thermogravimetry and CHN analysis, ranging from ca. 87 m/m% to ca. 2 m/m% of dry mass. The addition of kaolin during the composite synthesis was found to have a significant effect: the yield of in situ formed g-CNx drastically decreased (from ca. 4.9 m/m% to 3.8–0.1 m/m%) with increasing kaolin content. CHN and FTIR indicated the presence of nitrogen-rich g-CNx, having a specific surface area of 50 m²/g, which synergistically increased after composite synthesis to 67–82 m²/g. Estimated optical band gaps indicated the affinity to absorb in the visible light spectrum (λ < 413 nm). Photocatalytic activity upon both UV and artificial sunlight irradiation was observed by hydroxyl radical evolution, however, without the synergistic effect expected from the favorable porosity. Full article

Researching the mechanical characteristics of concrete subjected to the freeze–thaw cycle is crucial for building engineering in cold climates. As a result, uniaxial compression tests were performed on concrete samples exposed to various freeze–thaw (F–T) cycles, and the measurements of the pore size distribution, porosity, and P-wave velocity of the saturated concrete samples were obtained, both before and after being exposed to the F–T cycles. Concrete’s F–T damage mechanism and damage evolution model were thoroughly examined. Using rock structure and moisture analysis test equipment to observe the T₂ spectrum, the results showed that the F–T cycles can cause the internal structure of the samples to deteriorate. Porosity and F–T cycles have a positive correlation, although P-wave velocity has a negative correlation with the F–T cycles. As the F–T cycles increased, the specimens’ peak strength and elastic modulus steadily declined, while the peak strain clearly exhibited an increasing trend. A microscopic F–T damage model that takes into account the pore size distribution was developed, based on the relative changes in the pore structure distribution (PSD), before and after the F–T cycles. The concrete sample damage evolution law under various F–T cycles was examined using the following metrics: total energy, pore size distribution, static and dynamic elastic moduli, porosity, and P-wave velocity. Uniaxial compressive strength (UCS) and peak strain tests were used to evaluate the accuracy of the pore size distribution damage model, as well as that of five other widely used damage models. Full article

In this paper, the limestone reservoir of the Upper Permian Taiyuan Formation in the Ordos Basin is taken as the research object. Through various analysis and testing methods, the characterization and classification evaluation of pore structure were carried out. The core porosity and pore structure characteristics were analyzed using nuclear magnetic resonance, gas measurement, and CT scanning. Based on the characteristics of the limestone reservoir, the optimal parameters of NMR testing were calibrated, the NMR testing method of limestone reservoir properties was established, and the NMR porosity of limestone was calculated. Using the core gray map obtained using CT scanning imaging technology, the three-dimensional digital core model of limestone was constructed, its pore space was extracted, and the porosity, pore fractal dimension, and tortuosity were calculated. The results show that with the thermodynamic experiment, the porosity of the sample will remain basically unchanged after 180 min, and the pressure in the sample was measured after 4 h and no air leakage was found. The T2 spectrum of saturated marlite is in the form of three peaks, two peaks, and one peak. On the whole, the p1 peak of the T2 spectrum of limestone corresponds to micropores, and most of the p2 and p3 peaks correspond to mesopores–macropores. The pore size of high porosity samples is 150–350 nm, and the micropores are well developed; the pore size of medium porosity samples is 80–150 nm, and some samples are well developed; the pore size of low porosity samples is mostly bimodal, with two peaks >> 300 nm and <<100 nm. With the increase in depth, the porosity decreases gradually, the fractal dimension decreases, and the tortuosity increases. The research results provide data support for the characterization of the pore structure of the limestone reservoir in the Taiyuan Formation of the Ordos Basin. Full article

Carbon dots (CDs), owing to their excellent photoluminescent features, have been extensively studied for physics preparation methods and for biomedical and optoelectronic device applications. The assessment of the applicability of CDs in the production of luminescent polymeric composites used in LEDs, displays, sensors, and wearable devices is being pursued. The present study reports on an original, environmentally friendly, and low-cost route for the production of carbon dots with an average size of 4 nm by laser ablation in liquid. Jointly, to prove the significance of the study for a wide range of applications, a free-standing flexible polyvinyl alcohol (PVA) composite containing photoluminescent carbon dots was manufactured. CDs were prepared using targets of porose charcoal with a density of 0.271 g/cm³ placed in phosphate-buffered saline (PBS) liquid solution and irradiated for 30 min by pulsed IR diode laser. The optical properties of the obtained suspension containing carbon dots were studied with UV-ViS and FTIR spectroscopies. The photoluminescence of the produced carbon dots was confirmed by the emission peak at 480 nm in the luminescence spectrum. A narrow luminescence band with a full width at half-maximum (FWHM) of less than 40 nm could be an asset in spectral emission analysis in different applications. Atomic force microscopy confirms the feasibility of manufacturing CDs in clean and biocompatible environments, paving the way for an easier and faster production route, crucial for their wider applicability. Full article

The Upper Permian Longtan Formation in the Laoshan Uplift of the South Yellow Sea Basin hosts thick and distinctive tight sandstones. However, a comprehensive understanding of its pore structure and reservoir classification remains lacking. This study investigates the fully cored well, CSDP-2, utilizing thin section analysis, scanning electron microscopy, energy spectrum analysis, X-ray diffraction, high-pressure mercury intrusion, and nuclear magnetic resonance to characterize its petrophysical properties, pore space, and movable fluid characteristics. Additionally, fractal principles are further employed to examine reservoir heterogeneity and conduct a quantitative assessment, considering the complexity of tight sandstone pore structures. The findings reveal that the sandstones predominantly comprise feldspathic litharenites, with an average porosity of 1.567% and permeability of 0.099 mD, primarily containing intragranular pores. Two distinct sets of pores with significantly different sizes (r < 2 μm; r > 6 μm) were identified, displaying relatively high fractal dimensions and discrete distribution. Movable fluids primarily occupy pores with radii > 0.019 μm, reflecting pronounced overall heterogeneity. The reservoir was classified into three categories utilizing permeability, median radius, and movable fluid saturation as key evaluation parameters, with Class I representing a relatively high-quality reservoir. These findings advance our understanding of the pore development mechanism of tight sandstone reservoirs and provide geological evidence for further hydrocarbon exploration in this study area. Full article

Detailed analyses of the reasons for changes in the mechanical parameters of fiberglass exposed to different climatic zones have been made available in the literature; however, such detailed studies of basalt plastic do not yet exist. It is possible to make reasonable conclusions on the climatic resistance of reinforced plastics by monitoring the deformation–strength characteristics in combination with fractographic and DMA analyses of the solar- and shadow-exposed parts of the plastics; additionally, one can conduct analyses of the IR spectrum and the moisture sorbtion kinetics. As a starting point for the climatic aging of polymer composite materials, it is necessary to accept the time of exposure in which the maximum values of the elastic strength properties of polymeric materials are achieved. Based on the results of the DMA analysis, it was found that, unlike basalt-reinforced plastics (where the material is post-cured exclusively at the initial stage of the exposure), in glass-reinforced plastic, a process of destruction occurs. The formation of internal stresses in the material and their growth were determined through observing the duration of climatic exposure. The formation of closed porosity, depending on the duration of exposure, can be assessed using the values of the increase in the average moisture content. A set of experimental studies has established that glass-reinforced plastics are subject to greater destruction under the influence of a very cold climate than the basalt-reinforced plastic. Full article