Search Results (53)

In the context of this study, it is investigated whether catalytic pyrolysis of post-consumer polypropylene might prove an interesting route to the generation of liquid hydrocarbon materials from plastic waste. The optimum product selectivity can be achieved using the appropriate catalyst. To address this problem, we tested three altered natural zeolites as follows: H-ZN, AT-ZN, and AA-ZN, according to a factorial design which accounts for temperature (400–500 °C), heating rate (10–20 °C per minute), and catalyst loading (5–10 percent by weight). Initially, we verified by thermogravimetric and micro-Raman analyses the thermal behavior of the catalytic systems and the consistency of the polypropylene feedstock. This work confirms that the catalyst assists in initiating the chain-scission process, as changes to the zeolites are responsible for the breakdown of polypropylene at a lower temperature. H-ZN showed high liquid recovery (75.4 wt%), particularly under moderate conditions, as confirmed by product-yield analysis. On the other hand, AT-ZN was more conducive to gas formation and light-fraction production at higher temperatures. H-ZN kept the diesel-range fraction (C12–C20) stable nearly to 51%, according to GC–MS; AT-ZN shifted selectivity to gasoline-range hydrocarbons (C6–C11), up to 57% under severe conditions. AA-ZN showed intermediate behavior. The overall conversion and molecular profile of the liquid products were influenced not only by catalyst acidity, temperature, and their interactions but also by Pearson correlation and ANOVA. The results described above indicate that H-ZN is the most promising catalyst for selective polypropylene-to-diesel conversion and prove that modified natural zeolites are an inexpensive and scalable method for valorizing plastic waste in a circular economy. Full article

Keeping the levels of soil major nutrients (total nitrogen, TN; available phosphorous, AP; and available potassium, AK) in optimum condition is important to achieve the goals of precision agriculture systems. To address the issues of slow speed and low accuracy in soil nutrient detection, this study developed a prediction model for soil major nutrients content based on an improved Extreme Learning Machine (ELM) algorithm. This model utilizes a soil major nutrients detection system integrating pyrolysis and artificial olfaction. First, the Bootstrap Aggregating (Bagging) ensemble strategy was introduced during the model integration phase to effectively reduce prediction variance through multi-submodel fusion. Second, Generative Adversarial Networks (GAN) were employed for sample augmentation, enhancing the diversity and representativeness of the dataset. Subsequently, a multi-scale convolutional and Efficient Lightweight Attention Network (ELA-Net) was embedded in the feature mapping layer to strengthen the representation capability of soil gas features. Finally, adaptive hyperparameter tuning was achieved using the Adaptive Chaotic Bald Eagle Optimization Algorithm (ACBOA) to enhance the model’s generalization capability. Results demonstrate that this model achieves varying degrees of performance improvement in predicting total nitrogen (R² = 0.894), available phosphorus (R² = 0.728), and available potassium (R² = 0.706). Overall prediction accuracy surpasses traditional models by 8–12%, with significant reductions in both RMSE and MAE. These results demonstrate that the method can rapidly, accurately, and non-destructively estimate key soil nutrients, providing theoretical guidance and practical support for field fertilization, soil fertility assessment, and on-site decision-making in precision agriculture. Full article

In this study, the advanced oxidation system of peroxymonosulfate (PMS) was activated by molybdenite supported on biochar (Molybdenite@BC), and the degradation efficiency, influencing factors and degradation mechanism of sulfamethoxazole (SMX) were explored through experiments. Molybdenite@BC, a composite material used in the study, was prepared by pyrolysis at high temperature. The optimum pyrolysis temperature was 700 °C, and the mass ratio of molybdenite to biochar (BC) was 1:3. By changing dosage of Molybdenite@BC, pH value, initial concentration of PMS, and the types and concentration of inorganic anions, the effects of various factors on SMX degradation were systematically studied. The optimum reaction conditions of the Molybdenite@BC/PMS process were as follows: Molybdenite@BC dosage was 100 mg/L, PMS concentration was 0.2 mM, pH value was 6.9 ± 0.2, and initial SMX concentration was 6 mg/L. Under these conditions, the degradation rate of SMX was 97.87% after 60 min and 99.06% after 120 min. The material characterization analysis showed that Molybdenite@BC had a porous structure and rich active sites, which was beneficial to the degradation of pollutants. After the composite material was used, the peaks of MoO₂ and MoS₂ became weaker, which indicated that there was some loss of molybdenum from the material structure. Electron paramagnetic resonance (EPR) and radical quenching experiments revealed that Molybdenite@BC effectively catalyzed PMS to generate various reactive oxygen radicals and non-free radicals, including singlet oxygen (¹O₂), hydroxyl radical (^•OH), sulfate radical (SO₄^•−) and superoxide radical (^•O₂⁻). ¹O₂ played a leading role in the degradation of SMX, while ^•OH and SO₄^•− had little influence. The intermediate products of the degradation of SMX in Molybdenite@BC/PMS system were analyzed by liquid chromatography–tandem mass spectrometry (LC–MS). The results showed that there were nine main intermediate products in the process of degradation, and the overall toxicity tended to decrease during the degradation of SMX. The degradation path analysis showed that with the gradual ring opening and bond breaking of SMX, small molecular compounds were generated, which were finally mineralized into H₂O, CO₂, CO₃²⁻, H₂SO₄ and other substances. The research results confirmed that the Molybdenite@BC/PMS process provided a feasible new method for the degradation of SMX in water. Full article

Oil palm kernel shell is an abundant agricultural waste generated by the palm oil industry. To achieve sustainable use of this waste, oil palm kernel shells were converted into valuable resources as active biocarbons. A two-stage preparation method involving N₂ pyrolysis, followed by CO₂ activation, was used to produce the active biocarbon. The optimum pyrolysis conditions that produced the largest BET surface area of 519.1 m²/g were a temperature of 600 °C, a hold time of 2 h, a nitrogen flow rate of 150 cm³/min, and a heating rate of 10 °C/min. The optimum activation conditions to prepare the active biocarbon with the largest micropore surface area or the best micropore/BET surface area combination were a temperature of 950 °C, a CO₂ flow rate of 300 cm³/min, a heating rate of 10 °C/min, and a hold time of 3 h, yielding BET and micropore surface areas of 1232.3 and 941.0 m²/g, respectively, and consisting of 76.36% of micropores for the experimental optimisation technique adopted here. This study underscores the importance of optimising both the pyrolysis and activation conditions to produce an active biocarbon with a maximum micropore surface area for gaseous adsorption applications, especially to capture CO₂ greenhouse gas, to mitigate global warming and climate change. Such a comprehensive and detailed study on the conversion of oil palm kernel shell into active biocarbon is lacking in the open literature. The research results provide a practical blueprint on the process parameters and technical know-how for the industrial production of highly microporous active biocarbons prepared from oil palm kernel shells. Full article

This study investigated the degradation efficacy, kinetics, and mechanism of the ozone (O₃) process and two enhanced O₃ processes (O₃/peroxymonosulfate (O₃/PMS) and O₃/peroxymonosulfate/iron molybdates/biochar composite (O₃/PMS/FeMoBC)), especially the O₃/PMS/FeMoBC process, for the degradation of tetracycline (TC) in water. An FeMoBC sample was synthesized by the impregnation–pyrolysis method. The XRD results showed that the material loaded on BC was an iron molybdates composite, in which Fe₂Mo₃O₈ and FeMoO₄ accounted for 26.3% and 73.7% of the composite, respectively. The experiments showed that, for the O₃/PMS/FeMoBC process, the optimum conditions were obtained at pH 6.8 ± 0.1, an initial concentration of TC of 0.03 mM, an FeMoBC dosage set at 200 mg/L, a gaseous O₃ concentration set at 3.6 mg/L, and a PMS concentration set at 30 μM. Under these reaction conditions, the degradation rate of TC in 8 min and 14 min reached 94.3% and 98.6%, respectively, and the TC could be reduced below the detection limit (10 μg/L) after 20 min of reaction. After recycling for five times, the degradation rate of TC could still reach about 40%. The introduction of FeMoBC into the O₃/PMS system significantly improved the TC degradation efficacy and resistance to inorganic anion interference. Meanwhile, it enhanced the generation of hydroxyl radicals (^•OH) and sulfate radicals (SO₄^•−), thus improving the oxidizing efficiency of TC in water. Material characterization analysis showed that FeMoBC has a well-developed porous structure and abundant active sites, which is beneficial for the degradation of pollutants. The reaction mechanism of the O₃/PMS/FeMoBC system was speculated by the EPR technique and quenching experiments. The results showed that FeMoBC efficiently catalyzed the O₃/PMS process to generate a variety of reactive oxygen species, leading to the efficient degradation of TC. There are four active oxidants in O₃/PMS/FeMoBC system, namely ^•OH, SO₄^•−, ¹O₂, and •O₂⁻. The order of their contribution importance was ^•OH, ¹O₂, SO₄^•−, and •O₂⁻. This study provides an effective technological pathway for the removal of refractory organic matter in the aquatic environment. Full article

Elevated phosphorus levels in aquatic ecosystems have been identified as a critical driver of eutrophication processes, necessitating resource-recovery remediation strategies. Adsorption techniques show particular promise for nutrient recovery due to their selective binding capacities and operational feasibility. In this study, the Mg- and Ca-modified biogas residue-based biochar (Ca-Mg/BC) was successfully prepared via a “bimetallic loading-pyrolysis” modification strategy. The optimum temperature for the calcination of the material and the salt solution impregnation concentrations were determined experimentally through optimization of the synthesis conditions. Structural and chemical analyses of Ca–Mg/BC demonstrated that the material contains MgO and CaO. The specific surface area of Ca–Mg/BC was 8.49 times higher than that of the unmodified biochar (BC). The optimized Ca–Mg/BC achieved 95% phosphate removal rate (157.13 mg/g adsorption capacity). FTIR and XPS characterization results indicated the importance of Ca/Mg loading in phosphate capture. MgO and CaO were mainly loaded on the surface of the material and adsorbed phosphate through a chemical reaction. Crucially, the phosphate-laden biochar exhibited potential as a nutrient-enriched soil amendment, opening the material loop from wastewater treatment to agricultural applications. This sustainable strategy simultaneously addresses water pollution control and sustainable development, providing environmentally benign solutions compatible with industrial effluent treatment and sustainable agriculture practices. Full article

Pyroligneous acid (PA) or wood vinegar, a co-product of biomass pyrolysis, is thought to be beneficial for plant productivity and soils, with the potential to reduce otherwise harmful agrochemicals. Here, we review the evidence for the use of PA on plant growth and soil health parameters. The analysis includes 65 peer-reviewed studies with 171 (yield) and 123 (plant biomass) data sets, covering 33 different crops belonging to 6 plant groups. Significant positive, non-linear relationships between PA concentration, yield, and plant biomass were found at concentrations as low as 0.1%, with the optimum at around 0.5–1% and overall positive effects up to 6–11% (depending on the application type), but yield declines above these concentrations, suggesting herbicidal effects. Across the whole data set, yield and biomass increase by an average of 21% and 25%, respectively, and by an average of 31% at the optimum rate. The positive effect of PA is most pronounced for plant growth under sub-optimal conditions (salt, drought, and pathogens), while responses did not differ between plant groups. Soil organic matter content shows a small but significant positive response to PA application, but the amount of data is very small compared to the plant parameters. The major shortcomings identified include inconsistent measures of applied PA (amount and composition) and the short duration of experiments of typically only 1–2 growing seasons, which prevents analysis of long-term PA effects. Overall, the results of this review encourage further research on PA for sustainable agriculture. Full article

The continuous growth in world energy demands along with the urgent need for decarbonization are strong motivations for the development and usage of sustainable fuels. Hydrogen is highly anticipated to replace fossil fuels in energy production, as it is one of the cleanest energy sources with high energy density per weight. Among the hydrogen production methods, catalytic methane pyrolysis (CMP) stands out as it can contribute to the decarbonization process, since the only co-products include valuable carbon structures and no greenhouse emissions. Cobalt has been shown to be a competent metallic catalytic material with high activity in relation to hydrogen production and selectivity towards valuable carbon nanotubes (CNTs), or carbon nanofibers (CNFs). This review article aims to offer insights relevant to future developments in CMP, by reporting the advantages of methane decomposition over cobalt catalysts. It provides a summary of the factors that influence both hydrogen yield and carbon growth. More specifically, the impacts of different metal loadings and the benefits of utilizing both support carriers and bimetallic systems are addressed. Last but not least, the findings on the most efficient preparation procedures and the optimum operating conditions are also revealed, as supported by published experimental data. Full article

In this study, porous biochar (PvBC) was obtained by the pyrolysis of bean (phaseolus vulgaris) plant at 600 °C, and then activated biochar (PvBCZn) was synthesized by ZnCl₂ activation at an equal biomass ratio (1.0:1.0). Some analytical techniques (SEM-EDX (scanning electron microscopy–energy dispersive X-ray spectroscopy), TGA/DTA (Thermogravimetric/Differential Thermal Analysis), BET (Brunauer–Emmett–Teller), FTIR (Fourier Transform Infrared Spectroscopy) and XRD (X-ray diffraction)) were used to characterize both PvBC and PvBCZn. In addition, their antibiotic sensitivity, water solubility, moisture content and swelling behavior were investigated in detail. Furthermore, both PvBC and PvBCZn were used for the adsorption of primamycin la, an anti-inflammatory drug used in veterinary medicine whose active ingredient is oxytetracycline, in a milk sample. The effect of both pH and adsorbent dosage on the adsorption capacity was investigated. Based on adsorption studies, while the maximum adsorption capacity (q_max) of PvBCZn was found to be 188.48 mg/g, that of PvBC was found to be 122.49 mg/g. According to these results, PvBCZn is an excellent adsorbent for the removal of primamycin la from milk samples. The Langmuir isotherm model and the pseudo-second-order kinetic model were more suitable to describe the adsorption behavior of primamycin la. The PvBCZn adsorbent exhibited rapid removal exceeding 75% in the first 20 min and reached equilibrium after about 50 min. In addition, studies on the desorption and reusability of PvBCZn were carried out under the same optimum experimental conditions. The q_max value of PvBCZn was found to be 171.40 mg/g even in the fifth cycle, confirming the idea that it is a potential adsorbent for the removal of primamycin la. At the same time, the antimicrobial activity of PvBCZn against Escherichia coli bacteria increases its potential to be used in both purification systems and hygiene products. Full article

Biochar is gaining recognition as a sustainable material, with several applications in soil amendment, carbon sequestration, nutrient dynamics, the remediation of organic contaminants from soil, and water filtration. However, understanding its characteristics is limited due to its intricate structure. This study used response surface methodology (RSM) and artificial neural networks (ANNs) to optimize and predict the production of biochar from the pyrolysis of palm kernel shells. To determine how residence time, nitrogen flow rate, and pyrolysis temperature affected biochar production, a Box–Behnken experimental design was employed. The prediction of the biochar yield was modeled using four different models of ANNs: narrow, medium, wide, and optimum. The physicochemical properties of the biochar produced at pyrolysis temperatures ranging from 400 to 800 °C were determined using X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), nitrogen (N₂) physisorption analysis, and field emission scanning electron microscopy (FESEM). With a p-value significantly lower than 0.05, the response surface quadratic model was found to be the most suitable to optimize the biochar yield obtained from the PKS pyrolysis. Biochar production was very sensitive to the three operating parameters: pyrolysis temperature, nitrogen flow rate, and pyrolysis time. With a coefficient of determination (R²) of 0.900, root mean square error (RMSE) of 0.936, and mean absolute error (MAE) of 0.743, the optimized ANN outperformed the other three ANN models tested. When compared to the optimized ANN, the response surface quadratic model with an R² of 0.989 had better prediction of biochar yield. At optimized experimental conditions for nitrogen flow rate (150.01 mL/min), temperature (799.71 °C), and pyrolysis time (107.61 min), a biochar yield of 37.87% was obtained at a desirability function of 1. Full article

Background: Due to it containing cellulose, hemicellulose, and lignin with abundant specific functional groups which could interact with organic dyes, garlic peel (GP) might be used as an efficient biosorbent. The aim of this study is to evaluate the adsorption performances of GP-based bio-adsorbents and obtain optimum preparation conditions. Methods: GP-based bio-adsorbents were prepared by thermal pyrolysis under different temperatures (150–400 °C). The morphologies, chemical states, and surface functional groups of the adsorbents were analyzed by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). Batch experiments were conducted to investigate the adsorption of methylene blue (MB) under various conditions, including contact time, contact temperature, initial dye concentration, and initial pH value. The equilibrium adsorption data were fitted to different kinetic and isothermal models, and the adsorption thermodynamics were also calculated. Significant Findings: The physicochemical properties of the GP-based bio-adsorbents were primarily dominated by the pyrolysis temperature, because their morphologies and surface functional groups of GP-based bio-adsorbents significantly varied with the changes in pyrolysis temperature. The adsorption capacity of GP materials for MB decreased as the pyrolysis temperature increased. At an initial concentration of 50.00 mg L⁻¹, GP150 possessed a higher adsorption capacity of 167.74 mg g⁻¹ toward MB. The possible adsorbate–adsorbent interactions, including electrostatic attraction, hydrogen bonding, and π-π stacking, were recognized. After 10 consecutive adsorption–desorption cycles, GP150 maintained a high removal rate (88%) for MB, demonstrating its excellent adsorption performance, good reusability, and potential application in the treatment of MB-contaminated water. Full article

A recently used material that shows environmental and technical advantages for use as an asphalt binder modifier is biochar (BC). Different biomasses can be converted into BC by pyrolysis. One agro-industrial biomass that is abundant in copious quantities is oil palm mesocarp fiber (OPMF) obtained from African palm cultivation. In the present study, the use of a BC obtained from OPMF (BC-OPMF) as a modifier of asphalt binder (AC type) to produce a hot mix asphalt (HMA) was evaluated. This type of BC has not been investigated or reported in the reference literature as a binder and/or asphalt mix modifier. Initially, AC was modified with BC in three ratios (BC/AC = 5, 10, and 15%, with respect to mass) to perform penetration, softening point, and rotational viscosity tests; rheological characterization at high and intermediate temperatures; and scanning electron microscope (SEM) visualization. Based on this experimental phase, BC/AC = 10% was chosen to manufacture the modified HMA. Resistance parameters under monotonic loading (stability—S, flow—F, S/F ratio of the Marshall test, and indirect tensile strength in dry—ITSD and wet—ITSC conditions) and cyclic loading (resilient modulus, permanent deformation, and fatigue resistance under stress-controlled conditions) were evaluated on the control HMA (AC unmodified) and the modified HMA. Additionally, the tensile strength ratio (TSR) was calculated to evaluate the resistance to moisture damage. Abrasion and raveling resistance were evaluated by performing Cantabro tests. BC-OPMF is shown to be a sustainable and promising material for modifying asphalt binders for those seeking to increase stiffness and rutting resistance in high-temperature climates, resistance to moisture damage, raveling, and fatigue without increasing the optimum asphalt binder content (OAC), changing the volumetric composition of the HMA or increasing the manufacturing and construction temperatures. Full article

In this study, we took a closer look at the thermal recyclability of CFRP composites used in the manufacture of high-pressure cylinders. Thermal analysis was used to determine the minimum temperature at which stable resin decomposition begins. The aim was to find temperature parameters and retention times with which the pyrolysis process is as economically viable as possible, and the recovered fibers retain optimum mechanical properties. The surface morphology of fibers annealed in both inert and oxidizing atmospheres was examined. In addition, the mechanical strengths under static as well as dynamic conditions of the newly manufactured laminates containing the recovered fibers were investigated. During research, it was found that reusing fibers is very difficult. The recycled carbon fibers were successfully compressed in an epoxy matrix in the form of a pre-impregnated carbon mat with the presence of air. The presence of oxygen during the thermal degradation of the composite severely damaged the surface and structure of the carbon fiber, causing composites made from these fibers to be mechanically weaker by more than 247%. Full article

This work focused on the decolorization of methyl red (MR) from an aqueous solution utilizing Rumex abyssinicus-derived biochar (RAB). RAB was prepared to involve unit operations such as size reduction, drying, and carbonization. The pyrolysis of the precursor material was carried out at a temperature of 500 °C for two hours. After that, the prepared RAB was characterized by the pH point of zero charge (pHpzc), the Brunauer–Emmett–Teller (BET) method, Scanning Electron Microscopy (SEM) and Fourier-Transform Infrared (FTIR) spectroscopy. On the other hand, a batch adsorption experiment of MR removal onto RAB was conducted, considering four operating parameters: pH, contact time, adsorbent dose, and initial dye concentration. The characterization of the adsorbent material revealed a porous and heterogeneous surface morphology during SEM, a specific surface area of 45.8 m²/g during the BET method, the presence of various functional groups during FTIR, and a pHpzc of 6.2. The batch adsorption experiment analysis results revealed that a maximum removal efficiency of 99.2% was attained at an optimum working condition of pH 6, contact time of 40 min, initial dye concentration of 70 mg/L and adsorbent dosage of 0.2 g/100 mL. Furthermore, Freundlich isotherm (R² = 0.99) and pseudo-second-order kinetics (R² = 0.99) models confirmed the heterogeneous surface interaction and chemisorption nature. Generally, this study highlighted that RAB could be a potential adsorbent for the detoxification of MR-containing industrial effluents. Full article

Using sodium lignosulfonate as feedstock, ZnCl₂ and NaHCO₃ co-activated the hierarchical porous carbons (HPCs) were prepared by one-pot pyrolysis with different NaHCO₃ dosages (0–4 g) and carbonization temperatures (400–600 °C). Subsequently, phosphotungstate (HPW) was supported with the resulting biochar for the α-pinene hydration reaction to produce α-terpineol. The optimum preparation conditions were determined according to the yield of α-terpineol. The formation mechanism and physicochemical properties of HPCs were analyzed through TG, SEM, XPS, XRD, FT-IR, and N₂ adsorption–desorption isotherms. The results demonstrated that NaHCO₃ underwent a two-step reaction which liberated a substantial quantity of CO₂, thereby enhancing activated carbon’s macroporous and mesoporous structures. Simultaneously, NaHCO₃ mitigated strong acid gas (HCl) emissions during ZnCl₂ activation. Compared with AC450-4:8:0 prepared by ZnCl₂ activation alone, the total pore volume of AC450-4:8:2 prepared by co-activation is increased from 0.595 mL/g to 0.754 mL/g and the mesopore rate from 47.7% to 77.8%, which is conducive to reducing the steric hindrance of the hydration reaction and improving the selectivity. Hydration experiments show that the selectivity of α-terpineol is 55.7% under HPW/AC450-4:8:2 catalysis, higher than 31.0% for HPW and 47.4% for HPW/AC450-4:8:0. Full article