Search Results (321)

An experiment examined the impact of 0.2% to 1.0% w/w graphite nanoparticles in 15W40 lubricating oil on tribological and rheological behaviour. Analysis, conducted with a pin-on-disc machine and four-ball tester, revealed improved tribological properties and a 30% reduction in friction coefficient compared to fresh 15W40. Wear was negligible, and extreme-pressure performance increased by approximately 20%. SEM morphology confirmed the presence of graphite nanoparticles on the tribo-pair surface, indicating enhanced lubricant performance. Full article

Metal–organic frameworks (MOFs) and porous organic frameworks (POFs) have been extensively explored in recent years as lubricant additives for various systems due to their structural designability, pore storage capacity, and tunable surface chemistry. These materials are utilized to construct low-friction, low-wear interfaces and investigate the potential for superlubricity. This paper systematically reviews the tribological behavior and key mechanisms of MOFs/POFs in oil-based, water-based, and solid coating systems. In oil-based systems, MOFs/POFs primarily achieve friction reduction and wear resistance through third-body particles, layer slip, and synergistic friction-induced chemical/physical transfer films. However, limitations in achieving superlubricity stem from the multi-component heterogeneity of boundary films and the dynamic evolution of shear planes. In water-based systems, MOFs/POFs leverage hydrophilic functional groups to induce hydration layers, promote polymer thickening, and soften gels through interfacial anchoring. Under specific conditions, a few cases exhibit superlubricity with coefficients of friction entering the 10⁻³ range. In solid coating systems, two-dimensional MOFs/COFs with controllable orientation leverage interlayer weak interactions and incommensurate interfaces to reduce potential barriers, achieving structural superlubricity at the 10⁻³–10⁻⁴ level on the micro- and nano-scales. However, at the engineering scale, factors such as roughness, contamination, and discontinuities in the lubricating film still constrain performance, leading to amplified energy dissipation and degradation. Finally, this paper discusses key challenges in achieving superlubricity with MOFs/POFs and proposes future research directions, including the design of shear-plane structures. Full article

The stability of nanolubricants is critical for ensuring effective performance under extreme pressure (EP) conditions, where severe boundary lubrication governs friction and wear behaviour. This study examines palm kernel oil (PKO)-based nanolubricants enhanced with carbon graphene (CG), hexagonal boron nitride (hBN), and molybdenum disulfide (MoS₂), with and without oleic acid (OA) as a surfactant. OA incorporation improved CG dispersion stability, reducing agglomerate size by 30.4% (17.61 μm to 12.23 μm) and increasing the viscosity index from ~176 to 188, compared to 152 for the commercial hydrogen engine oil baseline. Under EP conditions, PKO + CG + OA achieved a 51.7% reduction in the coefficient of friction (0.58 to 0.28) and 18.2% improvement in weld load resistance, while wear scar diameter decreased by 13.4%. Surface and elemental analyses indicated the formation of a composite tribofilm containing oxide species, graphene platelets, and carboxylate-derived compounds from OA, consistent with iron–oleate-like chemistry that enhances load-carrying capacity and wear protection. These findings demonstrate the potential of OA-assisted PKO nanolubricants as sustainable, high-performance formulations for extreme pressure boundary lubrication, contributing to the advancement of green tribology. Full article

The global transition from internal combustion engines (ICEs) to hybrid (HEVs) and electric vehicles (EVs) is fundamentally reshaping lubricant design requirements, driven by evolving thermal demands, electrical constraints, and material compatibility challenges. Conventional ICE lubricants are primarily formulated to withstand high operating temperatures, mechanical stresses, and combustion-derived contaminants through established additive chemistries such as zinc dialkyldithiophosphate (ZDDP), with thermal stability and wear protection as dominant considerations. In contrast, HEV lubricants must accommodate frequent start–stop operation, pronounced thermal cycling, and fuel dilution while maintaining performance across coupled mechanical and electrical subsystems. EV lubricants represent a paradigm shift, where requirements extend beyond tribological protection to include electrical insulation and conductivity control, thermal management of electric motors and battery systems, and compatibility with copper windings, polymers, elastomers, and advanced coatings, alongside mitigation of noise, vibration, and harshness (NVH). This review critically examines lubricant behavior, formulation strategies, and performance requirements across ICE, HEV, and EV powertrains, with specific emphasis on heat transfer, electrical performance, and lubricant–material interactions, covering mineral, synthetic, and bio-based fluids. Additionally, regulatory drivers, sustainability considerations, and emerging innovations such as nano-additives, multifunctional and smart lubricants, and AI-assisted formulation are discussed. By integrating recent research into industrial practice, this work highlights the increasingly interdisciplinary role of tribology in enabling efficient, durable, and sustainable mobility for next-generation automotive systems. Full article

This study employs molecular dynamics simulations to investigate the frictional behavior of fullerene nano-additives on Fe-C alloy surfaces under varying loads and temperatures, focusing on boundary lubrication conditions. The results show that the x-direction friction force exhibits minimal sensitivity to normal pressure due to the high rigidity of fullerene molecules, which limits variations in real contact area and atomic interactions. In contrast, temperature has a significant effect: as it rises, enhanced atomic vibrations and thermal activation lower energy barriers for sliding. The coefficient of friction (COF) consistently decreases with both increasing load and temperature, driven by the mechanism of thermally activated motion. Although partial rotational motion from sliding to rolling friction was not explicitly observed in the simulations, the study remains within the sliding-dominated regime, highlighting the importance of temperature over load in controlling friction. A linear relationship between $\ln COF$ and $1/k_{B}T$ yields an average activation energy of ~0.03 eV, supporting a thermally activated friction mechanism. By introducing a composite parameter that combines load and temperature effects, the study provides a predictive framework for modeling friction behavior under thermo-mechanical coupling. These findings enhance the understanding of the friction-reducing capabilities of fullerene additives and offer a foundation for designing advanced nano-lubricants in boundary lubrication systems. Full article

This study examines the rheological and tribological behavior of bio-based nano-lubricants enhanced with cerium oxide (CeO₂) and multi-walled carbon nanotubes (MWCNTs), alongside the application of artificial intelligence (AI) models for performance prediction. Rheological results confirmed non-Newtonian, shear-thinning behavior across all formulations. CeO₂-based lubricants exhibited significantly higher viscosities at 40 °C (up to ~3700 mPa·s at low shear), which decreased sharply with shear, indicating strong particle interactions. In contrast, MWCNT-based lubricants maintained moderate viscosities (90–365 mPa·s at 40 °C) with improved flowability due to nanotube alignment. At 100 °C, both systems showed viscosity reduction, stabilizing between 8 and 18 mPa·s, which favors pumpability in high-temperature applications. Tribological testing revealed distinct performance characteristics. CeO₂ lubricants showed slightly higher coefficients of friction (0.144–0.169) but excellent wear resistance, achieving the lowest wear rate of 1.66 × 10⁻⁶ mm³/N-m. MWCNT-based lubricants offered stable and lower CoF values (0.116–0.148) while also providing very low wear rates, with MCO6 achieving 1.62 × 10⁻⁶ mm³/N-m. However, ternary blends (C20T80 and M20T80) displayed moderate CoF but significantly higher wear rates (up to 2.92 × 10⁻⁵ mm³/N-m), suggesting that blending improves dispersion but weakens tribo-film stability. To complement the experimental findings, support vector regression (SVR), artificial neural networks (ANN), and AdaBoost algorithms were employed to predict key performance parameters based on compositional and thermal input data. The models demonstrated high prediction accuracy, validating the feasibility of AI-driven formulation screening. These results highlight the complementary potential of CeO₂ and MWCNT additives for high-performance bio-lubricant development and emphasize the role of machine learning in accelerating material optimization for sustainable lubrication systems. Full article

This study systematically investigates the effect and mechanism of a TiO₂ nano-lubricant on edge cracking and surface quality during the rolling of Mg/Al composite foils. Initial friction and wear tests identified an optimal nano-lubricant concentration of 3.0 wt.%, at which the system achieved a minimum average coefficient of friction of 0.067. Subsequent rolling tests using this concentration showed that the nano-lubricant reduced rolling force by 5.39–7.54% compared to dry conditions. It also significantly suppressed the initiation and propagation of edge cracks. Furthermore, the surface roughness parameters Ra and Rz were reduced by 16.5% to 24.0%, and the height profile fluctuation range was reduced by 33% to 45%, resulting in a smoother and more uniform surface morphology. The analysis of the underlying mechanism indicates that the superior performance originates from the synergistic effects of the rolling effect, the mending effect, the polishing effect, and the protective film effect. This work establishes that the use of a 3.0 wt.% TiO₂ nano-lubricant is a viable strategy for fabricating high-quality Mg/Al composite foils with minimal defects. It thereby offers both theoretical and practical guidance for the advanced rolling of bimetallic composites. Full article

With the increasing harsh drilling environments encountered more frequently than ever before, developing environmentally benign and multifunctional additives is essential to formulate high performance drilling fluids. Herein, hydrothermal carbon/bentonite composites (HCBCs) were prepared by a hydrothermal carbonization reaction using soluble starch and sodium bentonite as raw materials. A systematic investigation was conducted into the effects of HCBC concentration on the rheological, filtration, and lubricating characteristics of xanthan gum, modified starch, and high-temperature polymer slurries. These properties were evaluated before and after exposure to hot rolling at different temperatures. The hydroxyl radical scavenging properties of HCBC were evaluated. Observation showed plentiful micro- and nano-sized carbon spheres deposited on the bentonite particles, endowing the bentonite with better dispersion. HCBCs could maintain stability of the water-based drilling fluids’ rheological profile, decrease filtration loss, and improve the lubrication with relatively low concentrations. The excellent properties were attributed to the highly efficient scavenging of free radicals and the stabilization of bentonite particle dispersion. Full article

The automotive industry is undergoing a transformative shift toward sustainability, driven by stringent environmental regulations, rising energy demands, and the pursuit of enhanced performance and efficiency. Lubricating materials play a pivotal role in reducing friction, wear, and energy losses in automotive systems, yet conventional lubricants, primarily petroleum-based, pose significant ecological and operational challenges. This review examines the development and performance of sustainable and advanced lubricant including bio-based oils, synthetic esters, nanolubricants, and ionic/solid lubricants for automotive applications. Drawing on tribological principles and recent advances in materials science, the article categorizes these lubricants based on source, chemical structure, and tribological behavior. A comparative framework is introduced to evaluate key performance indicators such as viscosity index, thermal stability, oxidation resistance, biodegradability, and compatibility with modern engine designs. The review also highlights emerging trends, including nanotechnology-based additives, green synthesis techniques, and novel antioxidant systems that enhance lubricant functionality and lifespan. Furthermore, a strategic research roadmap is proposed, outlining short-, medium-, and long-term priorities that integrate technical, environmental, and economic dimensions. By bridging foundational science with practical innovation, this article aims to guide researchers, manufacturers, and policymakers toward the adoption of high-performance, eco-compatible lubricants that support the transition to cleaner and more efficient mobility systems. Future directions and challenges in scaling, cost-effectiveness, and lifecycle assessment are discussed to guide innovation in this critical domain. Full article

The rapid advancement of micro/nano-electromechanical systems (MEMS/NEMS) and precision manufacturing has fundamentally challenged traditional friction theories at the nanoscale. Classical continuum models fail to capture energy dissipation mechanisms at the atomic level, which are influenced by interfacial phenomena such as electron transfer, charge redistribution, and energy level realignment. Density functional theory (DFT), renowned for its accurate description of ground-state properties in many-electron systems, has emerged as a key tool for uncovering quantized friction mechanisms. By quantifying potential energy surface (PES) fluctuations, the evolution of interfacial charge density, and dynamic electronic band structures, DFT establishes a universal correlation between frictional dissipation and electronic behavior, transcending the limitations of conventional models in explaining stick–slip motion, superlubricity, and non-Amonton effects. Research breakthroughs in the application of DFT include characterizing frictional chemical potentials, designing heterojunction-based superlubricity, elucidating strain/load modulation mechanisms, and resolving electronic energy dissipation pathways. However, these advances remain scattered across interdisciplinary studies. This article systematically summarizes methodological innovations and cutting-edge applications of DFT in computational tribology, with the aim of constructing a unified framework for carrying out the “electronic structure–energy dissipation–frictional response” predictions. It provides a state of the art of using DFT to help design high-performance lubricants and actively control interfacial friction. Full article

Graphite, with its layered structure and weak van der Waals bonding between graphene nano layers, exhibits excellent self-lubricating properties. Natural graphite, characterized by high crystallinity, and artificial graphite, with relatively low crystallinity, exhibit distinct friction behaviors and structural differences, which significantly influence the performance of graphite–resin composites as solid lubricants. This study investigates the effects of natural/artificial graphite ratios and hydrophobic silane coupling treatment on the oil impregnation behavior, friction coefficient, wear stability, and microstructural changes in graphite–resin composites. Under a vertical load of 88,260 N and surface pressure of 50 MPa, the impregnated graphite–resin composites demonstrated low friction coefficients and stable wear behavior. SEM analysis revealed well-preserved microstructures, and Raman spectroscopy confirmed the formation of stable lubrication films through the I_D/I_G ratio, indicating graphene exfoliation. The results indicate that natural graphite provides dense structures and stable friction, while artificial graphite enhances oil impregnation but leads to unstable friction behavior. Full article

The increased energy efficiency of electrified vehicles and their potential to reduce CO₂ emissions through the use of environmentally friendly materials are highlighted as reasons for the shift to electrified vehicles. Brief trends on the development of electric vehicles (EVs) have been discussed, presenting outstanding improvement towards the actualization of the green economy. The state of the art in lubrication has been thoroughly investigated as one of the factors influencing energy efficiency and the lifespan of machine components. As a result, many reports on the effectiveness of specific lubricants in electric vehicle applications have been developed. Good thermal and corrosion-resistant lubricants are necessary because of the emergence of several new tribological difficulties, especially in areas that interact with greater temperatures and currents. To avoid fluidity and frictional problems that may be experienced over its lifetime, a good viscosity level of lubricant was also mentioned as a crucial component in the formulation of EV lubricant. New lubricants are also necessary for the gearbox systems of electric vehicles. Furthermore, battery electric vehicles (BEVs) require a suitable cooling system for the batteries; thus, a compatible nano-fluid is recommended. Sustainable battery cooling options support global energy efficiency and carbon emission reduction while extending the life of EV batteries. The path for future advancements or the creation of the most useful and efficient EV lubricants is provided by this review study. Full article

The development of stable and efficient nanolubricants remains one of the main challenges in tribology due to particle agglomeration, poor long-term stability, and inconsistent frictional behavior under boundary lubrication. This study investigates the tribological performance of SAE 10W-40 engine oil enhanced with titanium dioxide (TiO₂) nanoparticles subjected to thermal treatments. TiO₂ powders (Degussa P25, ~30 nm) were calcined at 450 °C, 550 °C, 650 °C, and 750 °C, and incorporated into the base oil at a constant concentration of 0.05 wt%. Tribological tests were conducted using a four-ball tribometer under ASTM D4172 conditions (396 N, 1200 rpm, 30 min) at both ambient (23 °C) and elevated (75 °C) temperatures. The coefficient of friction (COF) and wear scar area (WSA) were measured, while the surface morphology was analyzed via 3D optical profilometry, SEM, and EDS. The results indicate that TiO₂ nanoparticles thermally treated at 550 °C offered the best tribological behavior, exhibiting the lowest COF and smallest WSA at both test temperatures. The improved performance is attributed to optimized crystalline structure and enhanced dispersion stability after calcination. Although no Ti-based tribofilm was detected, smoother wear scars suggest physical surface protection mechanisms, such as rolling and asperity smoothing. These findings highlight the critical influence of thermal treatment on nanoparticle effectiveness and demonstrate the potential of optimized nanoadditized lubricants for advanced friction and wear reduction under boundary lubrication conditions, providing practical guidance for developing next generation nanolubricants with improved durability and efficiency under boundary lubrication conditions. Full article

MXenes, an emerging class of two-dimensional (2D) transition metal carbides, nitrides, and carbonitrides, have demonstrated exceptional potential in tribology: the study of friction, wear, and lubrication. Their remarkable mechanical strength, thermal stability, and tunable surface chemistry make them ideal candidates for solid lubricants, lubricant additives, and protective coatings in mechanical systems. This review comprehensively examines the tribological performance of MXenes under diverse environmental conditions, including high temperatures, vacuum, humid atmospheres, and liquid lubricants. A particular emphasis is placed on the influence of surface terminations (-OH, -O, -F) on friction reduction and wear resistance. Additionally, we discuss strategies for enhancing MXene performance through hybridization with polymers, nanoparticles, and ionic liquids, enabling superior durability in applications ranging from micro/nano-electromechanical systems (MEMS/NEMS) to aerospace and biomedical devices. We also highlight recent advances in experimental characterization techniques and computational modeling, which provide deeper insights into MXene tribomechanics. Despite their promise, key challenges such as oxidation susceptibility, high synthesis costs, and performance variability hinder large-scale commercialization. Emerging solutions, including eco-friendly synthesis methods and optimized composite designs, are explored as pathways to overcome these limitations. Overall, MXenes represent a transformative avenue for developing next-generation tribological materials that combine high efficiency, sustainability, and multifunctionality. Continued research and innovation in this field could unlock groundbreaking advancements across industrial and engineering applications. Full article

Magnesium alloys are widely used in automotive and aerospace applications due to their light weight but suffer from poor tribological performance. This study investigates the effects of base oil (SAE 5W-30) with 100% hBN, 100% ZnO, and various ratios of hBN/ZnO hybrid nanoparticles on the tribological performance of AZ91D magnesium alloy. Pin-on-disk tribometer tests were conducted on AZ91D magnesium alloy under loads of 10–60 N and a sliding distance of 1000 m. Dry sliding produced the highest coefficient of friction (COF, ~0.30) and the greatest wear. Base oil lubrication reduced COF to ~0.14 and improved wear resistance by more than 50%. The 100% hBN nanolubricant provided the lowest wear and a COF of ~0.114, while the 75hBN/25ZnO hybrid achieved the lowest COF (~0.110) with wear values close to hBN. Surface analyses confirmed that hBN formed a lamellar tribofilm that minimized metal-to-metal contact, and ZnO contributed to the formation of load-bearing oxide layers that enhanced surface stability. Overall, the results demonstrate that hBN and ZnO, in single or hybrid form, can significantly reduce friction and wear, showing strong potential for applications in automotive, aerospace, defense, and industrial systems. Full article