Search Results (369)

A computational fluid dynamics (CFD) numerical simulation methodology was implemented to model transient heating processes in steel industry reheating furnaces, targeting combustion efficiency optimization and carbon emission reduction. The effects of oxygen concentration (O₂%) and different fuel types on the flow and heat transfer characteristics were investigated under both oxygen-enriched combustion and MILD oxy-fuel combustion. The results indicate that MILD oxy-fuel combustion promotes flue gas entrainment via high-velocity oxygen jets, leading to a substantial improvement in the uniformity of the furnace temperature field. The effect is most obvious at O₂% = 31%. MILD oxy-fuel combustion significantly reduces NOx emissions, achieving levels that are one to two orders of magnitude lower than those under oxygen-enriched combustion. Under MILD conditions, the oxygen mass fraction in flue gas remains below 0.001 when O₂% ≤ 81%, indicating effective dilution. In contrast, oxygen-enriched combustion leads to a sharp rise in flame temperature with an increasing oxygen concentration, resulting in a significant increase in NOx emissions. Elevating the oxygen concentration enhances both thermal efficiency and the energy-saving rate for both combustion modes; however, the rate of improvement diminishes when O₂% exceeds 51%. Based on these findings, MILD oxy-fuel combustion using mixed gas or natural gas is recommended for reheating furnaces operating at O₂% = 51–71%, while coke oven gas is not. Full article

Circulating fluidized bed fly ash (CFBFA) stockpiles release alkaline dust, high-pH leachate, and secondary CO₂/SO₂—an environmental burden that exceeds 240 Mt yr⁻¹ in China alone. Yet, barely 25% is recycled, because the high f-CaO/SO₃ contents destabilize conventional cementitious products. Here, we presents a pressurized flue gas heat curing (FHC) route to bridge this scientific deficit, converting up to 85 wt% CFBFA into structural lightweight gravel. The gypsum dosage was optimized, and a 1:16 (gypsum/CFBFA) ratio delivered the best compromise between early ettringite nucleation and CO₂-uptake capacity, yielding the highest overall quality. The optimal mix reaches 9.13 MPa 28-day crushing strength, 4.27% in situ CO₂ uptake, 1.75 g cm⁻³ bulk density, and 3.59% water absorption. Multi-technique analyses (SEM, XRD, FTIR, TG-DTG, and MIP) show that FHC rapidly consumes expansive phases, suppresses undesirable granular-ettringite formation, and produces a dense calcite/needle-AFt skeleton. The FHC-treated CFBFA composite gravel demonstrates 30.43% higher crushing strength than JTG/TF20-2015 standards, accompanied by a water absorption rate 28.2% lower than recent studies. Its superior strength and durability highlight its potential as a low-carbon lightweight aggregate for structural engineering. A life-cycle inventory gives a cradle-to-gate energy demand of 1128 MJ t⁻¹ and a process GWP of 226 kg CO₂-eq t⁻¹. Consequently, higher point-source emissions paired with immediate mineral sequestration translate into a low overall climate footprint and eliminate the need for CFBFA landfilling. Full article

Waste cooking oil (WCO) plays different roles in modified asphalt and significantly affects the performance of the binder. However, a systematic comparative study is still lacking in the existing research. This study investigates the effects of WCO used as a swelling agent for rubber powder (RP) and as a compatibilizer in rubber powder-modified asphalt (RPMA) on the performance of modified asphalt. Specifically, the microstructure and functional groups of WCO-coated RP were first characterized. Then, RPMAs with different RP dosages were prepared, and the storage stability and rheological properties of RPMAs were thoroughly investigated. Finally, the flue gas emission characteristics of different RPMAs at 30% RP dosing were further analyzed, and the corresponding inhibition mechanisms were proposed. The results showed that the RP coated by WCO was fully solubilized internally, and the WCO formed a uniform and continuous coating film on the RP surface. Comparative analysis revealed that when WCO was used as a swelling agent, the prepared S-RPMA exhibited superior storage stability. At a 30% RP content, the softening point difference value of S-RPMA was only 1.8 °C, and the reduction rate of the segregation index reached 40.91%. Surprisingly, after WCO was used to coat the RP, the average concentrations of VOCs and H₂S in S-RPMA30 were reduced to 146.7 mg/m³ and 10.6 ppm, respectively, representing decreases of 20.8% and 22.1% compared with the original RPMA30. These findings demonstrate that using WCO as a swelling agent enhances both the physical stability and environmental performance of RPMA, offering valuable insights for the rational application and optimization of WCO incorporation methods in asphalt modification. It also makes meaningful contributions to the fields of coating science and sustainable materials engineering. Full article

The efficient simultaneous removal of NO_x and CO from sintering flue gas under low-temperature conditions (110–180 °C) in iron and steel enterprises remains a significant challenge in the field of environmental catalysis. In this study, we present an innovative strategy to enhance the performance of CuSmTi catalysts through silver modification, yielding a bifunctional system capable of oxygen structure regulation and demonstrating superior activity for the combined NH₃-SCR and CO oxidation reactions under low-temperature, oxygen-rich conditions. The modified AgCuSmTi catalyst achieves complete NO conversion at 150 °C, representing a 50 °C reduction compared to the unmodified CuSmTi catalyst (T_100% = 200 °C). Moreover, the catalyst exhibits over 90% N₂ selectivity across a broad temperature range of 150–300 °C, while achieving full CO oxidation at 175 °C. A series of characterization techniques, including XRD, Raman spectroscopy, N₂ adsorption, XPS, and O₂-TPD, were employed to elucidate the Ag-Cu interaction. These modifications effectively optimize the surface physical structure, modulate the distribution of acid sites, increase the proportion of Lewis acid sites, and enhance the activity of lattice oxygen species. As a result, they effectively promote the adsorption and activation of reactants, as well as electron transfer between active species, thereby significantly enhancing the low-temperature performance of the catalyst. Furthermore, in situ DRIFTS investigations reveal the reaction mechanisms involved in NH₃-SCR and CO oxidation over the Ag-modified CuSmTi catalyst. The NH₃-SCR process predominantly follows the L-H mechanism, with partial contribution from the E-R mechanism, whereas CO oxidation proceeds via the MvK mechanism. This work demonstrates that Ag modification is an effective approach for enhancing the low-temperature performance of CuSmTi-based catalysts, offering a promising technical solution for the simultaneous control of NO_x and CO emissions in industrial flue gases. Full article

This study investigates the emission characteristics and environmental impacts of pollutants from bagasse-fired biomass boilers through the integrated field monitoring of two sugarcane processing plants in Guangxi, China. Comprehensive analyses of flue gas components, including PM_2.5, NOx, CO, heavy metals, VOCs, HCl, and HF, revealed distinct physicochemical and emission profiles. Bagasse exhibited lower C, H, and S content but higher moisture (47~53%) and O (24~30%) levels compared to coal, reducing the calorific values (8.93~11.89 MJ/kg). Particulate matter removal efficiency exceeded 98% (water film dust collector) and 95% (bag filter), while NOx removal varied (10~56%) due to water solubility differences. Heavy metals (Cu, Cr, Ni, Pb) in fuel migrated to fly ash and flue gas, with Hg and Mn showing notable volatility. VOC speciation identified oxygenated compounds (OVOCs, 87%) as dominant in small boilers, while aromatics (60%) and alkenes (34%) prevailed in larger systems. Ozone formation potential (OFP: 3.34~4.39 mg/m³) and secondary organic aerosol formation potential (SOAFP: 0.33~1.9 mg/m³) highlighted aromatic hydrocarbons (e.g., benzene, xylene) as critical contributors to secondary pollution. Despite compliance with current emission standards (e.g., PM < 20 mg/m³), elevated CO (>1000 mg/m³) in large boilers indicated incomplete combustion. This work underscores the necessity of tailored control strategies for OVOCs, aromatics, and heavy metals, advocating for stricter fuel quality and clear emission standards to align biomass energy utilization with environmental sustainability goals. Full article

The purpose of this study was to evaluate the energy and environmental potential of waste biomass in the form of hazelnut shells from selected Turkish varieties of Corylus avellana L. Eight commercial varieties (Çakıldak, Foşa, İnce Kara, Kalın Kara, Palaz, Tombul, Yassı Badem and Yuvarlak Badem) grown in different regions of the Black Sea coast of Turkey were analyzed. The scope of this study included whole nut and shell weight determination, technical and elemental analysis, higher heating value (HHV) and lower net heating value (LHV), as well as emission factors (CO, CO₂, NO_x, SO₂, dust) and flue gas composition based on stoichiometric calculations. The results showed a significant effect of varietal characteristics on all analyzed parameters. The share of shell in the total weight of the nut ranged from 43.5% (Tombul) to 55.3% (İnce Kara). HHV values ranged from 18.37 to 19.20 MJ·kg⁻¹, and LHV from 17.05 to 17.90 MJ·kg⁻¹. The İnce Kara and Yassı Badem varieties showed the most favorable energy properties. Elemental analysis confirmed a low nitrogen and sulfur content, which translated into low NO_x and SO₂ emissions. NO_x emissions were lowest for the Tombul variety (1.43 kg·Mg⁻¹), and SO₂ emissions were close to zero in each variety. The results confirm that Turkish hazelnut shells are a valuable energy resource and can be used as solid fuel or supplementary biomass. In particular, the İnce Kara variety was identified as the most promising due to its high shell weight, very good fuel properties, and high yield potential. This study underscores the importance of selecting the right variety to optimize agricultural waste utilization strategies within a circular economy. Full article

The combustion of fossil fuels is a major source of greenhouse gas emissions, drives climate change, and has intensified the search for cleaner energy alternatives such as biomass. Biomass derived from renewable organic materials, is considered a sustainable and carbon-neutral energy source. While biomass represents a renewable and clean energy source, its combustion, especially in pellet form, can produce various pollutants such as CO₂, SO₂, NO₂, CO, and PM. This study focuses on analyzing the combustion of six different pellet brands and the emissions they produce. A dedicated experimental procedure was designed and implemented to evaluate the combustion performance. The temperature shows a gradual increase in ambient temperature around 2.5 °C across all tests, with a similar behavior, the temperature of flue gas shows a similar behavior between tests with temperatures peaking around 300 °C and 340 °C. In the tests conducted, all pellets complied with the legal emission limits defined by legislation. The efficiency calculated using the direct method was lower by around 55%, primarily due to the use of an older boiler (manufactured in 2004) and short duration of the test. The indirect method shows better efficiency, around 70%, influenced by lower moisture content of the pellets. The results indicate that B pellets had a superior performance compared to the others evaluated. Full article

Heavy industry is a significant contributor to CO₂ global emissions, accounting for approximately 25% of the total. In Europe, the continent’s largest emitting industries, including steel, cement, and power generation, face significant decarbonization challenges due to multiple interrelated factors. Heavy industry must achieve carbon neutrality by 2050, as outlined in the 13th United Nations Sustainable Goals. One strategy to achieve this goal involves Carbon Capture Utilization and Storage (CCUS) with post-combustion carbon capture (PCC) technologies playing a critical role. Key methods include absorption, which uses chemical solvents like amines; adsorption, employing solid sorbents; cyclic CO₂ capture, such as calcium looping methods; cryogenic separation, which involves chilling flue gas to liquefy CO₂; and membrane separation, leveraging polymeric materials. Each technology offers unique advantages and challenges, necessitating hybrid approaches and policy support for widespread adoption. In this sense, this review provides a comprehensive overview of the existing European pilot and demonstration units and projects, funded by the EU across several industries. It specifically focuses on PCC. This study examines 111 industrial facilities across Europe, documenting the PCC technologies deployed at plants of varying capacities, geographic locations, and operational stakeholders. The review further evaluates the techno-economic performance of these systems, assessing their potential to advance carbon neutrality in heavy industries. Full article

Coke production generates up to 400 m³/min of flue gases containing 4% CO₂. This study evaluated the capacity of the microalga Halochlorella rubescens_UFPS013 to capture CO₂ from emissions generated by Excomin SAS (Colombia). A Central Composite Design and response surface methodology were employed to analyze the effects of CO₂ concentration and light–dark cycles on biomass production. The statistical model explained 99% of the observed variability, suggesting a robust foundation with room for further improvement. In situ test showed that H. rubescens_UFPS013 tolerated a flue gas flow rate of up to 0.587 L/min, achieving an optimal predicted biomass yield of 2 g/L under a 12.6 h photoperiod on day 20. The generated biomass exhibited significant protein (48.5%) and lipid (9.6%) content, highlighting its potential for industrial applications in the food and energy sectors. These findings underscore the role of H. rubescens_UFPS013 as a viable biotechnological tool for CO₂ capture in industrial processes, with prospects for scale-up and continuous optimization, contributing to sustainable solutions in emission reduction and the production of high-value bioproducts. Full article

Membrane-based CO₂ capture has emerged as a promising technology for industrial decarbonization, offering advantages in energy efficiency, modularity, and environmental performance. This review presents a comprehensive assessment of membrane processes applied across major emission-intensive sectors, including power generation, cement, steelmaking, and biogas upgrading. Drawing from pilot-scale demonstrations and simulation-based studies, we evaluate how flue gas characteristics, such as CO₂ concentration, pressure, temperature, and impurity composition, govern membrane selection, process design, and operational feasibility. Case studies highlight the technical viability of membrane systems under a wide range of industrial conditions, from low-CO₂ NGCC flue gas to high-pressure syngas and CO₂-rich cement emissions. Despite these advances, this review discusses the key remaining challenges for the commercialization of membrane-based CO₂ capture and includes perspectives on process design and techno-economic evaluation. The insights compiled in this review are intended to support the design of application-specific membrane systems and guide future efforts toward scalable and economically viable CO₂ capture across industrial sectors. Full article

A significant portion of energy losses in industrial systems arises from the inefficient use of high-temperature exhaust gases, emphasizing the need for enhanced heat recovery strategies. This study aims to improve energy efficiency by examining the effects of radiation-intensifying inserts on combined radiative and convective heat transfer in flue-gas heated channels. A systematic literature review revealed a research gap in understanding the interaction between these mechanisms in flue-gas heat exchangers. To address this, analytical calculations were conducted for two geometries: a radiation-intensifying plate between parallel plates and the same insert in a circular pipe. The analysis covered a range of gas-flue and wall temperatures (560–1460 K and 303–393 K, respectively), flow velocities, and spectral emissivity values. Key performance metrics included Reynolds and Nusselt numbers to assess flow resistance and heat transfer. Results indicated that flue-gas temperature has the most significant effect on total rate of heat transfer, and the insert significantly enhanced radiative heat transfer by over 60%, increasing flow resistance. A local Nusselt number minimum at a length-to-diameter ratio of approximately 26 suggested transitional flow behavior. These results provide valuable insights for the design of high-temperature heat exchangers, with future work planned to validate the findings experimentally. Full article

District heating systems in northern China predominantly rely on coal-fired heat sources, necessitating sustainable alternatives to reduce carbon emissions. This study investigates a biomass combined heat and power (CHP) system integrated with cascaded absorption heat pump (AHP) technology to recover waste heat from semi-dry flue gas desulfurization exhaust and turbine condenser cooling water. A multi-source operational framework is developed, coordinating biomass CHP units with coal-fired boilers for peak-load regulation. The proposed system employs a two-stage heat recovery methodology: preliminary sensible heat extraction from non-saturated flue gas (elevating primary heating loop (PHL) return water from 50 °C to 55 °C), followed by serial AHPs utilizing turbine extraction steam to upgrade waste heat from circulating cooling water (further heating PHL water to 85 °C). Parametric analyses demonstrate that the cascaded AHP system reduces turbine steam extraction by 4.4 to 8.8 t/h compared to conventional steam-driven heating, enabling 3235 MWh of annual additional power generation. Environmental benefits include an annual CO₂ reduction of 1821 tonnes, calculated using regional grid emission factors. The integration of waste heat recovery and multi-source coordination achieves synergistic improvements in energy efficiency and operational flexibility, advancing low-carbon transitions in district heating systems. Full article

Post-combustion technology is a new kind of low-nitrogen combustion technology. To achieve the combined removal of nitrogen oxides (NO_x) and sulfur dioxide (SO₂) emissions, the post-combustion technology combined with the sorbent injection in the furnace and post-combustion chamber is proposed. Experiments investigating the effects of the sorbent addition in a post-combustion chamber and post-combustion air arrangement on NO_x and SO₂ emissions were conducted in a 0.1 MWth circulating fluidized bed test platform. In addition, a comparative analysis of the NO_x and SO₂ emissions under both combined removal methods was also performed. The results indicated that adding sorbent to the post-combustion chamber can reduce SO₂ emissions, but further increasing the amount of sorbent will not significantly improve the desulfurization effect. The injection position of the post-combustion air will affect the emissions of NO_x and SO₂ in the flue gas. When the three-stage distribution of post-combustion air is adopted, the further back the third nozzle is distributed, the lower the temperature in the post-combustion chamber, which is beneficial to the control of NO_x and SO₂ emissions. Compared with the conventional combined removal method, the NO_x emissions were significantly reduced under the new combined removal method. Through secondary desulfurization in the furnace and post-combustion chamber, oxygen-deficient combustion in the furnace can achieve the combined removal of NO_x and SO₂. Full article

Recognizing the growing importance of natural gas as a transition fuel in Poland’s energy mix and the necessity of reducing CO₂ emissions, this article aims to assess the use of carbon capture and storage (CCS) technology to effectively reduce CO₂ emissions from combined cycle gas turbine (CCGT). The research employs the pressure–temperature swing adsorption (PTSA) to capture CO₂ from flue gases. Computer simulations, using IPSEpro (SimTech), are used to calculate the heat and mass balances for CCGT and PTSA units and assess their performance. In the first part of the research, the effect of sorbent type (Na-A and 5A) and flue gas share directed to the PTSA unit on the performance of the CCGT was investigated. Secondly, the parametric analysis regarding the adsorption and desorption pressures in the PTSA was carried out. The results showed that CO₂ emissions from CCGT can be reduced by 1.1 Mt (megatons) per year, but the use of PTSA was associated with a reduction in net electrical power and efficiency of the CCGT by up to 14.7% for Na-A and 11.1% for 5A sorbent. It was also found that the heat and electricity demand of the PTSA depends on the adsorption and desorption pressures. Full article

The combustion of gaseous fuels in condensing boilers contributes to the greenhouse gas and toxic compound emissions in exhaust gases. Hydrogen, as a clean energy carrier, could play a key role in decarbonizing the residential heating sector. However, its significantly different combustion behavior compared to hydrocarbon fuels requires thorough investigation prior to implementation in heating systems. This study presents experimental and theoretical analyses of the co-combustion of natural gas with hydrogen in low-power-output condensing boilers (second and third generation), with hydrogen content of up to 50% by volume. The results show that mixtures of hydrogen and natural gas contribute to increasing heat transfer in boilers through convection and flue gas radiation. They also highlight the benefits of using the heat from the condensation of vapors in the flue gases. Other studies have observed an increase in efficiency of up to 1.6 percentage points compared to natural gas at 50% hydrogen content. Up to a 6% increase in the amount of energy recovered by water vapor condensation was also recorded, while exhaust gas losses did not change significantly. Notably, the addition of hydrogen resulted in a substantial decrease in the emission of nitrogen oxides (NOx) and carbon monoxide (CO). At 50% hydrogen content, NO_x emissions decreased several-fold to 2.7 mg/m³, while CO emissions were reduced by a factor of six, reaching 9.9 mg/m³. All measured NO_x values remained well below the current regulatory limit for condensing gas boilers, which is 33.5 mg/m³. These results highlight the potential of hydrogen blending as a transitional solution on the path toward cleaner residential heating systems. Full article