Search Results (1,754)

This research highlights the mechanical performance of alkali-activated polypropylene fiber (PPF) mortar containing natural pozzolan (NP) and waste glass powder (WGP) as partial replacements for cement. A total of 45 mix combinations and 405 samples were prepared by varying the levels of NP, WGP, PPF, and sodium silicate (SS), with sodium hydroxide (SH) as an alkali activator. The levels for these variables are NP (0%, 10%, and 20%) and WGP (0%, 10%, 20%, and 30%) by weight of the cement; PPF (0%, 0.5%, and 1.5%) by volume of mortar; and SS + SH (30%, 40%, and 50%) by weight of the binder. The molarity of the SH solution was kept at 10 M, while the SS/SH ratio was maintained at 2.5. Compressive (f’c), flexural (fr), and split tensile strength (ft) were evaluated at 7, 28, and 90 days. The results showed that strength development is strongly age-dependent, with 85–90% of the total strength achieved at 28 days and continued moderate gains to 90 days. SS + SH was the most significant variable, with 50% of activator content achieving the highest f’c, fr, and ft values. Within the tested ranges of NP (0–20%) and WGP (0–30%), strength showed a decreasing trend with increasing replacement due to dilution. PPF had a very minute effect on f’c but significantly improved fr and ft at 0.5% dosage because of crack-bridging. Correlation analysis confirmed that cement and SS + SH are the most dominant strength-controlling factors. The results suggest that the combined use of NP, WGP, and PPF maintains mechanical performance while reducing cement consumption, highlighting the feasibility of this hybrid alkali-activated mortar as a low-carbon construction material. Full article

Vegetation concrete is a composite material integrating plant growth and concrete technology. In this study, solid waste materials (phosphogypsum and recycled aggregates) were utilized to prepare vegetation concrete. Semi-hydrated phosphogypsum (HPG) was used to replace ordinary Portland cement as a cementitious material in a gradient manner, while recycled coarse aggregates (RCAs) fully replaced natural crushed stone. The basic properties of phosphogypsum–recycled aggregate-based vegetation concrete were analyzed, and X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to characterize the hydration products of vegetation concrete with different mix ratios. The results indicated that replacing cement with HPG exerted a significant alkali-reducing effect and provided favorable cementitious strength. When the porosity was 24% and the HPG content was 50%, the vegetation concrete exhibited optimal performance: the 28-day compressive strength reached 12.3 MPa, and the pH value was 9.7. Recycled aggregates had a minimal impact on strength. When 0.5% sodium gluconate was added as a retarder, the initial setting time was 97 min and the final setting time was 192 min, which met construction requirements with little influence on later-stage strength. Microscopic analysis revealed that the early strength (3d–7d) of vegetation concrete was primarily contributed by CaSO₄·2H₂O crystals (the hydration product of HPG), while the later-stage strength was supplemented by C-S-H (the hydration product of cement). Planting tests showed that Tall Fescue formed a lawn within 30 days; at 60 days, the plant height was 18 cm and the root length was 6–8 cm. Some roots grew along the sidewalls of concrete pores and penetrated the 5 cm thick vegetation concrete slab, demonstrating good growth status. Full article

The comprehensive utilisation of solid waste is a primary approach to enhancing the utilisation efficiency of mineral resources. However, vanadium-titanium slag has long faced insufficient resource utilisation due to its low activity. To address this issue, this study integrated macro and micro analytical methods to systematically investigate the effect of mechanical grinding on the activity of vanadium-titanium slag, as well as its performance when partially replacing blast furnace slag in the system of slag—converter steel slag-desulfurization gypsum ternary gel system. Additionally, the hydration mechanism of this cementitious system was analysed. The research results indicate that mechanical grinding can significantly improve the activity index of vanadium-titanium slag and increase its specific surface area. Replacing an appropriate amount of slag with vanadium-titanium slag in the slag-steel slag-desulfurization gypsum ternary gel system can effectively enhance the mechanical properties of the cementitious system. The optimal mix proportion of vanadium-titanium slag:slag:steel slag:desulfurization gypsum as 10.5:31.5:42:16 with a water-to-binder ratio of 0.32, under which the 28-day compressive strength of the specimen reached 33.50 MPa. Through multiple microscopic analysis techniques, it was found that in the alkaline environment and sulfate excitation (provided by steel slag hydration and desulfurization gypsum), the cementitious system generates hydration products such as ettringite (AFt), C–S–H, and C–A–S–H gels. Some unreacted vanadium-titanium slag particles are wrapped and intertwined by hydrated calcium silicate (aluminium) gels, forming a stable dendritic structure that provides support for the system’s strength development. Full article

In order to ensure the structural safety and serviceability of existing reinforced concrete (RC) structures, there is a compelling need to develop efficient techniques for the rapid replacement of damaged RC beams within strong-column–weak-beam structural systems. This study introduces a novel prefabricated RC beam with welded cover-plate steel sleeve and bolted splice designed to facilitate accelerated replacement and enhance construction efficiency. The proposed beam is connected to cast-in-place RC columns, forming a prefabricated novel prefabricated RC joint with a welded cover-plate steel sleeve and a bolted splice; this configuration contrasts with conventional monolithic RC joints, which are formed by integrally casting beams and columns. The assembly speed of the prefabricated system markedly surpasses that of its cast-in-place counterpart, and the resulting beam–column system is fully demountable. Finite element simulations of the novel prefabricated RC joint with welded cover-plate steel sleeve and bolted splice, performed using ABAQUS, identified the thickness of the welded end-plate as a pivotal parameter influencing the joint’s mechanical behavior. Accordingly, quasi-static tests were carried out on three novel prefabricated RC joints with welded cover-plate steel sleeves and bolted splices and one cast-in-place RC joint, with the welded end-plate thickness serving as the primary test variable. The failure patterns, hysteretic responses, energy dissipation capacity, ductility, and stiffness degradation were systematically analyzed. Experimental findings indicate that increasing the end-plate thickness effectively improves both the peak load-bearing capacity and the ductility of the joint. All prefabricated specimens exhibited fully developed spindle-shaped hysteresis loops, with ductility coefficients ranging from 3.47 to 3.64 and equivalent viscous damping ratios exceeding 0.13. All critical seismic performance metrics either met or exceeded those of the reference cast-in-place RC joint, affirming the reliability and superior behavior of the proposed novel prefabricated RC joints with welded cover-plate steel sleeves. Full article

How to economically and effectively mobilize remaining oil and achieve carbon sequestration after water flooding in low-permeability, high-water-cut reservoirs is an urgent challenge. This study, focusing on Block Y of the Daqing Oilfield, employs numerical simulation to systematically reveal the synergistic influencing mechanisms of CO₂ flooding and geological storage. A three-dimensional compositional model characterizing this reservoir was constructed, with a focus on analyzing the controlling effects of key geological (depth, heterogeneity, physical properties) and engineering (gas injection rate, gas injection volume, bottom-hole flowing pressure) parameters on the displacement and storage processes. Simulation results indicate that the low-permeability characteristics of Block Y effectively suppress gas channeling, enabling a CO₂ flooding enhanced oil recovery (EOR) increment of 15.65%. Increasing reservoir depth significantly improves both oil recovery and storage efficiency by improving the mobility ratio and enhancing gravity segregation. Parameter optimization is key to achieving synergistic benefits: the optimal gas injection rate is 700–900 m³/d, the economically reasonable gas injection volume is 0.4–0.5 PV, and the optimal bottom-hole flowing pressure is 9–10 MPa. This study confirms that for Block Y and similar high-water-cut, low-permeability reservoirs, CO₂ flooding is a highly promising replacement technology; through optimized design, it can simultaneously achieve significant crude oil production increase and efficient CO₂ storage. Full article

This study focused on the preparation of microcapsules that simulate adipose tissue cells via complex coacervation, followed by the formation of block-like fat analogue products through gelation. The results indicated that microcapsules obtained by encapsulating coconut oil with soy protein isolate (SPI) and sodium alginate (SA) through a complex coacervation process could serve as effective fat substitutes in meat products. When the mass ratio of SPI to SA was 3:1, the core-to-wall mass ratio was 1:1, and the total wall material concentration was 3% (w/v), the oil loading rate of the microcapsules reached 39.17%. The particle size of the oil-loaded microcapsules was mainly distributed between 40–180 μm, which was comparable to the size of fat cells in animal adipose tissue. Microcapsules (50%, w/w) were mixed with a 5% (w/v) curdlan dispersion and heated at 95 °C for 60 min to form fat analogues. The fat analogues demonstrated significantly reduced cooking loss, enhanced textural rigidity, and superior chew resistance, achieving performance metrics comparable to those of natural adipose tissue. This dual-phase strategy—combining interfacial engineering of lipid microcapsules with polysaccharide-mediated gelation—provides a promising approach for developing sustainable, plant-based fat alternatives in meat product reformulation. The methodology not only addresses texture and flavour challenges in fat replacement but also enables precise control over lipid content, supporting applications in healthier food systems. Full article

With the continuous growth of the demand for concrete in infrastructure construction, natural aggregate resources have become increasingly scarce. The preparation of concrete using desert sand and recycled aggregates has emerged as an effective approach to achieving the sustainable development of building materials. However, desert sand recycled concrete still confronts critical durability-related challenges when exposed to freeze–thaw conditions. We examined how hybrid fibers (steel fibers and hybrid PP fibers) affect the mechanical performance and freeze–thaw durability of desert sand recycled aggregate concrete, along with the underlying mechanisms. Mechanical properties (compressive, splitting tensile, flexural strength) and freeze–thaw damage indicators (mass loss, dynamic elastic modulus) were tested. The findings indicated that at a 30% desert sand replacement ratio, the concrete achieved optimal initial mechanical properties. For the hybrid fibers group (F0.15-S0.5) with 0.15% hybrid PP fibers and 0.5% steel fibers incorporated, relative to the control group, its compressive strength rose by 31.6%, while mechanical property loss was notably mitigated after 125 freeze–thaw cycles. Freeze–thaw damage models based on the exponential function and the Aas-Jakobsen function were established. Microscopic analysis indicated that the fibers effectively suppressed crack propagation and interfacial transition zone (ITZ) damage. This research offers critical experimental evidence and theoretical frameworks for the application of fiber-reinforced desert sand recycled concrete in cold-climate regions. Full article

The overlying rock in the weathering and oxidation zone has well-developed micro-fissures, making roadway roof control highly challenging. Ordinary cement slurry is hard to inject, failing to achieve effective reinforcement. By introducing admixtures like ultrafine fly ash and polyvinyl alcohol (PVA) to modify ultrafine cement, this paper developed a PVA-modified ultrafine cement-based grouting material (PVAM-UFCG). It systematically investigated the influences of various factors on the slurry’s setting time, fluidity, water separation rate, viscosity, and 28-day uniaxial compressive strength, determining the optimal mix ratio through comprehensive analysis. The results show that the water–cement ratio is the dominant factor affecting slurry viscosity, strength, and setting time; the polycarboxylate superplasticizer concentration has the most significant influence on fluidity and water separation rate; a 20% ultrafine fly ash replacement rate can optimize particle gradation and enhance long-term strength; and a 1.0% polyvinyl alcohol concentration can effectively control the water separation rate (≤5%) and improve slurry cohesiveness. Through range analysis and multi-indicator comprehensive evaluation based on the entropy weight method, the performance-balanced optimal mix ratio meeting the grouting requirements for the Weathering and Oxidation Zone was determined: a water–cement ratio of 0.6, an ultrafine fly ash replacement rate of 20%, a polyvinyl alcohol concentration of 1.0%, and a polycarboxylate superplasticizer concentration of 0.4%. This mix ratio material exhibits good permeability, stability, and appropriate reinforcement strength. The research results can provide a new material choice and theoretical basis for controlling the surrounding rock of roadways under similar geological conditions. Full article

This study presents a comprehensive experimental evaluation of high-performance concretes incorporating calcium sulfoaluminate (CSA) cement as a partial replacement for ordinary Portland cement (OPC). Five CSA replacement levels (0, 15, 30, 45, and 60%) and two water-to-cement ratios (0.40 and 0.45) were examined to assess their effects on mechanical performance and key durability parameters. The experimental program simultaneously investigated compressive strength, tensile splitting strength, water absorption, sorptivity, gas permeability, and freeze–thaw resistance, offering an integrated assessment rarely addressed in previous studies, which typically focus on selected parameters or narrower replacement ranges. The results show that CSA addition enhances microstructural densification, substantially reducing sorptivity and gas permeability and markedly improving freeze–thaw performance even without air entrainment. High CSA contents (45–60%) yielded superior transport-related durability while maintaining competitive 28-day strengths, especially for w/c = 0.40. These findings clarify the interplay between CSA content, transport properties, and frost resistance, highlighting CSA–OPC hybrid binders as a durable and sustainable solution for high-performance concrete applications. Full article

Chronic kidney disease (CKD) is estimated to affect 843.6 million people, accounting for more than 10% of the world’s population, making it a serious public health issue. Dietary therapy is important for suppressing CKD progression risk factors such as hypertension. Fruits granola (FGR), which is rich in dietary fiber, including β-glucan and polyphenols, is expected to contribute to improving the intestinal environment and providing anti-inflammatory effects. We previously reported that FGR consumption improves blood pressure and the intestinal environment in hemodialysis patients. However, the safety and efficacy of FGR for patients with moderate CKD remain unclear. Therefore, we examined the effects of FGR by replacing the breakfast of 24 patients with moderate CKD at least 5 days per week over a total of 2 months. Patients with moderate CKD who were attending outpatient appointments at the Department of Nephrology at Juntendo University Hospital and whose condition was stable were included. Patients with cancer or poor nutritional status were excluded from this study. The results revealed lower systolic blood pressure, low-density lipoprotein cholesterol (LDL-C) levels, and LDL-C/HDL-C ratios after FGR intake. Furthermore, N-acetyl-β-D-glucosaminidase (NAG), a marker of renal tubular damage, was also reduced. Regarding the intestinal environment, improved bowel movements and stool quality were observed. Based on the results of this FGR intervention study, consuming dietary fiber, which is often deficient in moderate CKD patients, may have contributed to reducing risks for cardiovascular disease and urinary tubular dysfunction through FGR intake. Full article

Solid waste-based cementitious materials (SWCMs) represent an innovative class of binders derived mainly from construction and demolition waste as well as industrial byproducts. Their application in recycled mortar offers a promising pathway to partially replace conventional cement, thereby advancing resource recycling and facilitating a low-carbon transition in the cement industry. This review systematically examines the properties, activation techniques, strength development, and corrosion resistance of recycled mortar prepared with SWCMs. Recycled powder (RP) and industrial solid waste have gelation potential, but their low reactivity requires activation treatment to enhance utilization efficiency. Activation methods, including thermal activation, carbonation, and alkali activation, effectively enhance reactivity and promote the formation of dense gel structures (e.g., C-(A)-S-H, N-A-S-H). While low replacement ratios optimize pore structure via the microfiller effect, higher ratios introduce excessive inert components, impairing mechanical properties. SWCMs demonstrate superior resistance to sulfate and chloride attacks, but their acid resistance is relatively limited. They also have excellent freeze–thaw resistance. SWCMs represent a viable and sustainable alternative to conventional cement, exhibiting commendable mechanical and durability properties when properly activated and formulated, thereby contributing to resource recycling and environmental sustainability in the cement industry. Full article

Peat, a vital component of horticultural growing media (GM), is recognized by the Intergovernmental Panel on Climate Change (IPCC) as a solid fossil fuel which significantly contributes to the depletion of fossil resources and greenhouse gas emissions. This study evaluated the partial replacement of peat with three locally available by-products—wood fiber (WF), coffee silverskin (CS), and brewers’ spent grain (BSG)—in the cultivation of potted ornamental sage through an integrated environmental–economic approach. Ten GM formulations were modeled, with peat substitutions ranging from 0 to 40% (v/v) across one hectare of greenhouse production (90,000 pots). Environmental impacts were assessed using the EPD 2018 method in SimaPro, while eco-efficiency was calculated as the ratio of the environmental impact costs resulting from the different energy consumptions (EUR) to related revenues (EUR). Results revealed only minor variations among impact categories when comparing the alternative growing media with the peat-based control (0PR), with the exception of the Abiotic Depletion of Fossil Fuels (ADff), which showed a consistent decrease at higher peat replacement levels. Treatments with 40% substitution performed best, particularly BSG40 and CS40, with the lowest eco-efficiency ratios (≈approximately 11.4%). WF40 also showed favorable outcomes (≈12.7%), confirming that a 20–40% peat replacement offers the optimal balance between environmental sustainability and economic viability. Overall, partial peat replacement using local by-products effectively reduces the consumption of fossil resources without significantly impacting other environmental indicators, promoting circularity and competitiveness in ornamental plant production. Full article

While livestock production is a significant source of greenhouse gas emissions, it remains vital for fulfilling the growing global demand for animal protein. Including by-products in ruminant diets can enhance food circularity and reduce competition for human food, while also increasing the likelihood of reducing methane (CH₄) emissions. This study aimed to evaluate the impact of fully replacing corn grain and urea in the control diet with local by-products, specifically corn distillers’ grains combined with either barley brewed grains or with wheat middlings, on enteric CH₄ emissions and performance of sheep. Diets were balanced to be isoproteic and isoenergetic with 2.6 Mcal ME/kg of dry matter (DM) and 160 g crude protein/kg DM, respectively. Corn silage is the only source of forage in the diet, and the forage-to-concentrate ratio was maintained to 60:40 on a DM basis. Twelve Highlander female sheep of 35.9 ± 3.12 kg initial body weight (BW, mean ± standard deviation), were used in a Completely Randomized Block design, with four sheep per treatment and two measurement periods under the same treatment. Experiment lasted 60 d, 30 d acclimatization and 30 d measurements. Dry matter intake (DMI) was restricted to 2.5% of BW. Enteric CH₄ emissions of individual sheep were quantified in respiration chambers over a 48 h period. Dietary treatments did not have a significant effect either on DMI or BW gain. The diet containing barley brewed grains significantly reduced total daily CH₄ production by 22.3%, CH₄ emissions per kg of DMI by 34% and energy loss as CH₄ by 38% compared to the control diet. In conclusion, the agro-industrial by-products combinations evaluated in this study effectively replaced corn grain and urea without compromising feed intake or animal performance. Additionally, the diet containing barley brewed grains significantly reduced CH₄ yield, and energy loss compared to the control diet. Full article

This study investigates the impact of steel slag coarse aggregate (SSA) particle size on the macroscopic mechanical properties of concrete. Considering that the macroscopic behavior of concrete is significantly influenced by its mesoscale structural characteristics, and that coarse aggregate particle size is a key factor determining these features, uniaxial compression experiments together with mesoscale simulations were carried out to develop a model linking the mesoscale structure to the mechanical response of steel slag coarse aggregate concrete (SSAC). The results show that SSAC exhibits a failure pattern comparable to that of natural aggregate concrete (NAC), but its stress–strain curve exhibits a steeper ascending branch and higher peak stress. With the increasing SSA replacement ratio, the peak stress continuously increases; within the same particle size range, the elastic modulus shows an initial increase followed by a subsequent decrease, reaching its maximum at a 50% replacement ratio. Expanding the particle size range changes the peak strain response from approximately linear to rapidly increasing; smaller particle sizes result in a gentler post-peak drop, whereas higher replacement ratios produce a steeper decline. The mesoscale model further shows that for SSA particle sizes of 5–20 mm, 5–15 mm, and 5–10 mm, the cohesive strength of the interfacial transition zone (ITZ) increases by 75%, 106%, and 92%, respectively, compared with NAC. Increasing the coarse aggregate volume fraction further enhances the ITZ strength improvement. This study offers valuable insights for improving the mixture design and performance of SSAC. Full article

Semi-Flexible Pavement (SFP) combines the flexibility of asphalt concrete and the rigidity of cement concrete to provide excellent high-temperature rutting resistance in the summer. However, its application is often limited by the fluidity and mechanical properties of cement-based grouting materials. This study systematically optimized the mix ratios of three types of grouting materials (cement-based, mineral-modified, and polymer-enhanced) using response surface methodology combined with orthogonal tests. The effects of water–binder ratio (W/B), sand–binder ratio (S/B), mineral admixtures and polymer additives on the key properties of grouting materials were systematically studied. By using Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD), the evolution of the mixture microstructure and the mechanism of performance change were also analyzed. The test results show that the optimal mix ratio of the cement-based grouting material is W/B = 0.46 and S/B = 0.15; the optimal mix ratio of the mineral grouting material is to replace part of the cement with fly ash (9%), silica fume (6%) and microspheres (3%). Microscopic tests show that fly ash effectively inhibits bleeding; silica fume and fly ash promote the formation of calcium silicate hydrate (C-S-H) gel; microspheres optimize the rheology of the slurry; and the synergistic effect of silica fume and microspheres reduces the internal pores of the grouting material, achieving high fluidity, low bleeding rate and excellent mechanical properties of the grouting material. The polymer-reinforced grouting material is an enhanced slurry formed by adding high-performance water reducer (0.8%), rubber powder (2%) and coupling agent (0.9%) to the optimal mineral grouting material. The combined effect of rubber powder and coupling agent significantly improves the adhesive property between the grouting material and the asphalt interface, making it more suitable for the road performance of SFP in low-temperature environments. Full article