Search Results (161)

In the Roman Empire, lead tags were used for various purposes, one of which was to label textiles that needed cleaning, repairing or dyeing. So far, these tesserae have been found at over 90 sites in 13 Roman provinces. The cities of Siscia and Carnuntum in Pannonia Superior have the highest number of finds. In 2011, a Roman cesspit was excavated in the civil city of Carnuntum and dated to the mid-2nd century CE. The latrine contained household and food waste, human faeces, pottery shards, pollen, lime, amber and 179 lead tags. The tags bear inscriptions consisting of personal names, prices, and abbreviations of terms relating to garments, colours and services such as cleaning, mending, repairing, fulling, fumigating, perfuming, dyeing, and redyeing. The findings of Roman textiles unearthed in Carnuntum are too degraded to allow a successful dye analysis to be carried out. Therefore, the inscriptions are important sources for drawing conclusions about dyeing materials and techniques. This information was supplemented by ancient written sources as well as archaeobotanical finds of dye plants and dye analyses of archaeological textiles found in Central Europe dating from the same period or earlier. Full article

Air pollution poses significant risks to built heritage, yet traditional methods for diagnosing degradation patterns remain largely fragmented, often relying on isolated data streams and/or subjective comparative interpretations. This study proposes a novel modular workflow that integrates Raman spectroscopy and micro-XRF spectrometry data with user-defined contextual metadata to automate the characterisation of pollution-induced degradation layers on monuments. This method utilises algorithms for peak detection, dimensionality reduction, unsupervised machine learning clustering, variance analysis across centroids, and correlation analysis, as well as steps for data re-encoding and visualisation of the results, allowing for scalable and reproducible analyses on heterogeneous multidimensional datasets. Applied to case studies from Athens, Piraeus, and Eleusis, Greece, the workflow successfully identified pollution sources and degradation patterns, while also quantifying the contribution of features, including contextual variables such as surface orientation and sampling height. The results validate the method’s capacity to combine molecular and elemental data streams, to enhance interpretive clarity, and to minimise manual effort and subjectivity. This work showcases the potential of algorithmic approaches in cultural heritage diagnostics to adapt dynamically and incorporate additional datasets and informs future applications of automated methods in the broader field of heritage science. Full article

The Rotunda in Thessaloniki, Greece, preserves in its interior a magnificent wall mosaic assemblage of unique inspiration and beauty. Thirty-six (36) glass tesserae, blue, green, yellow, brown, black, gold and silver in color, were examined for the first time via UV-Vis reflectance spectroscopy, scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and X-ray diffraction (XRD) analysis, in order to investigate the base glass composition, and their technological and morphological features. Despite the heterogeneity observed in the glass composition, the results indicated similarities with other Early Christian and Byzantine wall mosaics in the use of colorants, opacifiers and decolorizers. Cobalt, copper, iron and manganese along with lead and tin compounds are responsible for the blue, green, yellow, brown and black colors. Tin-based opacifiers and bone ash contribute to the glass opacity. The use of different glass recipes and opacifiers in the Rotunda’s assemblage reflects the transition from the Roman glass tradition to the Byzantine glass production of the fourth and the fifth century in the eastern Mediterranean. Full article

This is the second of the Dyes in History and Archaeology series of conference papers to be published as a Special Issue of Heritage; as before, its focus is on the use of dyes extracted from naturally occurring sources or early synthetic dyes [...] Full article

The creation of the LitUCA lithotheque represents a significant methodological advance in geoarchaeological research in the southwest of Spain. This article presents a systematic framework for the conservation, documentation, and digital integration of lithic collections, with particular emphasis on data traceability, reproducibility, and interoperability. The methodology adopted is inspired by international standards, adapted to the regional context, and incorporates rigorous protocols for sampling, analytical documentation, and a relational database system. The collection comprises over 5000 items, all of which are catalogued, photographed, and characterised both petrographically and morphometrically, with metadata being progressively aligned with FAIR principles, aiming for full compliance in the future. Preliminary analysis demonstrates the collection’s capacity to facilitate comparative studies of procurement, mobility, and lithic technological organisation. Furthermore, the digital infrastructure developed promotes remote access and fosters both academic and societal collaboration. Despite ongoing challenges regarding sample representativeness and interoperability, LitUCA stands as a scalable and versatile model for the management of lithotheques. This study highlights the importance of integrated lithotheques for scientific progress, heritage management, and interdisciplinary education. Full article

This paper focuses on the study of the arena wall decoration in the amphitheater at the archaeological site of Viminacium. The architectural characteristics of the amphitheater, along with the spectacle iconography, have made this finding one of the most interesting discoveries at Viminacium, as well as in a wider context. A multidisciplinary approach that included an iconographic and archaeological study, as well as Energy Dispersive X-ray Fluorescence (EDXRF), X-ray Powder Diffraction (XRD), and Raman and Fourier-transform Infrared (FTIR) spectroscopy analysis, was applied to determine the palette of the pigments used for the arena wall decoration and understand the iconography and its context in more detail. Among the commonly used earth pigments (yellow, red, brown, and green colors), copper-based pigments (green and blue Egyptian blue), and the most precious ones for the period—namely, cinnabar and lapis lazuli—were identified. The applied analytical techniques enabled a tentative suggestion of the origin of the raw materials of some of the pigments that were used, such as marine sediments or rocks from different destinations. Due to the fact that the Viminacium amphitheater constitutes a typical example of a provincial building reserved for public spectacles, the results of this study will significantly contribute to our understanding of the function of the amphitheaters in the Danubian region, as well as throughout the Roman world. Full article

Museums may acquire archaeological artefacts discovered by non-specialists or amateur archaeologists, holding the potential to promote the safeguarding of cultural heritage by integrating the local community in their activities. However, this also creates an opportunity for the fraudulent sale of modern forgeries presented as archaeological artefacts, resulting in the need for a critical assessment of the artefact’s authenticity prior to acquisition by the museum. In 2019, the regional museum in Cáceres (Spain) was offered the opportunity to acquire a Phoenician-Punic head pendant, allegedly discovered in the vicinity of the city. The artefact’s authenticity was assessed by traditional approaches, including typological analysis and analysis of manufacture technique, which raised doubts about its purported age. VP-SEM-EDS analysis of the chemical composition of the different glass portions comprising the pendant was used for non-invasive determination of glassmaking recipes, enabling the identification of glass components incompatible with known Iron Age glassmaking recipes from the Mediterranean. Further comparison with historical and modern glassmaking recipes allowed for the identification of the artefact as a recent forgery made from glasses employing modern colouring and opacifying techniques. Full article

The great megalithic sites reveal an extended use of their monuments. In Late Prehistory, in Protohistory, and even in historical times, dolmens remained visible references on the landscape and were central for navigating it. The megaliths of Menga, Viera, and Romeral provide quality data to confirm their continued relevance. Our aim here is to understand whether menhirs also played that role, using the area of Tierras de Antequera, which is connected to the sea, as a case study. With that goal in mind, a research project has been initiated through intensive archaeological field surveying, combined with the collection of testimonies from oral tradition and other archaeological tools such as GIS, geophysical prospection, photogrammetry and RTI, for the detection of engravings and paintings on some of the located landmarks. We present in this paper the first geological analyses in the megalithic territory of Antequera to determine the raw material of the menhirs that are studied and the geological outcrops from which they come. Full article

This review synthesizes the corpus of archaeometric and analytical investigations focused on mortar-based materials, including wall paintings, plasters, and concrete, in the Roman Regio X and neighboring territories of northeastern Italy from the mid-1970s to the present. Organized into three principal categories—wall paintings and pigments, structural and foundational mortars, and flooring preparations—the analysis highlights the main methodological advances and progress in petrographic microscopy, mineralogical analysis, and mechanical testing of ancient mortars. Despite extensive case studies, the review identifies a critical need for systematic, statistically robust, and chronologically anchored datasets to fully reconstruct socio-economic and technological landscapes of this provincial region. This work offers a programmatic research agenda aimed at bridging current gaps and fostering integrated understandings of ancient construction technologies in northern Italy. The full forms of the abbreviations used throughout the text to describe the analytical equipment are provided at the end of the document in the “Abbreviations” section. Full article

Considering the increasing requirements for the recovery of different natural and industrial waste materials, the application of volcanic ash as an alternative sustainable binder to traditionally employed lime and cement is proposed for soil stabilization for geotechnical engineering purposes, thus providing a reduction in carbon emissions. Soil stabilization was performed on natural clays with very high swelling potential, i.e. those classified as inadequate for reuse as a building material for geotechnical purposes. A mineralogical and chemical characterization of raw materials was carried out prior to the performance of different geotechnical laboratory tests, i.e., testing Atterberg limits, compaction, swelling potential, compressibility and resistance parameters over naturally remolded clay and soil mixtures with different binders. The swelling potential was reduced with an increase in the amount of applied binder, necessitating the addition of 10, 20, and 30% of volcanic ash compared to 3% lime, 3% cement and 5% lime, respectively, for a similar reduction in swelling potential. An investigation of the resistance parameters for soil mixture specimens that provided a suitable reduction in swelling potential for their reuse was performed, and a comparison to the parameters of naturally remolded clay was made. Full article

In this study, a chemometrics-assisted calibration method was developed for the Z-903 SciAps handheld Laser-Induced Breakdown Spectroscopy (h-LIBS) device. For this purpose, seventeen silica-based standard samples with known chemical composition were collected, pelleted, and analyzed using h-LIBS. Spectral data were pre-processed using a Whittaker filter and normalized via Standard Normal Variate (SNV). The dataset was divided into calibration and validation sets using the Kennard–Stone algorithm. Partial Least Square (PLS) regression was employed for multivariate regression analysis, and a variable selection method (i.e., Variable Importance in Projection, VIP) was applied to reduce the number of predictors. Results from the PLS-VIP approach demonstrated that this device is suitable for the quantitative measurement of nineteen chemical elements, including major and minor elements, achieving significant R² values for major elements including Na (R² = 0.91), Mg (R² = 0.95), and Si (R² = 0.89). The limits of detection reached are satisfying, being, for example, 0.24%, 0.41%, 0.43%, 1.5%, and 1.7% for Na, Al, Ca, Si, and Fe, respectively, among major elements, and 189 ppm, 165 ppm, 203 ppm, and 1 ppm for Ba, Cu, Mn, and Rb, respectively, among minor elements. Uncertainties in prediction of the element concentrations were compared with data from the literature, and the effect of another baseline pretreatment algorithm, airPLS (adaptive iteratively reweighted PLS), was also tested. The method was then applied to nine silica-based artifacts of different typologies sampled from the Archaeological Park of Tindari (Italy), including bricks from the theatre, archaeological glasses, and volcanic rocks. Full article

Laboratory magnetoplasmas can become an intriguing experimental environment for fundamental studies relevant to nuclear astrophysics processes. Theoretical predictions indicate that the ionization state of isotopes within the plasma can significantly alter their lifetimes, potentially due to nuclear and atomic mechanisms such as bound-state β-decay. However, only limited experimental evidence on this phenomenon has been collected. PANDORA (Plasmas for Astrophysics, Nuclear Decay Observations, and Radiation for Archaeometry) is a novel facility which proposes to investigate nuclear decays in high-energy-density plasmas mimicking some properties of stellar nucleosynthesis sites (Big Bang Nucleosynthesis, s-process nucleosynthesis, role of CosmoChronometers, etc.). This paper focuses on the case of ⁷Be electron capture (EC) decay into ⁷Li, since its in-plasma decay rate has garnered considerable attention, particularly concerning the unresolved Cosmological Lithium Problem and solar neutrino physics. Numerical simulations were conducted to assess the feasibility of this possible lifetime measurement in the plasma of PANDORA. Both the ionization and atomic excitation of the ⁷Be isotopes in a He buffer Electron Cyclotron Resonance (ECR) plasma within PANDORA were explored via numerical modelling in a kind of “virtual experiment” providing the expected in-plasma EC decay rate. Since the decay of ⁷Be provides γ-rays at 477.6 keV from the ⁷Li excited state, Monte-Carlo GEANT4 simulations were performed to determine the γ-detection efficiency by the HPGe detectors array of the PANDORA setup. Finally, the sensitivity of the measurement was evaluated through a virtual experimental run, starting from the simulated plasma-dependent γ-rate maps. These results indicate that laboratory ECR plasmas in compact traps provide suitable environments for β-decay studies of ⁷Be, with the estimated duration of experimental runs required to reach 3σ significance level being few hours, which prospectively makes PANDORA a powerful tool to investigate the decay rate under different thermodynamic conditions and related charge state distributions. Full article

Towards the bioremediation of toxic compounds from aquatic environments using living microalgae, Chlorella vulgaris has emerged as a promising candidate for the removal of heavy metals. The present study advances the scale-up of the microalga’s culture and investigates its efficiency in multi-metal removal (Cu, Cd, Ni, Pb, and Zn at 1 ppm each). Two aeration conditions were investigated: standard/conventional aeration (SA), and an innovative, custom-built micro-bubble aeration (MBA), which optimizes CO₂ residence time to enhance photosynthesis. Conducted in a pilot-scale 30 L photobioreactor (PBR) over a cultivation period of 7 days, control and multi-metal treated cultures were monitored for pH, cell population growth, and pigment content. Heavy metal removal efficiency was evaluated by means of atomic absorption spectroscopy (AAS) on Days 3 and 7 of cultivation. The comparative results reveal that MBA significantly enhances both the population and the photosynthetic pigment content of the cultures. Furthermore, the heavy metal removal efficiency under MBA reached up to 95% even by Day 3 of cultivation, remarkably higher than the 67% of the SA treated culture. These findings not only demonstrate Chlorella vulgaris’s effectiveness in multi-metal treated systems but also highlight the potential of advanced aeration systems to enhance bioremediation efficiency in larger-scale aquatic environments. Full article

This paper presents the results of an archaeometric investigation of the preparatory mortars of the pebble pavements of the Basilica of St. Leucio in Canosa di Puglia (Bari, Southern Italy). The main aim of the presented study is to contribute to the dating of some portions of the pebble pavements by analyzing the preparatory layers and determining whether they pertain to the basilica (6^th century CE) or to the pre-existing temple (2^nd century BCE–4^th century CE). Further purposes are to provide information about the production technologies of the mortars and to identify the nature of the pigments found on some pebbles. In order to contribute to the dating studies of the floors, complicated by previous reuse and restoration, 12 samples of mortars, sometimes including pebbles, were collected in different areas of the site. They were analyzed by polarized light microscopy (PLM), X-ray diffractometry (XRPD), X-ray fluorescence spectroscopy (XRF), and scanning electron microscopy coupled with an energy-dispersive spectrometer (SEM-EDS). The results allowed us to advance chronological data on different pavement areas, to deepen our knowledge on mortar production, in terms of both raw materials and technology, and to identify red ochre as the pigment with which the pavement surface was painted. Full article

This article presents the first results of the zooarchaeological analysis of Chalcolithic levels of the Barrio del Castillo site (Torrejón de Ardoz), located within the Aldovea complex, which also contains evidence from other prehistoric periods. The Barrio del Castillo sector reveals an occupation pattern characterized by pit and silo fields, a common phenomenon in the Tagus Middle Valley’s Prehistory. This study focuses on the Chalcolithic phase, which exhibits two types of faunal accumulations: one linked to domestic activities (referred to as domestic assemblages), and another with a more symbolic character, involving the burial of articulated or semi-articulated animals, mainly dogs, designated as ritual deposits. The first type of accumulation is dominated by domestic species like caprines (sheep and goats) and cattle. Other domestic species, like pigs and dogs, alongside wild species, like horses and deer, appear in smaller quantities. On the other hand, ritual deposits are largely dominated by dogs in the Chalcolithic phase. This paper emphasizes the marked contrast between the two types of accumulations, domestic and ritual, and highlights the implications that these might have toward a better understanding of the world of the first metallurgical communities of the inner Iberian Peninsula. Full article