Applications of Polymer Materials in Energy Storage

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: 31 May 2024 | Viewed by 2093

Special Issue Editor


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Guest Editor
School of Chemistry and Materials Science, Hebei University, Baoding, China
Interests: metal-ion batteries; functional materials; energy storage and conversion; desalination

Special Issue Information

Dear Colleagues,

As human life gradually enters a new era of intelligence, the demand for energy has also greatly increased. Energy storage and conversion technology is an important research topic in the task of meeting energy demand. Polymer materials have been widely used in various fields, such as electrochemical energy storage (capacitors and batteries) and green energy (thermal and mechanical), due to their inherent low cost and high processability. These rich functionalities are achieved through active electrochemical, dielectric, piezoelectric, and pyroelectric properties, which can be tuned by different structural and morphological features of high molecular weight polymers. This Special Issue aims to collect research articles on the synthesis, characterization, and application of various polymer material systems, including polymer-based electrode materials, polymer-based electrolytes, composites of dielectric polymers, and other materials, etc.

Dr. Liubin Wang
Guest Editor

Manuscript Submission Information

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Keywords

  • energy storage
  • energy conversion
  • electrode materials
  • dielectric
  • ferroelectric polymers

Published Papers (2 papers)

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Research

13 pages, 5834 KiB  
Article
Analysis of the Impact of Electrochemical Properties of Copper-Doped Electrode Membranes on the Output Force of Biomimetic Artificial Muscles
by Yingxin Ji, Keyi Wang and Gang Zhao
Polymers 2023, 15(21), 4214; https://doi.org/10.3390/polym15214214 - 25 Oct 2023
Viewed by 829
Abstract
In this study, a biomimetic artificial muscle electroactive actuator was fabricated using environmentally friendly sodium alginate extract. Ultrasonic agitation was employed to embed ultrafine copper powder within a mesh-like structure formed by multi-walled carbon nanotubes (MWCNTs), aimed at reducing the internal resistance of [...] Read more.
In this study, a biomimetic artificial muscle electroactive actuator was fabricated using environmentally friendly sodium alginate extract. Ultrasonic agitation was employed to embed ultrafine copper powder within a mesh-like structure formed by multi-walled carbon nanotubes (MWCNTs), aimed at reducing the internal resistance of the composite electrode membrane and enhancing its output force performance. Focused gallium ion beam-scanning electron microscopy observations, energy-dispersive X-ray spectroscopy (EDS) analysis, and surface morphology imaging confirmed the successful incorporation of the ultrafine copper powder into the MWCNT network. Additionally, we designed and constructed an output force measurement apparatus to assess the output performance of biomimetic artificial muscles (BMAMs) doped with varying quantities of ultrafine copper powder. Electrochemical testing results demonstrated that the artificial muscles exhibited optimal performance when doped with a mass of 1.5 g, yielding a maximum output force of 6.96 mN, an output force density of 30.64 mN/g, and a peak average rate of 0.059 mN/s. These values represented improvements of 224%, 189%, and 222% compared to the electrode membrane without the addition of ultrafine copper powder, respectively. Full article
(This article belongs to the Special Issue Applications of Polymer Materials in Energy Storage)
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12 pages, 2346 KiB  
Article
One-Dimensional Croconate-Based Fe-CP as a High-Performance Anode Material for Lithium–Ion Batteries
by Lin Zhang, Xiaofei Zhang and Yingcai Gui
Polymers 2023, 15(18), 3728; https://doi.org/10.3390/polym15183728 - 11 Sep 2023
Viewed by 816
Abstract
Coordination polymers (CPs) have attracted greater scientific attention as promising electrode materials for lithium–ion batteries (LIBs) due to their diverse and versatile structural chemistry. This study introduces a croconate-based one-dimensional CP, namely [Fe(C5O5)(H2O)3]n) [...] Read more.
Coordination polymers (CPs) have attracted greater scientific attention as promising electrode materials for lithium–ion batteries (LIBs) due to their diverse and versatile structural chemistry. This study introduces a croconate-based one-dimensional CP, namely [Fe(C5O5)(H2O)3]n) (referred to as Fe-CP), as an efficient anode material with high-performance characteristics for rechargeable LIBs. The ligand with abundant redox sites coordinating to the transition metal ion endowed the anode material with a remarkable stability in the electrolyte, in addition to high capacity, high-rate capability, and high cycling performance during charging/discharging process. The Fe-CP has a unique chain-based supramolecular structure, setting it apart from other porous three-dimensional molecular materials. The presence of unrestricted channels between the chains facilitates the diffusion of lithium ions in this unique structure. When tested at 100 mA g−1 over a range of voltages between 0.01 and 2.4 V, the Fe-CP anode demonstrated a noteworthy specific capacity of 521 mA h g−1 over 140 cycles. Moreover, the Fe-CP anode material exhibited excellent rate performance and demonstrated favorable cyclability. Following exposure to high charging and discharging rates of 2 A g−1, the anode ultimately regained its initial capability when the current rate was back at 100 mA g−1. Full article
(This article belongs to the Special Issue Applications of Polymer Materials in Energy Storage)
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