Challenges of Groundwater Quality Degradation in the Past Decades: Clues from Water–Minerals Interaction, 2nd Edition

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Environmental Mineralogy and Biogeochemistry".

Deadline for manuscript submissions: 31 December 2025 | Viewed by 238

Special Issue Editors


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Guest Editor
School of Environmental Studies and State Key Laboratory of Biogeological Geology and Environmental Geology, China University of Geosciences, Wuhan 430000, China
Interests: groundwater hydrology and biogeochemistry; karst water resources and karst environment; contaminant hydrogeology; groundwater contamination remediation
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Guest Editor
School of Environmental Studies and State Key Laboratory of Biogeological Geology and Environmental Geology, China University of Geosciences, Wuhan 430000, China
Interests: primary inferior groundwater; groundwater hydrogeochemistry and biogeochemistry; karst water resources
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Groundwater is essential globally for human consumption, habitat maintenance, human society development, and the functioning of ecosystems. As a resource, groundwater is gaining increasing importance, especially in arid/semi-arid regions where surface waters are very scarce or absent. However, in the past few decades, with the rapid increase in population, the vigorous development of socioeconomy, and the growing number of abandoned coal mines worldwide, especially the continuous emergence of legacy issues such as acid mine drainage, the degradation of groundwater quality has been accelerating at an alarming rate and posing a major health risk for many people worldwide. Essentially, groundwater quality is largely a function of mineral composition, the formation of which results in water–mineral interaction. Many professionals believe that sharing knowledge and experiences of water–mineral interaction that controls groundwater quality degradation is an effective strategy to identify and promote optimal approaches to the assessment, development and management of groundwater resources.

A very successful Special Issue of Minerals, “Challenges of Groundwater Quality Degradation in the Past Decades: Clues from Water–Minerals Interaction”, explored novel methodologies for assessing groundwater quality pollution, including hydrochemical analysis, isotope studies, and statistical approaches like PCA. These studies provided valuable insights into the water–rock interactions contributing to groundwater quality deterioration in carbonate formations under urbanization impacts. Building on these findings, we invite submissions to a second volume on the same topic. In light of the changing environment of the past few decades (e.g., global climatic changes, changes in land use patterns, and the growing global demand for clean energy, especially with the depletion of coal resources leading to the closure of coal mines) and the rapid emergence of geochemical innovations (e.g., multi-isotopes, modeling and big data analysis), the current edition investigates innovative approaches, water–rock–gas interactions, and microbial mediated geochemical processes for groundwater quality deterioration in aquifers, especially those affected by coal mining. Water pollution treatment technologies are also welcomed. By addressing these fundamental scientific questions and applied environmental challenges, this Special Issue aims to present a comprehensive and up-to-data collection of research on groundwater quality degradation.

Prof. Dr. Xubo Gao
Prof. Dr. Chengcheng Li
Prof. Dr. Qianqian Yu
Guest Editors

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Keywords

  • water–mineral interaction
  • groundwater
  • coal-mine water
  • environmental biogeochemistry

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Research

24 pages, 2430 KiB  
Article
Mechanisms and Genesis of Acidic Goaf Water in Abandoned Coal Mines: Insights from Mine Water–Surrounding Rock Interaction
by Zhanhui Wu, Xubo Gao, Chengcheng Li, Hucheng Huang, Xuefeng Bai, Lihong Zheng, Wanpeng Shi, Jiaxin Han, Ting Tan, Siyuan Chen, Siyuan Ma, Siyu Li, Mengyun Zhu and Jiale Li
Minerals 2025, 15(7), 753; https://doi.org/10.3390/min15070753 (registering DOI) - 18 Jul 2025
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Abstract
The formation of acidic goaf water in abandoned coal mines poses significant environmental threats, especially in karst regions where the risk of groundwater contamination is heightened. This study investigates the geochemical processes responsible for the generation of acidic water through batch and column [...] Read more.
The formation of acidic goaf water in abandoned coal mines poses significant environmental threats, especially in karst regions where the risk of groundwater contamination is heightened. This study investigates the geochemical processes responsible for the generation of acidic water through batch and column leaching experiments using coal mine surrounding rocks (CMSR) from Yangquan, China. The coal-bearing strata, primarily composed of sandstone, mudstone, shale, and limestone, contain high concentrations of pyrite (up to 12.26 wt%), which oxidizes to produce sulfuric acid, leading to a drastic reduction in pH (approximately 2.5) and the mobilization of toxic elements. The CMSR samples exhibit elevated levels of arsenic (11.0 mg/kg to 18.1 mg/kg), lead (69.5 mg/kg to 113.5 mg/kg), and cadmium (0.6 mg/kg to 2.6 mg/kg), all of which exceed natural crustal averages and present significant contamination risks. The fluorine content varies widely (106.1 mg/kg to 1885 mg/kg), with the highest concentrations found in sandstone. Sequential extraction analyses indicate that over 80% of fluorine is bound in residual phases, which limits its immediate release but poses long-term leaching hazards. The leaching experiments reveal a three-stage release mechanism: first, the initial oxidation of sulfides rapidly lowers the pH (to between 2.35 and 2.80), dissolving heavy metals and fluorides; second, slower weathering of aluminosilicates and adsorption by iron and aluminum hydroxides reduce the concentrations of dissolved elements; and third, concentrations stabilize as adsorption and slow silicate weathering regulate the long-term release of contaminants. The resulting acidic goaf water contains extremely high levels of metals (with aluminum at 191.4 mg/L and iron at 412.0 mg/L), which severely threaten groundwater, particularly in karst areas where rapid cross-layer contamination can occur. These findings provide crucial insights into the processes that drive the acidity of goaf water and the release of contaminants, which can aid in the development of effective mitigation strategies for abandoned mines. Targeted management is essential to safeguard water resources and ecological health in regions affected by mining activities. Full article
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