Recent Developments in Medium and High Manganese Steels

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metal Casting, Forming and Heat Treatment".

Deadline for manuscript submissions: closed (31 January 2022) | Viewed by 26883

Special Issue Editor

NRCAN-RNCAN, Natural Resources Canada, Hamilton, ON, Canada
Interests: AHSS development; thermomechanical processing; structure/properties modelling

Special Issue Information

Dear Colleagues,

Manganese steels have been continuously studied since the publication of an article entitled, “Hadfield’s Patent Manganese Steel” in the 8 February 1884 edition of “The Engineer”. Incredibly, 136 years on, few areas of physical metallurgy still generate as much excitement and activity as the study of medium and high manganese steels. The current wave of interest began in the mid-1990s/early 2000s, triggered by the development of cold-rolled 2G and later 3G sheets to meet more stringent automotive weight reduction and crash resistance requirements. Some of the new alloys have already found their way into the automotive marketplace; many others are close to commercial production. A multitude of other, non-automotive, applications is also being enthusiastically pursued. These include shape memory alloys, steels for ballistic protection, cryogenic containers, medical stents, tank cars, slurry pipes, alloys for additive manufacturing, etc.

This Special Issue is intended to provide a broad forum for the latest results in the physical metallurgy of these fascinating steels. This includes fundamental questions regarding phase transformations and strain hardening mechanisms such as the relative importance of mechanical twinning and DSA in TWIP steels, and the factors governing the nucleation, growth and stability of austenite islands in TRIP alloys. Strain partitioning, size effects, extended Lüders plateaus and the origin of negative strain rate sensitivities are all crucial aspects that require much better understanding. Fracture properties and especially the sensitivity to hydrogen embrittlement are equally important subjects for research. Contributions on these and other topics related to the processing, testing, characterization and applications of modern manganese steels are invited.

Dr. Colin Scott
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Metals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Manganese steels
  • Alloy design
  • Strain hardening mechanisms
  • Phase transformations
  • Mechanical properties

Published Papers (10 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Editorial

Jump to: Research, Review

3 pages, 162 KiB  
Editorial
Recent Developments in Medium and High Manganese Steels
by Colin P. Scott
Metals 2022, 12(5), 743; https://doi.org/10.3390/met12050743 - 27 Apr 2022
Cited by 2 | Viewed by 1653
Abstract
A huge amount of intellectual effort is currently being devoted to the study of medium and high manganese steels due to the diverse and impressive mechanical properties that can be achieved with these steels [...] Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)

Research

Jump to: Editorial, Review

20 pages, 9493 KiB  
Article
Effect of Intercritical Annealing Parameters and Starting Microstructure on the Microstructural Evolution and Mechanical Properties of a Medium-Mn Third Generation Advanced High Strength Steel
by Kazi M. H. Bhadhon, Xiang Wang, Elizabeth A. McNally and Joseph R. McDermid
Metals 2022, 12(2), 356; https://doi.org/10.3390/met12020356 - 18 Feb 2022
Cited by 10 | Viewed by 2426
Abstract
A prototype medium-Mn TRIP steel (0.2 C–6 Mn–1.7 Si–0.4 Al–0.5 Cr (wt %)) with a cold-rolled tempered martensite (CR) and martensitic (M) starting microstructures was subjected to continuous galvanizing line (CGL) compatible heat treatments. It was found that the M starting microstructures achieved [...] Read more.
A prototype medium-Mn TRIP steel (0.2 C–6 Mn–1.7 Si–0.4 Al–0.5 Cr (wt %)) with a cold-rolled tempered martensite (CR) and martensitic (M) starting microstructures was subjected to continuous galvanizing line (CGL) compatible heat treatments. It was found that the M starting microstructures achieved greater than 0.30 volume fraction of retained austenite and target 3G properties (UTS × TE ≥ 24,000 MPa%) using an intercritical annealing temperature (IAT) of 675 °C with an IA holding time of 60–360 s, whereas the CR microstructure required an IAT of 710 °C and annealing times of 360 s or greater to achieve comparable fractions of retained austenite and target 3G properties. This was attributed to the rapid austenite reversion kinetics for the M starting microstructures and rapid C partitioning from the C supersaturated martensite, providing chemical and mechanical stability to the retained austenite, thereby allowing for a gradual deformation-induced transformation of retained austenite to martensite—the TRIP effect—and the formation of nano-scale planar faults in the retained austenite (TWIP effect), such that a high work-hardening rate was maintained to elongation of greater than 0.20. Overall, it was concluded that the prototype steel with the M starting microstructure is a promising candidate for CGL processing for 3G AHSS properties. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

15 pages, 3725 KiB  
Article
Study on High-Temperature Mechanical Properties of Fe–Mn–C–Al TWIP/TRIP Steel
by Guangkai Yang, Changling Zhuang, Changrong Li, Fangjie Lan and Hanjie Yao
Metals 2021, 11(5), 821; https://doi.org/10.3390/met11050821 - 18 May 2021
Cited by 8 | Viewed by 1851
Abstract
In this study, high-temperature tensile tests were carried out on a Gleeble-3500 thermal simulator under a strain rate of ε = 1 × 10−3 s−1 in the temperature range of 600–1310 °C. The hot deformation process of Fe–15.3Mn–0.58C–2.3Al TWIP/TRIP at different [...] Read more.
In this study, high-temperature tensile tests were carried out on a Gleeble-3500 thermal simulator under a strain rate of ε = 1 × 10−3 s−1 in the temperature range of 600–1310 °C. The hot deformation process of Fe–15.3Mn–0.58C–2.3Al TWIP/TRIP at different temperatures was studied. In the whole tested temperature range, the reduction of area ranged from 47.3 to 89.4% and reached the maximum value of 89.4% at 1275 °C. Assuming that 60% reduction of area is relative ductility trough, the high-temperature ductility trough was from 1275 °C to the melting point temperature, the medium-temperature ductility trough was 1000–1250 °C, and the low-temperature ductility trough was around 600 °C. The phase transformation process of the steel was analyzed by Thermo-Calc thermodynamics software. It was found that ferrite transformation occurred at 646 °C, and the austenite was softened by a small amount of ferrite, resulting in the reduction of thermoplastic and formation of the low-temperature ductility trough. However, the small difference in thermoplasticity in the low-temperature ductility trough was attributed to the small amount of ferrite and the low transformation temperature of ferrite. The tensile fracture at different temperatures was characterized by means of optical microscopy and scanning electron microscopy. It was found that there were Al2O3, AlN, MnO, and MnS(Se) impurities in the fracture. The abnormal points of thermoplasticity showed that the inclusions had a significant effect on the high-temperature mechanical properties. The results of EBSD local orientation difference analysis showed that the temperature range with good plasticity was around 1275 °C. Under large deformation extent, the phase difference in the internal position of the grain was larger than that in the grain boundary. The defect density in the grain was large, and the high dislocation density was the main deformation mechanism in the high-temperature tensile process. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

17 pages, 3795 KiB  
Article
Temperature Effects on Tensile Deformation Behavior of a Medium Manganese TRIP Steel and a Quenched and Partitioned Steel
by Whitney A. Poling, Emmanuel De Moor, John G. Speer and Kip O. Findley
Metals 2021, 11(2), 375; https://doi.org/10.3390/met11020375 - 23 Feb 2021
Cited by 15 | Viewed by 2506
Abstract
Third-generation advanced high-strength steels (AHSS) containing metastable retained austenite are being developed for the structural components of vehicles to reduce vehicle weight and improve crash performance. The goal of this work was to compare the effect of temperature on austenite stability and tensile [...] Read more.
Third-generation advanced high-strength steels (AHSS) containing metastable retained austenite are being developed for the structural components of vehicles to reduce vehicle weight and improve crash performance. The goal of this work was to compare the effect of temperature on austenite stability and tensile mechanical properties of two steels, a quenched and partitioned (Q&P) steel with a martensite and retained austenite microstructure, and a medium manganese transformation-induced plasticity (TRIP) steel with a ferrite and retained austenite microstructure. Quasi-static tensile tests were performed at temperatures between −10 and 85 °C for the Q&P steel (0.28C-2.56Mn-1.56Si in wt.%), and between −10 and 115 °C for the medium manganese TRIP steel (0.14C-7.14Mn-0.23Si in wt.%). X-ray diffraction measurements as a function of strain were performed from interrupted tensile tests at all test temperatures. For the medium manganese TRIP steel, austenite stability increased significantly, serrated flow behavior changed, and tensile strength and elongation changed significantly with increasing temperature. For the Q&P steel, flow stress was mostly insensitive to temperature, uniform elongation decreased with increasing temperature, and austenite stability increased with increasing temperature. The Olson–Cohen model for the austenite-to-martensite transformation as a function of strain showed good agreement for the medium manganese TRIP steel data and fit most of the Q&P steel data above 1% strain. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Graphical abstract

18 pages, 15513 KiB  
Article
Effect of Processing Parameters on Mechanical Properties of Deformed and Partitioned (D&P) Medium Mn Steels
by Chengpeng Huang and Mingxin Huang
Metals 2021, 11(2), 356; https://doi.org/10.3390/met11020356 - 20 Feb 2021
Cited by 6 | Viewed by 2240
Abstract
Deformed and partitioned (D&P) medium Mn steels exhibiting high strength, large ductility, and excellent fracture toughness have been developed recently. The ultra-high dislocation density and transformation-induced plasticity (TRIP) effect are the main mechanisms for their exceptional mechanical properties. The simple processing route to [...] Read more.
Deformed and partitioned (D&P) medium Mn steels exhibiting high strength, large ductility, and excellent fracture toughness have been developed recently. The ultra-high dislocation density and transformation-induced plasticity (TRIP) effect are the main mechanisms for their exceptional mechanical properties. The simple processing route to manufacturing D&P steel makes it promising for large-scale industrial applications. However, the exact effect of each processing step on the final mechanical properties of D&P steel is not yet fully understood. In the present work, the effects of processing parameters on the mechanical properties of D&P steels are systematically investigated. The evolution of microstructure, tensile behavior and austenite fraction of warm rolled samples and D&P samples are revealed. Two D&P steels, with and without the intercritical annealing process, are both produced for comparison. It is revealed that the intercritical annealing process plays an insignificant role to the mechanical properties of D&P steel. The partitioning process is extremely important for obtaining large uniform elongation via slow but sustaining strain hardening by the TRIP effect in the partitioned austenite. The cold rolling process is also significant for acquiring high strength, and the cold rolling thickness reduction (CRTR) is extremely critical for the strength–ductility synergy of D&P steels. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

15 pages, 4750 KiB  
Article
Effect of Niobium on Inclusions in Fe-Mn-C-Al Twinning-Induced Plasticity Steel
by Fangjie Lan, Wenhui Du, Changling Zhuang and Changrong Li
Metals 2021, 11(1), 83; https://doi.org/10.3390/met11010083 - 03 Jan 2021
Cited by 8 | Viewed by 1981
Abstract
The effect of Nb addition on the composition, morphology, quantity, and size of inclusions in Fe-Mn-C-Al steel was studied by SEM, EDS, and thermodynamic analysis. The research shows that the number of inclusions in Fe-Mn-C-Al high manganese steel decreases obviously after adding 0.04% [...] Read more.
The effect of Nb addition on the composition, morphology, quantity, and size of inclusions in Fe-Mn-C-Al steel was studied by SEM, EDS, and thermodynamic analysis. The research shows that the number of inclusions in Fe-Mn-C-Al high manganese steel decreases obviously after adding 0.04% element Nb, and some inclusions in the steel evolve into complex niobium inclusions. When the niobium content increases to 0.08%, the influence of niobium on inclusions in steel becomes more obvious. The precipitation temperature of inclusions in Fe-Mn-C-Al steel was analyzed by thermodynamics. The results show that the nucleation core of the composite inclusions is AlN, and then NbC and MnS precipitate locally on its surface. With the increase of Nb, the amount and volume fraction of NbC inclusions precipitated in steel increase. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

14 pages, 9430 KiB  
Article
Microstructural Influence on Mechanical Properties of a Lightweight Ultrahigh Strength Fe-18Mn-10Al-0.9C-5Ni (wt%) Steel
by Michael Piston, Laura Bartlett, Krista R. Limmer and Daniel M. Field
Metals 2020, 10(10), 1305; https://doi.org/10.3390/met10101305 - 29 Sep 2020
Cited by 9 | Viewed by 2389
Abstract
This study evaluates the role of thermomechanical processing and heat treatment on the microstructure and mechanical properties of a hot rolled, annealed, and aged Fe-18Mn-10Al-0.9C-5Ni (wt%) steel. The steel exhibited rapid age hardening kinetics when aged in the temperature range of 500–600 °C [...] Read more.
This study evaluates the role of thermomechanical processing and heat treatment on the microstructure and mechanical properties of a hot rolled, annealed, and aged Fe-18Mn-10Al-0.9C-5Ni (wt%) steel. The steel exhibited rapid age hardening kinetics when aged in the temperature range of 500–600 °C for up to 50 h, which has been shown in other work to be the result of B2 ordering in the ferrite and κ-carbide precipitation within the austenite matrix. The ultimate tensile strength increased from 1120 MPa in the annealed condition to 1230 MPa after 2 h of aging at 570 °C. Charpy V-notch toughness was evaluated at −40 °C in sub-sized specimens with a maximum in the annealed and quenched condition of 28.5 J in the L-T orientation. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

13 pages, 3339 KiB  
Article
The Influence of Specimen Geometry and Strain Rate on the Portevin-Le Chatelier Effect and Fracture in an Austenitic FeMnC TWIP Steel
by Jidong Kang, Liting Shi, Jie Liang, Babak Shalchi-Amirkhiz and Colin Scott
Metals 2020, 10(9), 1201; https://doi.org/10.3390/met10091201 - 08 Sep 2020
Cited by 4 | Viewed by 2238
Abstract
We studied the Portevin-Le Chatelier effect and fracture behavior of a FeMnC TWIP steel using high speed digital image correlation by varying the specimen geometry (flat vs. round) and test strain rate (0.001 vs. 0.1 s−1). The results show that the [...] Read more.
We studied the Portevin-Le Chatelier effect and fracture behavior of a FeMnC TWIP steel using high speed digital image correlation by varying the specimen geometry (flat vs. round) and test strain rate (0.001 vs. 0.1 s−1). The results show that the mean flow stress, the mean strain hardening rate and the mean strain rate sensitivity parameters are all independent of the specimen geometry and are uncorrelated with the presence or not of Portevin-Le Chatelier (PLC) bands, the type of PLC bands observed or the critical strain for band formation. However, both the fracture strains and stresses and the PLC behavior are highly geometry and/or strain rate dependent. Dynamic strain aging (DSA) and in particular the presence of PLC instabilities appears to play an important but as yet unclear role in promoting premature necking and final fracture. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

15 pages, 4823 KiB  
Article
On Mechanical Properties of Welded Joint in Novel High-Mn Cryogenic Steel in Terms of Microstructural Evolution and Solute Segregation
by Jia-Kuan Ren, Qi-Yuan Chen, Jun Chen and Zhen-Yu Liu
Metals 2020, 10(4), 478; https://doi.org/10.3390/met10040478 - 04 Apr 2020
Cited by 10 | Viewed by 3405
Abstract
There is a growing demand for high-manganese wide heavy steel plate with excellent welding performance for liquefied natural gas (LNG) tank building. However, studies on welding of high-Mn austenitic steel have mainly focused on the applications of automotive industry for a long time. [...] Read more.
There is a growing demand for high-manganese wide heavy steel plate with excellent welding performance for liquefied natural gas (LNG) tank building. However, studies on welding of high-Mn austenitic steel have mainly focused on the applications of automotive industry for a long time. In the present work, a high-Mn cryogenic steel was welded by multi-pass Shielded Metal Arc Welding (SMAW), and the microstructural evolution, solute segregation and its effect on the properties of welded joint (WJ) were studied. The yield strength, tensile strength and elongation of the WJ reached 804 MPa, 1027 MPa and 11.2% at −196 °C, respectively. The elongation of WJ was reduced with respect to the BM due to the poorer strain hardening capacity of weld metal (WM) at −196 °C. The WM and coarse-grained heat affected zone (CGHAZ) had the lowest cryogenic impact absorbed energy of ~55 J (at −196 °C). The inhibited twin formation caused by the higher critical resolved shear twinning stress ( τ T ) in the C-Mn-Si segregation band, the inhomogeneous microstructure caused by solute segregation, and the hardened austenite matrix deteriorated the plastic deformation capacity, finally resulting in the decreased cryogenic impact toughness of the CGHAZ. To summarize, the cryogenic toughness and tensile properties of the WJ meet the requirements for LNG tank building. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

Review

Jump to: Editorial, Research

23 pages, 7539 KiB  
Review
Hydrogen Embrittlement of Medium Mn Steels
by Lawrence Cho, Yuran Kong, John G. Speer and Kip O. Findley
Metals 2021, 11(2), 358; https://doi.org/10.3390/met11020358 - 20 Feb 2021
Cited by 17 | Viewed by 4561
Abstract
Recent research efforts to develop advanced–/ultrahigh–strength medium-Mn steels have led to the development of a variety of alloying concepts, thermo-mechanical processing routes, and microstructural variants for these steel grades. However, certain grades of advanced–/ultrahigh–strength steels (A/UHSS) are known to be highly susceptible to [...] Read more.
Recent research efforts to develop advanced–/ultrahigh–strength medium-Mn steels have led to the development of a variety of alloying concepts, thermo-mechanical processing routes, and microstructural variants for these steel grades. However, certain grades of advanced–/ultrahigh–strength steels (A/UHSS) are known to be highly susceptible to hydrogen embrittlement, due to their high strength levels. Hydrogen embrittlement characteristics of medium–Mn steels are less understood compared to other classes of A/UHSS, such as high Mn twinning–induced plasticity steel, because of the relatively short history of the development of this steel class and the complex nature of multiphase, fine-grained microstructures that are present in medium–Mn steels. The motivation of this paper is to review the current understanding of the hydrogen embrittlement characteristics of medium or intermediate Mn (4 to 15 wt pct) multiphase steels and to address various alloying and processing strategies that are available to enhance the hydrogen-resistance of these steel grades. Full article
(This article belongs to the Special Issue Recent Developments in Medium and High Manganese Steels)
Show Figures

Figure 1

Back to TopTop