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Materials

Materials is an international peer-reviewed, open access journal on materials science and engineering published semimonthly online by MDPI. The Spanish Materials Society (SOCIEMAT), Manufacturing Engineering Society (MES) and Chinese Society of Micro-Nano Technology (CSMNT) are affiliated with Materials and their members receive discounts on the article processing charges.

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All Articles (58,383)

  • Article
  • Open Access

ReaxFF molecular dynamics was used to examine oxygen–carbon bonding and carbon network reconstruction of pristine C60, monovacancy C59, and two specific C58 vacancy configurations at 1600-2800 K. Oxidation and oxygen-free conditions each used three independent trajectories and 200 ps production periods. At 2800 K and nominal oxygen loading of 0.5, the normalized C–O bond order sums were 0.04075 ± 0.03532 for V2-adj and 0.17501 ± 0.04520 for V2-sep. Their initial C–C retention fractions were 0.9617 ± 0.0397 and 0.6231 ± 0.1279, respectively. These late-stage differences persisted across bond order thresholds of 0.30–0.40. Matched oxygen-free controls showed substantial thermal reconstruction, especially for V1, demonstrating that connectivity replacement cannot generally be attributed to oxygen attack. The V2-sep mean was 7.85% below an additive two-V1 bonding benchmark, but the difference was smaller than its propagated sampling uncertainty. The results concern the selected configurations and parametrization, whose initial coordination environments differ; they do not establish universal vacancy separation effects or real soot oxidation kinetics.

Materials

22 October 2026

Schematic representations of the initial fullerene nanocage models and vacancy topologies used in the simulations. The red dashed boxes highlight the vacancy sites, and the open circles indicate the original positions of the removed carbon atoms.
  • Article
  • Open Access

In this paper, the effects of rotating magnetic field (RMF) excitation current intensity on Sn segregation, grain refinement, and mechanical properties of Cu-6Ni-6Sn alloy were systematically investigated. The results demonstrate that the application of RMF can effectively refine the as-cast microstructure and mitigate Sn macro-segregation. The average grain size of the as-cast Cu-6Ni-6Sn alloy decreases monotonously with the increase in the excitation current, from 1563 ± 502 μm at 0 A to 207 ± 112 μm at 120 A. In addition, it was found that the difference in Sn content in the radial direction of the ingot reduced from 3.9 wt.% to 1.0 wt.%. The RMF improves heat transfer through forced convection, reduces temperature gradients and alleviates solute enrichment. It increases both thermal undercooling and the growth restriction factor to hinder grain growth and reduces constitutional undercooling to suppress segregation. In addition, the application of the RMF can synergistically increase the tensile strength and the elongation of the as-cast Cu-6Ni-6Sn alloy, with the values changing from 349 ± 4 MPa and 36.9 ± 0.8% at 0 A to 413 ± 4 MPa and 42.8 ± 0.9% at 80 A, respectively. This work quantitatively reveals the coupling relationship between RMF excitation current, grain refinement degree and Sn macro-segregation homogenization in Cu-6Ni-6Sn alloy, and quantitatively clarifies the dominant grain-boundary strengthening mechanism of the alloy under RMF.

Materials

21 October 2026

Schematic diagram of the alloy preparation process.
  • Review
  • Open Access

In Al–Cu–Mg–Ag sheets considered for aircraft skins, forming and aging alter the state relevant to subsequent fatigue and fracture. Favorable precipitation and tensile responses alone do not establish retention of a specified fracture or fatigue property. This critical narrative review evaluates composition and inherited state, deformation–aging sequence, and separately defined damage endpoints. Documented supplementary searches and evidence mapping support the authors’ engineering and scientific assessment. Chemistry and thermal history jointly control competing precipitates; a smaller Ω volume fraction can coexist with higher yield strength, while resistance to stable tearing can decrease after thermal exposure even when yield strength changes little. Responses to small tensile prestrain, rolling, loading during aging and warm compression depend on the initial state and intervention timing. Tear tests, three-dimensional damage observations, fatigue-life distributions and fatigue-crack-growth measurements reveal distinct roles for particles, boundaries, texture and initiation sites. Cross-over alloys offer bounded comparisons of forming–hardening strategies. The synthesis identifies controls for comparing complete processing routes and locating susceptible regions. Process-retained damage tolerance provides a reporting framework that preserves absolute performance alongside relative change and distinguishes mechanism identification from route optimization. Future work should connect mapped local histories to matched crack endpoints and representative curved structures.

Materials

21 October 2026

Measured strength and tear initiation across four composition–treatment states [31]. (a) Yield strength (YS); (b) Kahn unit initiation energy (UIE), defined as energy to maximum tear load divided by initial ligament area; (c) measured Cu/Mg/Ag contents and thermal schedules. The category labels denote nominal Mg contents, not a continuous single-variable experiment. All sheets were 1.6 mm thick, water quenched, pre-stretched by 2%, and peak-aged at 160 °C; the homogenization, solution temperature, and peak-aging time covary. The reproduced graphical error bars have unreported statistical definitions and specimen counts, and are not assigned standard deviation (SD), standard error (SE), or confidence interval (CI) meanings. Extraction details are in Methods S1. UIE is not KIC; source-model quantities are separated in Table S2. Possible baseline overlap with [44] is retained in the source records.
  • Article
  • Open Access

The production of pretensioned concrete elements is significantly influenced by the ability to achieve required bond stress values shortly after the element is formed, which is essential for transferring prestressing force. Due to the complex testing procedure, bond strength is not directly measured in practice. Instead, decisions regarding the transfer of prestressing force to the concrete element are based on the tested compressive strength (typically 30–35 MPa). The literature contains studies and guidelines that define bond strength in normal concretes (generally dependent on the compressive strength of the concrete). Such relationships are lacking for lightweight aggregate concretes (LWAC). CEM I 52.5R is the most commonly used type of cement for prestressed concrete elements due to its rapid strength development. However, concrete with CEM II/A-V 52.5R-NA is characterized by better workability and a lower carbon footprint. This paper presents the results of experimental studies on the bond strength of LWAC made with artificial Certyd aggregate and cement CEM II/A-V 52.5R-NA. The obtained results were compared with results from similar previous studies on LWAC using cement CEM I 52.5R. The analysis encompassed bond stress–slip curves and the correlation between bond strength and free-end slip after 3 and 28 days of curing. The tests conducted and the final analysis of the test results pointed out that Certyd lightweight aggregate concrete made with a concrete mixture with cement type CEM I 52.5R, as well as with cement type CEM II/A-V 52.5R-NA, is appropriate for pretensioned concrete members.

Materials

21 October 2026

The arrangement of the prestressing steel strand within the individual molds for the test specimens [17].

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Materials - ISSN 1996-1944