Silica Aerogel: Synthesis, Properties and Characterization

A special issue of Gels (ISSN 2310-2861). This special issue belongs to the section "Gel Analysis and Characterization".

Deadline for manuscript submissions: 31 October 2025 | Viewed by 1254

Special Issue Editor


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Guest Editor
College of Energy Environment and Safety Engineering, China Jiliang University, Hangzhou 310018, China
Interests: silica aerogels; combustion behavior; high performance insulation materials; fire protection; safety management
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Special Issue Information

Dear Colleagues,

Silica aerogel is a highly porous and lightweight material known for its exceptional thermal insulation and unique properties. The synthesis of silica aerogel typically involves sol-gel techniques, where silica particles are formed in a liquid solution and subsequently transformed into a gel state. This gel undergoes supercritical drying to remove the liquid component without collapsing the structure, resulting in an aerogel.

The properties of silica aerogel include low density, high specific surface area, and low thermal conductivity, making it an ideal candidate for various applications, ranging from insulation in buildings and aerospace to drug delivery systems and environmental remediation. The characterization of silica aerogel involves various techniques such as scanning electron microscopy (SEM) and nitrogen adsorption-desorption isotherms, which help in understanding its microstructure and porosity.

Overall, silica aerogel is a versatile material that is continuously being explored for innovative uses in numerous fields due to its unique combination of properties and performance characteristics. As research progresses, advancements in synthesis methods and material formulations are likely to enhance its applicability and functionality in real-world applications. I am thrilled to invite you, as renowned experts in the field, to contribute to this Special Issue and the development of the scientific study of silica aerogel.

Prof. Dr. Dongmei Huang
Guest Editor

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Keywords

  • silica aerogel
  • highly porous and lightweight material
  • sol-gel techniques
  • buildings and aerospace
  • drug delivery systems
  • environmental remediation

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Published Papers (2 papers)

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Research

22 pages, 8987 KiB  
Article
Microfluidic Synthesis of Magnetic Silica Aerogels for Efficient Pesticide Removal from Water
by Dana-Ionela Tudorache (Trifa), Adelina-Gabriela Niculescu, Alexandra-Cătălina Bîrcă, Denisa Alexandra Florea, Marius Rădulescu, Bogdan-Ștefan Vasile, Roxana Trușcă, Dan-Eduard Mihaiescu, Tony Hadibarata and Alexandru-Mihai Grumezescu
Gels 2025, 11(6), 463; https://doi.org/10.3390/gels11060463 - 17 Jun 2025
Cited by 1 | Viewed by 612
Abstract
Aerogels have gained much interest in the last decades due to their specific properties, such as high porosity, high surface area, and low density, which have caused them to be used in multiple and varied fields. As the applicability of aerogels is tightly [...] Read more.
Aerogels have gained much interest in the last decades due to their specific properties, such as high porosity, high surface area, and low density, which have caused them to be used in multiple and varied fields. As the applicability of aerogels is tightly correlated to their morpho-structural features, special consideration must be allocated to the fabrication method. An emerging technique for producing nanostructured materials with tailored morphology and dimensions is represented by continuous-flow microfluidics. In this context, this work explores the synergic combination of aerogel-based materials with microfluidic synthesis platforms to generate advanced nanocomposite adsorbents for water decontamination. Specifically, this study presents the novel synthesis of a magnetic silica-based aerogel using a custom-designed 3D microfluidic platform, offering enhanced control over nanoparticle incorporation and gelation compared to conventional sol–gel techniques. The resulting gel was further dried via supercritical CO2 extraction to preserve its unique nanostructure. The multi-faceted physicochemical investigations (XRD, DLS, FT-IR, RAMAN, SEM, and TEM) confirmed the material’s uniform morphology, high porosity, and surface functionalization. The HR-MS FT-ICR analysis has also demonstrated the advanced material’s adsorption capacity for various pesticides, suggesting its adequacy for further environmental applications. An exceptional 93.7% extraction efficiency was registered for triazophos, underscoring the potential of microfluidic synthesis approaches in engineering advanced, eco-friendly adsorbent materials for water decontamination of relevant organic pollutants. Full article
(This article belongs to the Special Issue Silica Aerogel: Synthesis, Properties and Characterization)
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14 pages, 3844 KiB  
Article
Ambient-Dried Silica Xerogels with Enhanced Strength and Thermal Insulation via Calcium Ion-Glycerol Synergistic Crosslinking
by Xiaoyu Xie, Zilin Zhu, Yu Meng, Lijia Wang, Fuquan Zhao, Lingqing Chen, Lijie Jiang, Ming Yan and Xiaofan Zhou
Gels 2025, 11(6), 462; https://doi.org/10.3390/gels11060462 - 16 Jun 2025
Viewed by 398
Abstract
Despite their high porosity and wide applicability, silica xerogels face mechanical strength limitations for high-performance applications. This study presents an ambient-pressure sol-gel strategy utilizing calcium-glycerol synergy to produce robust xerogels with enhanced properties. Physicochemical analyses reveal that controlled Ca2+ incorporation (optimal at [...] Read more.
Despite their high porosity and wide applicability, silica xerogels face mechanical strength limitations for high-performance applications. This study presents an ambient-pressure sol-gel strategy utilizing calcium-glycerol synergy to produce robust xerogels with enhanced properties. Physicochemical analyses reveal that controlled Ca2+ incorporation (optimal at 6 wt.%) accelerates gelation kinetics while establishing a hybrid network through ionic complexation and hydrogen bonding. The resulting xerogels achieve exceptional compressive strength (30.8 MPa) while maintaining uniform mesoporosity (50–90 nm pore size). Remarkably, the as-prepared silica xerogels demonstrate outstanding thermal insulation, maintaining a 220 °C temperature differential in 300 °C environments. These results prove that the ambient-pressure sol-gel strategy utilizing calcium-glycerol synergy can enhance the mechanical performance and thermal insulation performance of silica xerogels with the dual actions of Ca2+-induced network reinforcement via silanol coordination and glycerol-mediated stress relief during ambient drying. Overall, this work can offer a scalable, energy-efficient approach to produce high-performance silica xerogels with huge potential in building envelopes and aerospace systems. Full article
(This article belongs to the Special Issue Silica Aerogel: Synthesis, Properties and Characterization)
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