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17 pages, 7560 KiB

Open AccessArticle

A Multi-Analytical Diagnostic on an Outdoor Wall Painting: The Study on the Déesis of St. Maria Annunziata’s Church, Motta San Giovanni (Reggio Calabria, Italy)

by Giorgia Salatino, Maria Antonietta Zicarelli, Michela Ricca, Andrea Macchia, Luciana Randazzo, Paola Pogliani, Anna Arcudi, Silvestro Antonio Ruffolo and Mauro Francesco La Russa

Appl. Sci. 2023, 13(18), 10439; https://doi.org/10.3390/app131810439 - 18 Sep 2023

Cited by 3 | Viewed by 1343

Abstract

This article concerns the diagnostic campaign aimed at analyzing the mural painting representing the iconographic theme of the Deesis of the Church of St. Maria Annunziata, Motta San Giovanni, in the province of Reggio Calabria. In 1951, a flood caused the collapse of [...] Read more.

This article concerns the diagnostic campaign aimed at analyzing the mural painting representing the iconographic theme of the Deesis of the Church of St. Maria Annunziata, Motta San Giovanni, in the province of Reggio Calabria. In 1951, a flood caused the collapse of the building and the consequent breaking of the apse into two parts. The present study focused on the left side of the apse, hosting the figures of Christ and Mary, in order to plan the best conservation intervention strategy. For this purpose, non-invasive investigations and laboratory analytical methods were conducted in order to characterize the constituent materials and to identify the forms of alteration and degradation present on the surface of the painting. In particular, Raman spectroscopy, optical microscopy, scanning electron microscopy coupled to the chemical analysis by an EDS probe, Fourier-transform infrared spectroscopy and ion chromatography were employed. The results highlighted the presence of a single layer of plaster made with a lime-based binder. The chromatic palette of the painting is characterized by ochres and carbon black mixed with lime to obtain the different shades. Finally, the definition of the nature of the deposits and of the overlaid materials was fundamental in order to identify the best products and methods to restore the readability of the work. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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21 pages, 17762 KiB

Open AccessArticle

Multi-Analytical Investigation on a Renaissance Polychrome Earthenware Attributed to Giovanni Antonio Amadeo

by Vittoria Guglielmi, Chiara Andrea Lombardi, Giacomo Fiocco, Valeria Comite, Andrea Bergomi, Mattia Borelli, Monica Azzarone, Marco Malagodi, Mario Colella and Paola Fermo

Appl. Sci. 2023, 13(6), 3924; https://doi.org/10.3390/app13063924 - 20 Mar 2023

Cited by 3 | Viewed by 2069

Abstract

This research aimed to characterise pigments used to decorate a polychrome earthenware bas-relief of the 15th century entitled “Madonna with Child, Saint Catherine of Siena, and a Carthusian Prior”, attributed to Giovanni Antonio Amadeo (Pavia, 1447–Milan, 1522) and owned by the Sforzesco Castle [...] Read more.

This research aimed to characterise pigments used to decorate a polychrome earthenware bas-relief of the 15th century entitled “Madonna with Child, Saint Catherine of Siena, and a Carthusian Prior”, attributed to Giovanni Antonio Amadeo (Pavia, 1447–Milan, 1522) and owned by the Sforzesco Castle Museum of Milan. The artwork underwent a cleaning procedure whose aims were the removal of the dark coating that obscured its surface and restoration work that could bring back its original features. Before the cleaning, six microsamples were collected and analysed using optical microscopy (OM), scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDXS), and Fourier-transform infrared microspectroscopy in ATR mode (ATR-FTIR), providing the restorers with decisive information on the materials underlying the coating. After the cleaning, the terracotta appeared vibrantly coloured, mainly with bright red, blue, green, black, and white tones. Then, some in situ, non-destructive, spectroscopic measurements were performed by a portable Raman spectrometer on some of the areas that could not otherwise have been sampled. The analyses revealed the presence of natural pigments, including lead white, azurite, yellow ochre, carbon black, calcite, cinnabar, and gypsum. For Madonna’s mantle, cobalt and Prussian blue were employed. Furthermore, the presence of barium sulphate was widely evidenced on the bas-relief. Albeit cobalt blue is of synthetic origin, its presence is compatible with the 15th-century palette, whereas Prussian blue and barium sulphate could be imputed to a previous restoration. Finally, the use of true gold for the background of the earthenware attests to the artwork’s importance and value. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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14 pages, 10639 KiB

Open AccessArticle

Restoration of a Textile Artefact: A Comparison of Cleaning Procedures Applied to a Historical Tapestry from the Quirinale Palace (Rome)

by Vittoria Guglielmi, Valeria Comite, Chiara Andrea Lombardi, Andrea Bergomi, Elisabetta Boanini, Roberto Bonomi, Elisa Monfasani, Letizia Sassi, Mattia Borelli and Paola Fermo

Appl. Sci. 2023, 13(4), 2669; https://doi.org/10.3390/app13042669 - 19 Feb 2023

Cited by 2 | Viewed by 2298

Abstract

The cleaning of textile artefacts and in particular historical tapestries is generally carried out using standard methods. Different cleaning procedures, including a new method based on a hydro-aspiration mechanism, recently developed by restorers with the aim of improving the efficiency of the cleaning [...] Read more.

The cleaning of textile artefacts and in particular historical tapestries is generally carried out using standard methods. Different cleaning procedures, including a new method based on a hydro-aspiration mechanism, recently developed by restorers with the aim of improving the efficiency of the cleaning system, were applied to a historical tapestry belonging to the lower edge of one of the tapestries of the “Ulysses Stories” series exhibited at the Quirinale Palace (Rome). The tapestry was made of wool and silk and has precious decorations made of metal yarns, which are particularly fragile. The new cleaning system was compared with the traditional methods commonly used by restorers for tapestry cleaning. For this purpose, the quantity and chemical composition of the particles removed and collected on quartz fibre filters by applying the different cleaning systems, were estimated by means of analytical techniques, such as IC (Ion Chromatography) for the quantification of the ionic species collected into the rinsing water, the TOT (Thermal Optical Transmittance) method for the quantification of the carbonaceous particles and SEM-EDX (Scanning Electron Microscopy coupled to Energy Dispersive X-ray Spectroscopy) for yarn morphological characterization and elemental analysis of the deposited particles. The objective of this study is to identify the correct cleaning method to apply to the polymaterial tapestry and, in particular, to the gilded silver and gold metallic yarns, whose conservation state requires the preservation of the “self-protection” patina necessary for the future exhibition inside the Quirinale Palace. The new hydro-aspiration method was found to be more efficient in removing dirt and preserving the structure of the metallic threads being in this way less invasive in detaching the fragile surface patina and at the same time more effective in removing dirt. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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27 pages, 24352 KiB

Open AccessFeature PaperArticle

A Multi-Analytical Investigation of Liu Kang’s Colour Palette and Painting Technique from the Shanghai Period (1933–1937)

by Damian Lizun, Teresa Kurkiewicz, Bogusław Szczupak and Jarosław Rogóż

Appl. Sci. 2023, 13(4), 2414; https://doi.org/10.3390/app13042414 - 13 Feb 2023

Cited by 3 | Viewed by 2480

Abstract

This study presents the analytical characterisation of Liu Kang’s paint mixtures and the painting technique used during the important Shanghai artistic phase (1933−1937). Liu Kang (1911–2004) was a Chinese artist who received an academic art education in Shanghai (1926–1928) and Paris (1929–1932). He [...] Read more.

This study presents the analytical characterisation of Liu Kang’s paint mixtures and the painting technique used during the important Shanghai artistic phase (1933−1937). Liu Kang (1911–2004) was a Chinese artist who received an academic art education in Shanghai (1926–1928) and Paris (1929–1932). He settled permanently in Singapore in 1945 and became a leading contributor to the national art scene. This study showcases 12 paintings on canvas from the collections of the National Gallery Singapore and the Liu family. An integrated approach combined non- and micro-invasive analytical methods supplemented with archival sources and enabled characterising the investigated paint mixtures and revealing details of the artist’s painting technique. The study has proved the artist’s ability to produce a variety of hues by utilising a conventional palette of colours. The predilection for ultramarine, viridian, yellow and red iron-rich earth pigments, umber, yellow chromate pigments, as well as lead white, zinc white or Zn-base compounds like lithopone and barium white was recorded. The study emphasises a minor use of Prussian blue, emerald green, cadmium yellow or its variant and bone black. Although it remains unknown what brands of paints Liu Kang used, the available archival sources give insights into the painting materials available in Shanghai that the artist could have had at his disposal during the period under review. The archival information is based on the Chinese and overseas colourmen advertisements printed in Chinese journals and the respective contemporary colourmen catalogues. The artist’s painting technique departs from the experimental approach of his Paris phase. In Shanghai, he focused on synthesising the painting principles of the School of Paris with traditional Chinese calligraphy. The outcomes of this research may support future technical studies of works by other artists contemporary to Liu Kang and who were active in pre-war Shanghai. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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15 pages, 2228 KiB

Open AccessArticle

Impact of Environmental Factors on the Formation and Development of Biological Soil Crusts in Lime Concrete Materials of Building Facades

by Wenxuan Xiong, Yue Tao, Panpan Wang, Kaiting Wu and Lanzhou Chen

Appl. Sci. 2022, 12(6), 2974; https://doi.org/10.3390/app12062974 - 15 Mar 2022

Viewed by 2701

Abstract

Microbial colonization leads to the formation of biological soil crusts (BSCs) on the surface of architecture, which causes the deterioration of construction materials. However, little information is available on the formation of BSCs on lime concrete materials of early architecture. In this study, [...] Read more.

Microbial colonization leads to the formation of biological soil crusts (BSCs) on the surface of architecture, which causes the deterioration of construction materials. However, little information is available on the formation of BSCs on lime concrete materials of early architecture. In this study, the variances of microbial communities, physicochemical properties, and surrounding environmental factors of the lime concrete facades from the early architecture of Wuhan University were investigated. It was found that the surface of lime concrete materials was internally porous and permeable, embedded with biofilms of cyanobacteria, mosses, bacteria, and fungi. Redundancy analysis (RDA) analysis showed that the abundances of photoautotrophic microorganisms depended on light intensity and moisture content of construction materials, while that of heterotrophic microorganisms depended on total nitrogen (TN) and NO₃⁻-N content. The deposition of total carbon (TC), NH₄⁺-N, and total organic carbon (TOC) was mainly generated by photoautotrophic microorganisms. The lime concrete surface of early architecture allowed internal growth of microorganisms and excretion of metabolites, which promoted the biodeterioration of lime concrete materials. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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18 pages, 10343 KiB

Open AccessArticle

Multi-Technique Diagnostic Investigation in View of the Restoration of “The Glory of St. Barbara” Painting by Mattia Preti

by Francesco Caridi, Michela Ricca, Giuseppe Paladini, Vincenza Crupi, Domenico Majolino, Antonio Donato, Sante Guido, Giuseppe Mantella, Luciana Randazzo, Mauro Francesco La Russa and Valentina Venuti

Appl. Sci. 2022, 12(3), 1385; https://doi.org/10.3390/app12031385 - 27 Jan 2022

Cited by 4 | Viewed by 2837

Abstract

The present paper illustrates the results of a diagnostic investigation performed on the oil on canvas painting “The Glory of St. Barbara” (1680–1688) by Mattia Preti. The painting is located inside the St. Barbara Church in Taverna (Catanzaro, Italy), the city that gave [...] Read more.

The present paper illustrates the results of a diagnostic investigation performed on the oil on canvas painting “The Glory of St. Barbara” (1680–1688) by Mattia Preti. The painting is located inside the St. Barbara Church in Taverna (Catanzaro, Italy), the city that gave birth to the artist. In situ, non-invasive studies, by applying X-ray fluorescence (XRF) spectroscopy, along with laboratory micro-destructive analytical investigations, by employing electron probe microanalyses (EPMA) coupled with energy-dispersive spectrometry (EDS) and micro-Raman (µ-Raman) spectroscopy, were combined to retrieve the color palette and identify the painting technique and style of the famous master. As a result of this multi-scale characterization, an extraordinary pictorial technique was revealed, enriching knowledge about one of the oldest pictorial traditions outlined by Mattia Preti, and solving doubts still existing about many of his investigated artworks. Moreover, the achieved results represent useful and essential tools to address management issues of the artwork, by providing valuable information for planning and monitoring future restoration interventions of the canvas. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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19 pages, 6094 KiB

Open AccessArticle

Investigation of Ancient Wall Painting Fragments Discovered in the Roman Baths from Alburnus Maior by Complementary Non-Destructive Techniques

by Ioana Maria Cortea, Lucian Ratoiu, Luminița Ghervase, Ovidiu Țentea and Mihaela Dinu

Appl. Sci. 2021, 11(21), 10049; https://doi.org/10.3390/app112110049 - 27 Oct 2021

Cited by 17 | Viewed by 2976

Abstract

In this study, several wall painting fragments discovered in the Roman baths from the archeological site Alburnus Maior (Roşia Montană, Romania) were analyzed with the aim to investigate the material composition of both plasters and pictorial layers. Dated from the beginning of the [...] Read more.

In this study, several wall painting fragments discovered in the Roman baths from the archeological site Alburnus Maior (Roşia Montană, Romania) were analyzed with the aim to investigate the material composition of both plasters and pictorial layers. Dated from the beginning of the second century AD, these rare findings stand among the oldest examples of preserved decorative polychrome paintings on plaster excavated thus far in the former territory of the Roman province of Dacia. A non-destructive multi-analytical approach based on complementary techniques was considered: Fourier transform infrared (FTIR) spectroscopy, X-ray fluorescence (XRF), X-ray diffraction (XRD), UV fluorescence, and hyperspectral imaging (HSI). The obtained results highlight a common Roman color palette mainly based on naturally occurring earth pigments. Red ochre, yellow ochre, manganese-rich ochres/wads, carbon black, and calcite were identified. A traditional two-layer sequence of plasters was found—arriccio (based on lime and siliceous sands), and intonaco (pure lime). The presence of an organic protein binder, identified via FTIR analysis, and sustained by combined imaging documentation, indicates that the pigments were applied a secco. The obtained results are discussed in relation to previous published data, and they can be considered as valuable archeological indicators that contribute to the understanding of the painting techniques and the materials used in the Roman provinces. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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14 pages, 2869 KiB

Open AccessFeature PaperArticle

A Combined Non-Destructive and Micro-Destructive Approach to Solving the Forensic Problems in the Field of Cultural Heritage: Two Case Studies

by Michela Ricca, Maria F. Alberghina, Luciana Randazzo, Salvatore Schiavone, Antonio Donato, Maria P. Albanese and Mauro F. La Russa

Appl. Sci. 2021, 11(15), 6951; https://doi.org/10.3390/app11156951 - 28 Jul 2021

Cited by 14 | Viewed by 3239

Abstract

The present paper discusses the importance of non-destructive and micro-destructive technology in forensic investigations in the field of cultural heritage. Recent technological developments and the wide availability of modern analytical instrumentation are creating new possibilities for performing scientific measurements and acquiring data directly [...] Read more.

The present paper discusses the importance of non-destructive and micro-destructive technology in forensic investigations in the field of cultural heritage. Recent technological developments and the wide availability of modern analytical instrumentation are creating new possibilities for performing scientific measurements and acquiring data directly on-site—thereby limiting, where possible, sampling activity—as well as learning about the technologies and materials that were employed in the past to create cultural assets. Information on periods, chemical composition, manufacturing techniques, etc., can be gathered more easily. Overall, the benefits of on-site forensic investigations are multiple, including the potential to increase substantially the speed and efficacy of the criminal justice system. However, such benefits are only realized when data quality is guaranteed and findings can be used as forensic evidence in court. The present paper shows data from the non-destructive and micro-destructive analysis of different artworks and objects provided by the Cosenza Carabinieri Unit for the Protection of Cultural Heritage and Anti-Counterfeiting (Calabria, Italy). In particular, two oil paintings on canvas depicting cherubs (Italian: putti), recovered as fragments of larger religious artworks, and two bronze belt and helmet fragments were investigated. In the first case, the research aimed to define the original pictorial layer, identify any reconstruction pictorial areas or pictorial retouching, assess the state of conservation, reconstruct the previous conservation treatments, and provide indications about the chronology of the artworks. In the second case, analysis was performed both to define the bronze chemical composition and the origin of the soil (earth) found within the objects during their recovery. For these purposes, the analytical approach involved the use of non-destructive and micro-destructive analysis as follows: infrared reflectography (IRR), ultraviolet-induced visible fluorescence (UV), X-ray fluorescence analysis (XRF), digital optical microscopy (DOM), scanning electron microscopy equipped with EDX microanalysis (SEM-EDX), and Fourier transform infrared spectroscopy (FT-IR). The results made it possible to collect valuable diagnostic information and answer questions posed by the institutions for the resolution of various doubts about forensic science and cases concerning the seizure, recovery, or return of archaeological or historical-artistic objects of cultural interest. Full article

(This article belongs to the Special Issue Analytical Methodologies Applied to the Study of Cultural Heritage Surface II)

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