Thermo-Reversible Self-Healing Composites

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Materials Science and Engineering".

Deadline for manuscript submissions: closed (30 April 2019) | Viewed by 3009

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Netherlands Organization for Applied Scientific Research - TNO, 5656AE Eindhoven, High Tech Campus 25, The Netherlands
Interests: polymers; interfaces; phase transitions; material chemistry and physics
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Dear Colleagues,

Composite materials are increasingly employed in many areas, not only in high-tech applications but also in the energy sector, transport industry, building sector, up to the manufacturing of many objects used in daily life, mainly because of their high strength-to-weight ratio, easy formability, and relatively low costs. However, composites are subjected to internal microscopic damage occurring during the manufacturing process (i.e., caused by thermal stresses), machining (i.e., while drilling holes for bolted joints), components assembly, or, ultimately, in-service loading. The incorporation of an in-situ repair solution that can be activated after each of the above processes may efficiently reduce composite components scrappage rates and post-manufacture and other repairs and, simultaneously, increase the period of time before non-destructive testing inspection. By utilizing specific thermo-reversible (cross)-linking chemistry that can achieve multiple repair/healing cycles, any damage generated throughout a component life cycle can be repaired, and its service life extended; also, complete recycling of fibers and resins may become possible. The embedded reversible chemistry can be activated post-damage to repair the internal structure, akin to the healing processes characteristic of animals and plants. This is a real benefit to the industry because it promotes the optimization of composite manufacturing by reducing both post-manufacture inspection time and material wastage costs, while also maximizing the lifetime of the composite components in service and introducing a true recycling possibility through the recovery of the binder material system and of the reinforcing fibers.

This Special Issue of Applied Sciences on “Thermo-Reversible Self-Healing Composites” aims to attract contributions covering all areas of the subject, ranging from material system design and synthesis, to manufacturing, testing, and recycling of such systems. Papers dealing with all aspects of the topic are welcome. 

Dr. Hartmut R. Fischer
Guest Editor

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Keywords

  • recycling of composites
  • thermo-reversible chemistry
  • intrinsic self-repair of composites

Published Papers (1 paper)

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20 pages, 12311 KiB  
Article
Effect of Doping Microcapsules on Typical Electrical Performances of Self-Healing Polyethylene Insulating Composite
by Youyuan Wang, Yudong Li, Zhanxi Zhang and Yanfang Zhang
Appl. Sci. 2019, 9(15), 3039; https://doi.org/10.3390/app9153039 - 27 Jul 2019
Cited by 20 | Viewed by 2724
Abstract
Polyethylene cables, as important transmission equipment of modern power grid, would inevitably be slightly damaged, which seriously threatens the safety of the power supply. This paper has pioneered the preparation and typical performances of a self-healing polyethylene insulating composite. The self-healing performance to [...] Read more.
Polyethylene cables, as important transmission equipment of modern power grid, would inevitably be slightly damaged, which seriously threatens the safety of the power supply. This paper has pioneered the preparation and typical performances of a self-healing polyethylene insulating composite. The self-healing performance to structural damage was verified by tests of electrical and mechanical damage. The effect mechanism of doping microcapsules on the electrical performance of polyethylene was emphatically analyzed. The results show that in appropriate conditions (such as 60 °C/30 min), the composite can not only repair the electrical tree and scratches, but also restore the insulation strength of damaged area. The effect of doping microcapsules on the electrical performances of polyethylene, such as breakdown strength, volumetric resistivity, dielectric properties, and space charge characteristics, are mainly related to impurity and the interface of microcapsule. Polarization and ionization of impurities can reduce the electrical performance of polyethylene. The interface not only improves the microstructure of polyethylene (such as how the heterogeneous nucleation effect increases the number of crystal regions, and the anchoring effect enhances the stability of amorphous regions), but also increases the charge traps. Moreover, the microstructure and charge trap can affect the characteristics of carrier transport, material polarization, and space charge accumulation, thus improving the electrical performance of polyethylene. In addition, the important electrical performance of the composite can meet the basic application requirements of polyethylene insulating material, which has good application prospects. Full article
(This article belongs to the Special Issue Thermo-Reversible Self-Healing Composites)
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