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Magnetochemistry, Volume 11, Issue 5

2025 May - 10 articles

Cover Story: The reaction between LiCp* (Cp* = pentamethylcyclopentadienylide) and RECl3 (RE = Y, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) generated a series of trinuclear rare-earth cluster complexes [(Li(THF)(Et2O))(Cp*RE)3(μ-Cl)4(μ3-Cl)2(μ4-Cl)] (RE3) with coordination by capping Cp* and bridging chloro ligands. The relative disposition of the Cp* ligands has been shown to strongly affect the superexchange interactions in Gd3 and intramolecular dipolar interactions in Dy3. Furthermore, complex Dy3 behaves as a single-molecule magnet with slow magnetic relaxation under a zero DC applied field up to 23 K and an energy barrier of 125(6) cm−1. View this paper
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Articles (10)

  • Article
  • Open Access
972 Views
7 Pages

Synthesis, Structure and Magnetic Properties of Sm6−xLaxMn23 (0.5 ≤ x ≤ 4) Alloys

  • Ying-Hua Liang,
  • Zhong Zhang,
  • Jihoon Park,
  • Jia-Cheng Lyu,
  • Hong-Liang Ge,
  • Ping-Zhan Si and
  • Chul-Jin Choi

The structure and magnetic properties of Sm6−xLaxMn23 (x = 0.5, 1, 2, 3 and 4) alloys have been studied systematically. We found that the Th6Mn23-type Sm6−xLaxMn23 alloys become less stable with increasing La content, and α-Mn becom...

  • Article
  • Open Access
1,747 Views
17 Pages

Development of NiZn Ferrites Doped with Co for Low Power Losses at High Frequencies (10 MHz) and High Temperatures (>80 °C)

  • Stefanos Zaspalis,
  • Georgios Kogias,
  • Vassilios Zaspalis,
  • Eustathios Kikkinides,
  • Elisabeth Rauchenwald,
  • Christoph Vogler and
  • Kevin Ouda

Polycrystalline nickel–zinc (NiZn) ferrites are widely used in high-frequency applications due to their excellent magnetic properties such as low power losses, high magnetic permeability, and adequate saturation induction. However, data on thei...

  • Article
  • Open Access
1 Citations
2,510 Views
9 Pages

ESR and Mössbauer Spectroscopy of Iron(III) Spin Crossover Complexes Based on Pentadentate Schiff Base Ligands with Pseudohalide Coligands

  • Rene Lucka,
  • Besnik Elshani,
  • Maximilian Seydi Kilic,
  • Stephen Klimke,
  • Christoph Krüger,
  • Michael Menzel,
  • Reinhard Stößer,
  • Ján Titiš,
  • Roman Boča and
  • Franz Renz

Two iron(III) spin crossover complexes [Fe(5Cl-L)(NCS)] (1) and [Fe(5Cl-L)(NCSe)] (2) were synthesized with the pentadentate Schiff base ligand 5Cl-L and thiocyanato and selenocyanato as coligands. 5Cl-L, as an asymmetric {N3O2} donor Schiff base, wa...

  • Article
  • Open Access
2 Citations
1,455 Views
13 Pages

We have investigated for the first time the temperature, size, and ion-doping concentration dependence of the magnetic properties, band-gap energy, and specific heat of CuFeO2 in both bulk materials and nanoparticles using a microscopic model (the s-...

  • Article
  • Open Access
1 Citations
1,298 Views
9 Pages

Multifunctional Synergistic Response Induced by Phase Transition in Molecular Compounds

  • Xiao-Feng Chen,
  • Tao Wang,
  • Dan Liao,
  • Nan Wu,
  • Yan Peng,
  • Shi-Yong Zhang and
  • Zhao-Bo Hu

Two organic–inorganic materials (TMAA)2[CoCl4] (1) and (TMAA)2[MnCl4] (2) (TMAA = N,N,N-trimethyl-1-adamantylammonium hydroxide) were synthesized and characterized. It was found that both compounds exhibit first-order structural phase transitio...

  • Article
  • Open Access
2 Citations
1,266 Views
30 Pages

Design of Ricker Wavelet Neural Networks for Heat and Mass Transport in Magnetohydrodynamic Williamson Nanofluid Boundary-Layer Porous Medium Flow with Multiple Slips

  • Zeeshan Ikram Butt,
  • Muhammad Asif Zahoor Raja,
  • Iftikhar Ahmad,
  • Muhammad Shoaib,
  • Rajesh Kumar and
  • Syed Ibrar Hussain

In the current paper, an analysis of magnetohydrodynamic Williamson nanofluid boundary layer flow is presented, with multiple slips in a porous medium, using a newly designed human-brain-inspired Ricker wavelet neural network solver. The solver emplo...

  • Article
  • Open Access
1,289 Views
9 Pages

Rhenium-Induced Negative Magnetoresistance in Monolayer Graphene

  • Ying Zhang,
  • Jiali You,
  • Weiwei Li,
  • Zijie Huang,
  • Yuxiang Feng,
  • Yuyu Liu and
  • Jing Li

The impact of rhenium doping on the transport properties and electron localization in monolayer graphene was experimentally investigated. In this study, we report the emergence of unsaturated negative magnetoresistance in Re-doped graphene devices, w...

  • Article
  • Open Access
1 Citations
2,093 Views
13 Pages

Organometallic rare-earth complexes have attracted considerable attention in recent years due to their unique structures and exceptional magnetic properties. In this study, we report the synthesis and magnetic characteristics of a family of monopenta...

  • Article
  • Open Access
3 Citations
1,838 Views
16 Pages

This study focuses on understanding the bioconvection in Jeffery–Hamel (JH) flow, which has valuable applications in areas like converging dies, hydrology, and the automotive industry, which make it a topic of practical importance. This researc...

  • Article
  • Open Access
1,105 Views
12 Pages

Cationic Mismatch Effect Induced by Double Substitution on the Structural and Magnetic Properties of La0.5Ca0.5MnO3

  • Wadie Abdelhedi,
  • Akram Krichene,
  • Wahiba Boujelben and
  • Nassira Chniba-Boudjada

In this study, we aimed to induce controlled structural disorder through a double substitution approach in the La0.5Ca0.5MnO3 compound by investigating La0.5−xRexCa0.5−yAeyMnO3 compounds with x = 0.05 and 0.1 and Re = Eu, Nd, Gd, Pr, and...

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Magnetochemistry - ISSN 2312-7481