Next Article in Journal
Synthesis, Structure and Magnetic Properties of Sm6−xLaxMn23 (0.5 ≤ x ≤ 4) Alloys
Previous Article in Journal
ESR and Mössbauer Spectroscopy of Iron(III) Spin Crossover Complexes Based on Pentadentate Schiff Base Ligands with Pseudohalide Coligands
Previous Article in Special Issue
Phase Formation, Microstructure, and Permeability of Fe-Deficient Ni-Cu-Zn Ferrites (II): Effect of Oxygen Partial Pressure
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Development of NiZn Ferrites Doped with Co for Low Power Losses at High Frequencies (10 MHz) and High Temperatures (>80 °C)

by
Stefanos Zaspalis
1,*,
Georgios Kogias
2,*,
Vassilios Zaspalis
1,2,*,
Eustathios Kikkinides
1,
Elisabeth Rauchenwald
3,
Christoph Vogler
3 and
Kevin Ouda
3
1
Department of Chemical Engineering, Aristotle University of Thessaloniki, University Campus, 54124 Thessaloniki, Greece
2
Center for Research and Technology-Hellas, Chemical Process and Energy Resources Institute, Thermi, P.O. Box 60361, 57001 Thessaloniki, Greece
3
Huawei Technologies Co., Ltd., Huawei Industrial Base Bantian, Longgang, Shenzhen 518129, China
*
Authors to whom correspondence should be addressed.
Magnetochemistry 2025, 11(5), 44; https://doi.org/10.3390/magnetochemistry11050044
Submission received: 22 March 2025 / Revised: 13 May 2025 / Accepted: 15 May 2025 / Published: 17 May 2025

Abstract

:
Polycrystalline nickel–zinc (NiZn) ferrites are widely used in high-frequency applications due to their excellent magnetic properties such as low power losses, high magnetic permeability, and adequate saturation induction. However, data on their power loss behavior at 10 MHz, particularly at elevated temperatures, remain limited in the literature. This study investigates the magnetic performance of Co-doped NiZn ferrites at 10 MHz, under varying induction fields (3–10 mT) and temperatures (20–120 °C), with a focus on reducing high-temperature losses. Ferrite samples were synthesized using the conventional mixed oxide method and systematically varied in composition (Fe, Co content and Ni/Zn molar ratio). Key findings reveal that the incorporation of cobalt significantly enhances high-temperature performance by shifting resonance frequencies, attributed to increased domain wall pinning. Samples with optimized compositions and processing demonstrated power losses at 10 MHz, 10 mT and 25 °C, 100 °C and 120 °C as low as 310 mW cm−3, 1233 mW cm−3 and 1400 mW cm−3, respectively, with relative initial permeabilities exceeding 80 at these temperatures. These results provide insights into the design of high-frequency magnetic components and highlight strategies to minimize high-temperature losses.

1. Introduction

Polycrystalline nickel–zinc (NiZn) ferrites are an important family of soft magnetic materials in modern electromagnetic technology, widely used in high-frequency applications such as transformers, inductors, antennas, and noise suppressors [1]. Their exceptional magnetic properties, such as low power losses, high magnetic permeability, and sufficient saturation induction, make them ideal materials for devices operating in the megahertz range [2,3]. Their relatively high specific resistivity helps minimize eddy currents, further enhancing performance at high frequencies. The growing demand for more compact, efficient, and high-performing electronic devices is driven by the increasing switching frequencies of wide-band semiconductors [4,5]. One major limitation to device miniaturization arises from the high power losses of the ferrite materials, which, combined with their high thermal resistance, may lead to excessive heating, and consequently reduced component efficiency.
Research on the development of improved monolithic polycrystalline NiZn ferrite magnetic components for inductors and transformers spans several key directions, focusing on enhancing their properties, expanding their applications, and addressing challenges in high-frequency performance. Regarding property enhancement, primary areas of exploration include: (i) investigating the effects of additions of various substitutional or grain boundary metals ions (such as, i.e., Cu [6,7], Co [2,8,9], Sn [10], V [11], Mn [12] or rare earth elements [13]) to optimize magnetic permeability, coercivity and loss behavior. (ii) Microstructural engineering, which involves studying the impact of grain size on magnetic losses, permeability and saturation magnetization to enhance high-frequency performance [14,15]; understanding and controlling lattice defects such as dislocations and vacancies [16]; and exploring advanced sintering methods like microwave [17], spark plasma [18] or hot-pressing [19] to achieve dense, homogeneous materials with superior properties. Additionally, significant research efforts focused on analyzing and mitigating losses caused by eddy currents, hysteresis, and domain wall dynamics, particularly in the megahertz range [20,21].
Cobalt-doped NiZn ferrites have been extensively investigated, and the mechanisms through which cobalt influences magnetic performance have been the subject of several studies [20,22,23,24,25]. The materials exhibit ferrimagnetic ordering, which is characteristic of spinel ferrites, in general. The magnetic moments on A and B sites are antiparallel, but unequal in magnitude, resulting in a net magnetization. The cation site occupancy in NiZn ferrites and Co-doped NiZn ferrites has been extensively reported in the literature [26,27]. These materials typically adopt a mixed spinel structure with a certain degree of inversity. For example, in (Ni0.5Zn0.5)Fe2O4 annealed at 1100 °C, Zn2+ ions show a strong preference for tetrahedral (A) sites, while Ni2+ ions exhibit an even stronger preference for octahedral (B) sites, resulting in an inversion degree of approximately 0.5. Co2+ ions also show a strong site preference. When Co2+ is introduced into the lattice—either by partially substituting Ni2+ or as an additional dopant—it significantly alters the cation distribution, and consequently, the magnetic behavior. Co2+ ions prefer octahedral sites, primarily due to their larger crystal field stabilization energy (CFSE). This site selectivity also causes a redistribution of Fe3+ ions toward the A-sites to maintain charge neutrality and site balance. It is important to note that, although the general trends in site preferences remain consistent, the exact cation site occupation fractions are influenced by the synthesis method and processing conditions, such as annealing temperature and particle or grain size [28]. Most research on Co-doped NiZn ferrites has focused on particles and structures in the submicron range [29], primarily in the context of developing materials for microwave, non-reciprocal devices or antenna applications. In such cases, dielectric losses and permittivity are properties of significant importance. For power applications, even at frequencies of 10 MHz, the key performance parameters are power losses, initial permeability, and the frequency stability of the permeability. This distinction also explains the lower cobalt content used in this study, which is significantly less than that reported in most previous works [22,23,24]. Higher cobalt concentrations, while increasing coercivity, also raise hysteresis losses and reduce initial permeability to levels unsuitable for power applications.
In addition, most investigations into power losses have not extended the frequency range beyond 5 MHz. To the authors’ knowledge, data on NiZn ferrite power losses (expressed as mW cm−3) at 10 MHz is scarcely available in the scientific literature. In this article, the magnetic performance of Co-doped NiZn ferrites at 10 MHz is investigated under fields ranging from 3 to 10 mT and at temperatures from 20 to 120 °C. The dependence on compositional and operational parameters is discussed. Emphasis is placed on high-temperature (>80 °C) losses, and certain strategies for mitigating these losses are proposed.

2. Materials and Methods

Polycrystalline NiZn ferrites were synthesized using the conventional mixed oxide method. Oxide precursors of the cations (NiO, ZnO, Co3O4, Fe2O3, all Merck analytical grade) were proportioned for a synthesis batch of approximately 500 g and subsequently wet-mixed for 3 h in a ball mill containing 500 mL double-distilled water and approximately 3.6 kg of steel milling balls with a nominal diameter of 12 mm. The mixed product was dried and pre-fired at 750 °C for 3 h in air. The pre-fired powder was then ball-milled under the same conditions as the wet-mixing step. The milled powder was roll-granulated with the addition of 10 wt.% of a binder solution, consisting of 2 wt.% aqueous Tylose solution (Tylose MH 300 P2 Shin Etsu, Venlo, the Netherlands). The granulated powder was subsequently uniaxially compacted at a pressure of 100 MPa, to form ring-shaped specimens with an outer diameter of 23 mm and an inner diameter of 15 mm. These specimens were finally sintered in air at temperature ranging between 1125 and 1225 °C. The sintered specimens had a nominal outer diameter of 20 mm, an inner diameter of 12.5 mm and a height of 8 mm. The synthesized ferrite compositions, divided into three groups (A, B and C) are listed in Table 1.
In the synthesis experiments of group A, the effect of varying iron content was studied while keeping the cobalt, nickel and zinc contents constant. The Ni/Zn molar ratio was maintained at 1 to achieve high saturation induction and magnetic permeability [2]. Additionally, a cobalt content of 0.02 atoms per formula unit was introduced because, as reported, this content significantly increases the specific resistivity of NiZn ferrites [12] and retards domain wall or ferromagnetic resonance [20,30]. In group B experiments, the cobalt content was varied at a constant iron content (equal to 1.95 iron atoms per formula unit) and Ni/Zn ratio (equal to 1). The cobalt was increased in steps of 2000 ppm (wt.) CoO (or approximately 0.06 cobalt atoms per formula unit) from 0.02 up to 0.052 cobalt atoms per formula unit. Higher cobalt contents resulted to an unacceptable increase in the high-frequency power losses and are, therefore, not studied further. Finally, in group C, the effect of the Ni/Zn molar ratio was investigated while maintaining constant iron (equal to 1.95 iron atoms per formula unit) and cobalt (equal to 0.040 cobalt atoms per formula unit) contents. Specimens A195/B020 and B040/C100 have a double code name since they can be encountered as members of two experimental series.
The microstructure of the sintered polycrystalline specimens was examined using a scanning electron microscope (SEM, JEOL JSM-IT500, Tokyo, Japan) on thermally etched and gold-sputtered cross sections. Particle size analyses and specific surface area measurements of pre-fired and milled powders were performed using laser scattering (Mastersizer S, Malvern, UK) and nitrogen adsorption–desorption (Autosorb 1, Quantachrome, Boynton Beach, FL, USA), respectively. X-ray diffraction (XRD) was conducted for structural determination using CuKa radiation (Bruker D8 Advance, Munich, Germany). The final densities of the sintered specimens were measured geometrically. Based on repeated measurements, the absolute error was estimated to be ±0.05 g cm−3.
The magnetic properties of the specimens were measured using an automated programmable unit consisting of: an impedance-gain analyzer (E4991A, Agilent Technologies Inc., Kobe, Japan), an oscilloscope (MDO4034C, Tektronix Inc., Beaverton, OR, USA), a power amplifier (2200L, Electronics and Innovation, Rochester, NY, USA), a frequency generator (33500B, Keysight, Santa Rosa, CA, USA) and a programmable oven. The measurements were performed on toroidal specimens wound with copper wires to form inductors. The power losses were measured directly from the alternating voltage across the winding, the in-phase component of the current (complex permeability) and the specimen volume. Sinusoidal magnetic field is applied to the ferrite material, and the resulting voltage and current waveforms are measured. The waveforms are then multiplied together to obtain the instantaneous power loss at each point in the cycle. The average power loss is then calculated by integrating the instantaneous power over a complete cycle. For each sintering trial, four identical specimens were stacked and sintered simultaneously. The two specimens in the middle were used for magnetic performance characterization. The results were very reproducible, with a relative error of less than 5%, even under the heaviest conditions of 10 MHz and 10 mT.

3. Results and Discussion

All prefired and milled powders of group A syntheses were characterized to ensure identical structure, providing a common starting point for the sintering and microstructure development steps without the influence of factors other than chemical composition. Indicative particle size analysis results for prefired and -milled powders A192, A195 and A198 are presented in Figure 1. In all cases, a bimodal particle size distribution was observed, with an average particle size d50 ranging between 0.4 and 0.5 μm. The differences between the powders are considered negligible and within the experimental uncertainties. The BET specific surface areas of all group A syntheses range from 3.0 to 3.5 m2 g−1.
XRD analysis revealed that all prefired and milled powders consisted of a single spinel phase. Representative results for powder samples A192 and A198 are shown in Figure 2.
The prefiring temperature of 750 °C appears sufficient to drive the ferrite formation reaction almost to completion. Minor, barely detectable traces of Fe2O3 (marked with black cycles in Figure 2) are not considered significant and are unlikely to influence the subsequent microstructure development or magnetic performance. It is therefore concluded that all prefired powders in group A are structurally nearly identical.
In Figure 3 the final densities of all group A syntheses sintered at different temperatures (from 1125 to 1225 °C) are presented. As expected, the final density increases with higher sintering temperatures. Furthermore, at a constant sintering temperature, the final density decreases with increasing iron content. Iron deficiency introduces oxygen vacancies in the structure which, in turn, facilitate the diffusion of oxygen anions. In ionic solids, the diffusion of the slowest-moving oxygen ions is generally regarded as the rate-controlling step for densification [31,32]. Most commercially available NiZn ferrites are iron-deficient to enhance densification.
For optimal high-frequency magnetic performance, both density and grain size are critical factors. In polycrystalline materials, grain size significantly affects both domain wall and spin rotational resonance [33,34]. During sintering, densification and grain growth occur simultaneously [35], and the microstructure for optimal high-frequency magnetic performance should exhibit sufficiently high density and sufficiently low grain size. Figure 4 shows typical SEM images. Figure 4a–d correspond to a constant composition (A195) at different sintering temperatures, while Figure 4e–h correspond to a constant sintering temperature (1175 °C) with varying compositions.
Although the effect of sintering temperature on the microstructure is evident in the SEM images (Figure 4a–d), the influence of iron content on the density and microstructure is not clearly visible. The same is true also for specimens of group B, where at an identical sintering temperature of 1150 °C, the microstructure did not seem to be affected by the cobalt content. The obtained SEM micrographs were similar to those presented in Figure 4e–h, and are therefore not presented. In general, at sintering temperatures below 1200 °C the average grain size is estimated to be below 3 μm, which lies within the monodomain region [14,36].
The power losses at 10 MHz and 100 °C for relatively high (10 mT) and low (3 mT) fields are shown in Figure 5.
As shown, the lowest power losses are achieved with iron contents lower than 1.95 and sintering temperatures between 1150 and 1175 °C. Lower sintering temperatures result in higher losses due to insufficient densification, while at higher sintering temperatures, the 10 MHz losses increase due to larger grain sizes. Power losses also increase with iron contents higher than 1.95. This could be explained either by the fact that high iron contents are associated with lower densities (Figure 3) or by the fact that higher iron contents lead to higher magnetic permeabilities, which in turn lower the resonance frequency, as described by the law of Snoek [37]. In particular, specimen A195 ((Ni0.49Zn0.49Co0.02)Fe1.95O4) sintered at 1175 °C exhibited power losses of 40 mW cm−3 (10 MHz, 3 mT, 100 °C) and 2100 mW cm−3 (10 MHz, 10 mT, 100 °C). Based on this superior high-frequency high-temperature performance, and its relatively high iron content, further optimization was conducted based on this composition at sintering temperatures of 1150 °C and 1175 °C.
In Figure 6, the 10 MHz power losses of specimen A195 (sintered at 1175 °C) are shown as a function of temperature, for different induction levels. At low temperatures, the power losses are initially independent of temperature. Beyond a certain temperature, however, a sharp increase in losses with temperature is observed. It is believed that in the temperature-independent region, hysteresis losses dominate. The sharp increase in losses at higher temperatures is most likely dominated due to resonance phenomena, as it is unlikely that eddy currents play a significant role in NiZn ferrites. The DC-specific resistivity of specimen A195 was found to be ~105 Ω m at 25 °C, which is considered quite high in order to induce appreciable amounts of eddy current losses. Additionally, the temperature at which power losses begin to increase depends on the applied field. At 3 mT, the losses remain constant up to 100 °C, whereas at 10 mT, the losses start to increase at approximately 60 °C.
The previous considerations suggest that any further reduction in high-temperature losses should focus on increasing the resonance frequency. Cobalt is a well-known ion with a relatively high positive contribution to the magnetocrystalline anisotropy of the host lattice [2]. Additionally, cobalt has been reported to enhance domain wall pinning, thereby hindering their movement [8,20].
In Figure 7, the final densities of group B samples are shown for the two sintering temperatures tested in the laboratory, 1150 and 1175 °C. The observed pattern is identical for both sintering temperatures. At cobalt contents up to 0.034 ions per formula unit, the densification appears to be slightly retarded, whereas at higher cobalt contents, enhanced densification is observed. Representative SEM images for the two sintering temperatures are included as insets in Figure 7. No microstructural differences were visually detected either between the samples with varying cobalt content or between chemically identical specimens sintered at the two different temperatures. The high-frequency power losses of the samples sintered at 1150 °C were superior to those sintered at 1175 °C. This enhanced densification is likely associated with grain growth, which is not visually detectable, but is sufficient to negatively affect the 10 MHz power losses. Consequently, the results reported in the following paragraphs for group B samples refer exclusively to a sintering temperature of 1150 °C.
Figure 8 shows the 10 MHz power losses as a function of temperature for group B specimens with gradually increasing cobalt content.
In general, cobalt stabilizes the temperature dependence of the power losses. This is likely due to shift in resonance to higher frequencies, as will be described in a subsequent paragraph. At an induction field of 10 mT (Figure 8a), the low-temperature losses, attributed to hysteresis, increase with increasing cobalt content, while the losses at temperatures above 80 °C decrease significantly. For instance, at 10 MHz, 10 mT and 100 °C, specimen A195/B020 exhibited power losses of 2100 mW cm−3, while specimen B040 1233 mW cm−3 exhibited an approximate decrease of 41%. A similar reduction is observed at 120 °C, where losses decrease by 57% between specimens A195/B020 (4072 mW cm−3) and B046 (1751 mW cm−3). As shown in Figure 8b, the beneficial effect of cobalt on reducing high-frequency, high-temperatures losses weakens at lower fields. This is because at lower fields, the temperature range over which hysteresis losses dominate is broader (Figure 6), and these losses increase with higher cobalt content.
The initial magnetic permeabilities and the saturation magnetic flux densities are shown in Figure 9.
The permeabilities, in all cases, increased with increasing temperature. Furthermore, it appears that permeability decreases with increasing cobalt content. However, it is challenging to attribute this effect solely to the presence of cobalt since the counteracting effect of density is also included in these results. On the other hand, the saturation flux density seems to increase with cobalt content up to a level of 0.046 cobalt ions per formula unit, beyond which it decreases. As reported in the literature [26,27,28], the strong preference of Co2+ ions for octahedral (B) sites leads to a broader cation redistribution, including the migration of Fe3+ ions from octahedral to tetrahedral (A) sites. At higher levels of redistribution, the Fe3+ distribution becomes the dominant factor influencing the magnetic properties. As the Co2+ doping concentration increases, the occupancy of Fe3+ ions on the A-sites also increases. At a certain Co2+ concentration, the magnetic moment of the A-sublattice becomes sufficiently large to reduce the net magnetic moment of the material. This behavior explains the observed trend in the saturation induction of the group B specimens, as shown in Figure 9b.
Another approach to increasing the resonance frequency involves varying the Ni/Zn molar ratio, which was maintained equal to 1 in all group A and B specimens. It is known that increasing the Ni/Zn ratio raises the magnetocrystalline anisotropy constant while reducing the saturation flux density and initial magnetic permeability [2]. Consequently, the resonance frequency is expected to shift to higher frequencies, leading to reduced high-frequency losses. The decision to vary the Ni/Zn ratio from 1 to higher values was made for specimen B040/C100. This specimen was selected because it exhibited the lowest losses at 100 °C, sufficiently low losses at 120 °C and acceptable magnetic permeabilities and saturation flux densities. Based on this rationale, group C syntheses were developed.
The final sintered densities of group C specimens are shown in Figure 10. The initial increase in the Ni/Zn ratio to 1.18 results in higher densities, while a further increase shows a tendency toward lower densities. SEM investigations did not reveal any clearly distinguishable differences in the microstructures.
The 10 MHz power losses as a function of temperature are shown in Figure 11. The advantage of a higher Ni/Zn ratio becomes evident only at the relatively high field of 10 mT. Achieved power losses at 120 °C with specimen C118 were 1400 mW cm−3, which are lower than the corresponding values of all group B specimens reported earlier (Figure 8). Under low fields of 3 mT (Figure 11b), the specimen B040 remains superior in terms of power losses.
The initial magnetic permeabilities and saturation flux densities of group C specimens are shown in Figure 12.
The magnetic permeabilities clearly decrease with increasing Ni/Zn ratio, as predicted by the theory of antiferromagnetism [2]. However, this trend is not entirely followed by the saturation flux density, which increases significantly when the Ni/Zn ratio varies from 1 to 1.18, beyond which it decreases, as expected. The saturation flux density that physically represents the resultant magnetic moment per unit volume, appears to be influenced by the density more than the initial permeability. Despite the higher Ni/Zn ratio, the permeability of specimen C118 is higher than that of specimen B040 due to its higher density (Figure 10). At comparable densities, however, the permeability decreases, as the Ni/Zn ratio becomes the determining factor.
Power losses in ferrites are generally categorized into hysteresis losses (Ph), eddy current losses (Pe) and residual losses (Pr). The identification of loss sources relies on their distinct frequency dependencies: per cycle, hysteresis losses remain independent of frequency, eddy current losses increase linearly with frequency, and residual losses exhibit an even stronger frequency-dependent growth [38]. Figure 13 illustrates the power losses per cycle as a function of frequency for specimen A195/B020 across three temperatures, highlighting these trends.
The power losses per cycle remain independent of frequency up to approximately 6 MHz, beyond which they increase significantly. This frequency-independent portion corresponds to hysteresis losses. At higher frequencies, losses exceeding the hysteresis level are attributed to eddy current and residual losses, collectively referred to as Pe + Pr. Differentiating the linear and exponential components graphically is challenging, but it is believed that most of these losses result from resonance effects. Additionally, the threshold frequency at which losses begin to rise decreases with temperature, shifting from approximately 8 MHz at 25 °C to about 6 MHz at 120 °C. Spin rotational resonance is proportional to saturation magnetization, which diminishes as temperature increases [37]. Furthermore, higher temperatures reduce domain wall stiffness and pinning effects [38], leading to a decrease in domain wall resonance. At 10 MHz and 120 °C, resonance accounts for over 70% of the observed losses.
Consequently, the sharp increase in 10 MHz losses with temperature, as shown in Figure 6, is attributed to the same mechanism: resonance effects. The temperature at which losses significantly rise is strongly influenced by the applied field. It is unlikely that the rotational resonance frequency decreases with increasing field strength [37,39]. Instead, the primary explanation is that domain wall resonance, the dominant loss-generating mechanism, becomes more pronounced as the applied field reduces the effectiveness of domain wall pinning. Similar effects have been observed in [8] at 1.5 MHz, where losses were linked to the inefficiency of pinning induced by cobalt.
The introduction of cobalt to NiZn ferrites significantly impacts their magnetic performance, with effects similar to those observed in MnZn ferrites [8,20,40,41]. At lower frequencies, cobalt compensates for the negative anisotropy of the host lattice, inducing secondary permeability maxima or power loss minima. However, as shown in Figure 8, these phenomena are absent at 10 MHz. While increasing cobalt content leads to higher hysteresis losses, it also enhances the temperature stability of these losses, likely due to stronger domain wall pinning. This is further evidenced by the decrease in initial permeability with increased cobalt content (Figure 9a), indicating that magnetization at low frequencies and induction levels relies heavily on domain wall movements. At higher frequencies, such as 10 MHz, the effects of magnetocrystalline anisotropy compensation are overshadowed by resonance losses. The saturation flux density, depicted in Figure 9b, initially increases with cobalt content due to the higher magnetic moment of Co2+ ions on B-sites [23,42,43], and subsequently decreases at higher Co2+ concentrations (e.g., specimen B052) due to the forced migration of Fe3+ ions to octahedral sites [23,26,27,28].
Ιn Figure 14, the frequency dependence of the real (μ′) and imaginary (μ′′) components of the complex permeability (μ = μ′ + iμ′′) is presented for specimens of group A and group B. The initial increase in the real part, coinciding with the rise in the imaginary part, is typically attributed to domain wall resonance [16]. This peak shifts to lower frequencies with increasing iron content (Figure 14a) and to higher frequencies with increased cobalt content (Figure 14b). In agreement with the low of Snoek in all cases, the higher resonance frequencies are associated with lower magnetic permeabilities. When the iron content is higher than approximately 1.95 atoms per formula unit (i.e., specimens A196 and A197), a relatively sharp increase in permeability occurs, associated with a decrease in resonance frequency. Taking into account also the lower final densities of these specimens, the sharp increase in the 10 MHz power losses (Figure 5) can be explained. At iron contents lower than 1.95 atoms per formula unit, the drop in permeability and the increase in resonance frequency become less pronounced. In contrast, as shown in Figure 14b, the effect of cobalt on the resonance frequency becomes more obvious, indicating enhanced domain wall pinning.
Although cobalt enhances domain wall pinning and facilitates low losses at high temperatures, it also increases the system’s sensitivity to minor variations in operational parameters. Figure 15 shows the 10 MHz power loss as a function of temperature for specimen B046, sintered at 1150 °C and 1175 °C. While low-temperature losses (up to 60 °C) remain relatively unchanged, and do not seem to be significantly affected, a sharp rise is observed at higher temperatures. As previously noted, no significant differences in the microstructure were detected via SEM analysis. Additionally, the slightly varying densities (shown in Figure 7) do not account for the substantial differences in power losses.
In the inset of Figure 15, the real and imaginary components of the magnetic permeability are shown as functions of frequency. The domain wall resonance is clearly shifted to lower frequencies, leading to a sharp increase in power loss at higher temperatures. These results, together with those shown in Figure 14, provide strong evidence for the co-existence of a domain wall movement magnetization mechanism, even under conditions where the individual particles are considered monodomain, and are consistent with similar phenomena reported in the literature [21,22]. The efficiency of cobalt-induced pinning points appears to depend strongly on the sintering temperature, although the underlying mechanism remains unclear. Possible factors include diffusion, segregation and oxidation-reduction reactions during sintering, which may influence the cobalt distribution within the microstructure or its valence. It is worth noting that a 25 °C temperature difference is comparable to the temperature gradients typically observed in industrial production furnaces.
Increasing the Ni/Zn ratio further increases further the hysteresis losses and reduces the permeability, as shown in Figure 11a and Figure 12a. The increase in hysteresis losses is primarily attributed to the rise in the magnetocrystalline anisotropy constant [2], whose contribution to losses becomes more pronounced. At low temperatures, hysteresis losses are no longer independent of temperature, but instead exhibit a decreasing trend (Figure 9a), reflecting the temperature-dependent reduction of the magnetocrystalline anisotropy constant. Magnetic permeability decreases even further (Figure 12a), and as shown in Figure 16, resonance frequencies shift to higher values as a direct consequence of Snoek’s law, which applies to both magnetization mechanisms. Despite the reduced permeability, power losses of 1.4 W cm−3 were achieved at 10 MHz, 10 mT and 120 °C.
Power loss data at 10 MHz, especially at high temperatures, are scarce or nearly absent in the scientific literature, which hinders comparative discussions. In [15], power losses of approximately 250 mW cm−3 were measured at 3 MHz, 10 mT and 25 °C for NiCuZn ferrites. Although this frequency range lies beyond the scope of our study, the power losses of the materials presented in this article (samples A195), under identical conditions, ranged between 100 and 150 mW cm−3. These values are comparable to those reported in [44] for NiZn ferrites. However, at 7 MHz, 10 mT and 25 °C, the power losses of about 1000 mW cm−3 reported in [15] were significantly higher than the 200–250 mW cm−3 measured for sample A195/Β020. Additionally, power losses at 10 MHz, 10 mT and 25 °C, reported in [45], exceed 4 W cm−3, considerably higher than the corresponding losses presented in Figure 6. Finally, in [46], the power losses of NiCuZn ferrites doped with various amounts of V2O5 and Bi2O3 are reported to be 113 mW cm−3 at 10 MHz, 5 mT and 25 °C. The corresponding value for the A195/B020 specimen was 60 mW cm−3, which is approximately 41% lower.

4. Conclusions

Polycrystalline NiZn ferrites with excellent magnetic performance at high frequencies, particularly at 10 MHz, were synthesized using the conventional mixed oxide method. Optimized conditions were found to require slight iron deficiency and sintering temperatures between 1150 °C and 1175 °C to achieve a balance between densification and microstructural refinement.
The incorporation of cobalt significantly reduced high-temperature power losses by enhancing domain wall pinning and stabilizing the temperature dependency of these losses. However, this improvement was accompanied by an increase in hysteresis losses and a decrease in permeability. A moderate cobalt content (e.g., 0.04 atoms per formula unit) provided the best trade-off, yielding materials with power losses of 1233 mW cm−3 at 10 MHz, 10 mT and 100 °C. The corresponding initial permeability and saturation flux density at 100 °C were 90 (−) and 230 mT, respectively.
Stabilization of high-temperature, high-frequency power losses through domain wall pinning induced greater sensitivity to process operational parameters, such as the sintering temperature.
Increasing the Ni/Zn molar ratio above 1 enhanced the magnetocrystalline anisotropy constant and shifted resonance frequencies to higher values. However, this also resulted in increased hysteresis losses and reduced permeability. At a Ni/Zn molar ratio of 1.18 the measured power losses were 1400 mW cm−3 at 10 MHz, 10 mT and 120 °C. The corresponding initial permeability and saturation flux density at 120 °C were 97 (−) and 270 mT, respectively.

Author Contributions

Formal analysis, data curation, writing—editing original draft, S.Z. and G.K.; writing—review and editing V.Z. and E.K.; supervision E.R.; conceptualization, validation C.V. and K.O. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The original contributions presented in the study are included in the article, further inquiries can be directed to the corresponding authors.

Conflicts of Interest

Authors Elisabeth Rauchenwald, Christoph Vogler and Kevin Ouda were employed by the company Huawei Technologies Co., Ltd. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

References

  1. Goldman, A. (Ed.) Handbook of Modern Ferromagnetic Materials; Springer: Boston, MA, USA, 2006. [Google Scholar]
  2. Smit, J.; Wijn, H.P.J. Ferrite; Philips Technical Library: Eindhoven, The Netherlands, 1959. [Google Scholar]
  3. Leary, A.M.; Ohodnicki, P.R.; McHenry, M.E. Soft Magnetic Materials in High-Frequency, High-Power Conversion Applications. JOM 2012, 64, 772–781. [Google Scholar] [CrossRef]
  4. Chen, J.; Du, X.; Luo, Q.; Zhang, X.; Sun, P.; Zhou, L. A Review of Switching Oscillations of Wide Bang Gap Semiconductor Devices. IEEE Trans. Power Electron. 2020, 35, 13182–13199. [Google Scholar] [CrossRef]
  5. Morel, H.; Alam, M.; Bevilacqua, P.; Tournier, D.; Planson, D. Impact of Wide Band-Gap Semiconductors on the Design in Power Electronics. In Proceedings of the Symposium on Advanced Technologies in Electrical Systems (SATES 2023), Arras, France, 22–23 March 2023. [Google Scholar]
  6. Su, H.; Zhang, H.; Tang, X.; Xiang, X. High-permeability and high-Curie temperature NiCuZn ferrite. J. Magn. Magn. Mater. 2004, 283, 157–163. [Google Scholar] [CrossRef]
  7. Zaspalis, S.; Kogias, G.; Zaspalis, V. The effect of Sintering Temperature on the Densification and Magnetic Performance of NiCuZn-ferrites (CuO 0–6 wt.%). Materials 2024, 17, 2293. [Google Scholar] [CrossRef]
  8. Lucas, A.; Lebourgeois, R.; Mazaleyrat, F.; Laboure, E. Temperature dependence of core loss in cobalt substituted Ni-Zn-Cu ferrites. J. Magn. Magn. Mater. 2011, 323, 735–739. [Google Scholar] [CrossRef]
  9. Byun, T.Y.; Byeon, S.C.; Hong, K.S. Factors affecting initial permeability of Co- substituted Ni–Zn–Cu ferrites. IEEE Trans. Magn. 1999, 35, 3445–3447. [Google Scholar] [CrossRef]
  10. Sun, K.; Lan, Z.; Yu, Z.; Li, L.; Huang, J.; Zhao, X. Effects of SnO2 addition on the microstructure and magnetic properties of NiZn-ferrites. J. Magn. Magn. Mater. 2008, 320, 3352–3355. [Google Scholar] [CrossRef]
  11. Hu, J.; Shi, G.; Ni, Z.; Zheng, L.; Chen, A. Effects of V2O5 addition on NiZn ferrites synthesized using two-step sintering process. Physica B 2012, 407, 2205–2210. [Google Scholar] [CrossRef]
  12. Van Uitert, L.G. High-Resistivity Nickel Ferrites—The Effect of Minor Additions of Manganese or Cobalt. J. Chem. Phys. 1956, 24, 306–310. [Google Scholar] [CrossRef]
  13. Jacobo, S.E.; Duhalde, S.; Bertorello, H.R. Rare earth influence on the structural and magnetic properties of NiZn ferrites. J. Magn. Magn. Mater. 2004, 272–276, 2253–2254. [Google Scholar] [CrossRef]
  14. Priese, C.; Töpfer, J. The effect of microstructure on the initial permeability of Ni-Zn ferrite. J. Magn. Magn. Mater. 2022, 560, 169581. [Google Scholar] [CrossRef]
  15. Su, H.; Zhang, H.; Tang, X.; Jing, Y. Influence of microstructure on permeability dispersion and power loss of NiZn ferrite. J. Appl. Phys. 2008, 103, 093903. [Google Scholar] [CrossRef]
  16. Andalib, P.; Harris, V.G. Grain boundary engineering of power inductor cores for MHz applications. J. Alloys Compd. 2020, 832, 153131. [Google Scholar] [CrossRef]
  17. Clausell-Terol, C.; Barba, A.; Mormeneo-Segarra, J.A.; Putyra, P.; Jarowska, L. Enhancing NiZn ferrite properties through microwave sintering: A comparative study. Boletín Sociedad Española Ceramíca Vidryo 2024, 63, 161–171. [Google Scholar] [CrossRef]
  18. Gao, S.; Song, S.; Song, Q. Effect of High-Energy Ball Milling on the Magnetic Properties of NiZn Ferrite Ceramics Synthesized by Spark Plasma Sintering. J. Mater. Sci. Chem. Eng 2015, 3, 50–55. [Google Scholar] [CrossRef]
  19. Brissette, L.S.; Grossi, E.A.; Titlar, J.M.; Cherven, K.; Spriggs, R.M. Hote pressed ceramic ferrites: Magnetic-mechanical-microstructural interactions. AIP Conf. Proc. 1976, 29, 561. [Google Scholar] [CrossRef]
  20. Frajer, G.; Isnard, O.; Chaza, H.; Delette, G. Effect of cobalt addition on the magneto-crystalline anisotropy parameter of sintered NiZn ferrites evaluated from magnetization curves. J. Magn. Magn. Mater. 2019, 473, 92–98. [Google Scholar] [CrossRef]
  21. Fiorillo, F.; Coisson, M.; Beatrice, C.; Pasquale, M. Permeability and losses in ferrites from dc to the microwave regime. J. Appl. Phys. 2009, 105, 07A517. [Google Scholar] [CrossRef]
  22. Mohapatra, P.P.; Singh, H.K.; Kiran, M.S.R.N.; Dobbidi, P. Co-substituted Ni-Zn ferrites with tunable dielectric and magnetic response for high-frequency applications. Ceram. Int. 2022, 48, 29217–29228. [Google Scholar] [CrossRef]
  23. Msomi, J.Z.; Nhapo, T.A.; Stanciu, A.; Greculeasa, S.; Kunczer, V.; Moyo, T. Temperature dependent magnetic properties of NixCo1-xFe2O4: Single and multidomain particles. Phys. B Condens. Matter 2023, 650, 414595. [Google Scholar] [CrossRef]
  24. Mattei, J.L.; Le Guen, J.L.; Chevalier, A.; Tarot, A.C. Experimental determination of magnetocrystalline anisotropy constants and saturation magnetostriction constants for NiZn and NiZnCo ferrites intended to be used for antennas miniaturization. J. Mag. Magn. Mater. 2015, 374, 762–768. [Google Scholar] [CrossRef]
  25. Chand, P.; Vaish, S.; Kumar, P. Structural, optical and dielectric properties of transition metal (MFe2O4; M=Co, Ni and Zn) nanoferrites. Phys. B Condens. Matter 2017, 524, 53–63. [Google Scholar] [CrossRef]
  26. Henderson, C.M.B.; Charnock, J.M.C.; Plant, D.A. Cation occupancies in Mg, Co, Ni, Zn, Al ferrite spinels: A multi-element EXAFS study. J. Phys. Condens. Matter 2007, 19, 076214. [Google Scholar] [CrossRef] [PubMed]
  27. Srikanth, H.V.; Ramesh, S.; Rajulu, K.C.V.; Dhanalakshmi, B.; Rao, D.J.; Rao, B.P. Rietveld analysis and cation distribution of Co-substituted Ni-Zn ferrite nanoparticles. J. Indian Chem. Soc. 2024, 101, 101312. [Google Scholar] [CrossRef]
  28. Upadhyay, C.; Verma, H.C.; Anand, S. Cation distribution in nanosized Ni-Zn ferrites. J. Appl. Phys. 2004, 95, 5746–5751. [Google Scholar] [CrossRef]
  29. Thakur, P.; Taneja, S.; Chahar, D.; Ravelo, B.; Thakur, A. Recent advances on synthesis, characterization and high frequency applications of Ni-Zn ferrite nanoparticles. J. Magn. Magn. Mater. 2021, 530, 167925. [Google Scholar] [CrossRef]
  30. De Lau, J.G.M.; Broese van Groenou, A. High-frequency properties of Ni-Zn-Co ferrites in relation to Iron content and microstructure. J. Phys. Colloq. 1977, 38, C1-17–C1-22. [Google Scholar] [CrossRef]
  31. Stuijts, A.L. Control of microstructures in ferrites. In Proceedings of the International Conference on Ferrites, Kyoto, Japan, 6–15 July 1970; pp. 108–113. [Google Scholar]
  32. Reijnen, P.J.L. Sintering behavior and microstructures of aluminates and ferrites with spinel structure with regard to deviation from stoichiometry. Sci. Ceram. 1968, 4, 169–188. [Google Scholar]
  33. Globus, A. Some physical considerations about the domain wall size theorie of magnetization mechanisms. J. Phys. Colloq. 1977, 38, C1.1–C1.15. [Google Scholar] [CrossRef]
  34. Visser, E.G.; Johnson, M.T. A novel interpretation of the complex permeability in polycrystalline ferrites. J. Magn. Magn. Mater. 1991, 101, 143–147. [Google Scholar] [CrossRef]
  35. Kingery, W.D.; Bowen, H.K.; Uhlmann, D.R. Introduction to Ceramics, Chapter 10, Grain Growth, Sintering and Vitrification; John Wiley & Sons: Hoboken, NJ, USA, 1976; ISBN 0-471-47860-1. [Google Scholar]
  36. van der Zaag, P.J.; van der Valk, P.J.; Rekveldt, M.T. A domain size effect in the magnetic hysteresis of NiZn ferrites. Appl. Phys. Lett. 1996, 69, 2927–2929. [Google Scholar] [CrossRef]
  37. Snoek, J.L. Dispersion and absorption in magnetic ferrites at frequencies above one Mc/s. Physica 1948, 14, 207–217. [Google Scholar] [CrossRef]
  38. Wu, P.; Wu, W.; Tu, C.; Wang, W.; Sheng, Y.; Li, F.; Qiao, L. Temperature dependence of complex permeability and power losses for Mn-Zn ferrites. J. Appl. Phys. 2023, 134, 223903. [Google Scholar] [CrossRef]
  39. Lakshmanan, M. The fascinating world of the Landau-Lifshitz-Gilbert equation: An overview. Philos. Trans. R. Soc. A 2011, 369, 1280–1300. [Google Scholar] [CrossRef] [PubMed]
  40. Beatrice, C.; Dobák, S.; Tsakaloudi, V.; Ragusa, C.; Fiorillo, F.; Martino, L.; Zaspalis, V. Magnetic loss, permeability, and anisotropy compensation in CoO-doped Mn-Zn ferrites. AIP Adv. 2018, 8, 047803. [Google Scholar] [CrossRef]
  41. Tsakaloudi, V.; Beatrice, C.; Dobák, S.; Fiorillo, F.; Zaspalis, V. Measuring and modeling broadband magnetic losses versus temperature and aging effects in CoO-doped Mn-Zn ferrites. In Proceedings of the 2020 IEEE 29th International Symposium on Industrial Electronics (ISIE), Delft, The Netherlands, 17–19 June 2020; pp. 1454–1458. [Google Scholar] [CrossRef]
  42. Alqarni, A.N.; Almessiere, M.A.; Güner, S.; Sertkol, M.; Shirsath, S.E.; Tashkandi, N.; Baykal, A. Structural and magnetic properties of hydrothermally synthesized Bi-substituted Ni–Co nanosized spinel ferrites. Ceram. Int. 2022, 48, 5450–5458. [Google Scholar] [CrossRef]
  43. Almessiere, M.A.; Slimani, Y.; Gungunes, H.; Gondal, M.A.; Hassan, M.; Shirsath, S.E.; Baykal, A. Bi3+ and V3+ co-substituted Ni-Co spinel ferrites: Synthesis, optical, magnetic characterization and hyperfine interaction. Mater. Sci. Eng. B 2022, 284, 115905. [Google Scholar] [CrossRef]
  44. Kawano, K.; Hachiya, M.; Iijima, Y. Study of Low-Loss NiZn-ferrite. J. Jpn. Soc. Powder Powder Metall. 2012, 60, 103–107. [Google Scholar] [CrossRef]
  45. Su, H.; Zhang, H.; Tang, X.; Shi, Y. Effects of microstructure on permeability and power loss charactersitcis of the NiZn ferrites. J. Magn. Magn. Mater. 2008, 320, 483–485. [Google Scholar] [CrossRef]
  46. Fan, X.; Bai, G.; Zhang, Z.; Chen, Q.; Jin, J.; Xu, J.; Zhang, X.; Yan, M. Synergistic effect of V2O5 and Bi2O3 on the grain boundary structure of high-frequency NiCuZn ferrite ceramics. J. Adv. Ceram. 2022, 11, 912–921. [Google Scholar] [CrossRef]
Figure 1. Representative particle size distributions of prefired and -milled powders A192, A195 and A198, determined by laser scattering.
Figure 1. Representative particle size distributions of prefired and -milled powders A192, A195 and A198, determined by laser scattering.
Magnetochemistry 11 00044 g001
Figure 2. Representative XRD patterns of prefired and -milled powders A192 and A198.
Figure 2. Representative XRD patterns of prefired and -milled powders A192 and A198.
Magnetochemistry 11 00044 g002
Figure 3. Final sintered densities as a function of iron content, at different sintering temperatures.
Figure 3. Final sintered densities as a function of iron content, at different sintering temperatures.
Magnetochemistry 11 00044 g003
Figure 4. Typical SEM images of specimens from group A. Panels (ad) show constant iron content with varying sintering temperature, while panels (eh) show constant sintering temperature with varying iron content.
Figure 4. Typical SEM images of specimens from group A. Panels (ad) show constant iron content with varying sintering temperature, while panels (eh) show constant sintering temperature with varying iron content.
Magnetochemistry 11 00044 g004
Figure 5. Power losses at 10 MHz, 100 °C and (a) 10 mT, (b) 3 mT as a function of the iron content at different sintering temperatures.
Figure 5. Power losses at 10 MHz, 100 °C and (a) 10 mT, (b) 3 mT as a function of the iron content at different sintering temperatures.
Magnetochemistry 11 00044 g005
Figure 6. Power losses measured at 10 MHz as a function of temperature for varying induction fields in specimen A195 sintered at 1175 °C.
Figure 6. Power losses measured at 10 MHz as a function of temperature for varying induction fields in specimen A195 sintered at 1175 °C.
Magnetochemistry 11 00044 g006
Figure 7. Final sintered densities as a function of cobalt content for group B specimens sintered at 1150 and 1175 °C.
Figure 7. Final sintered densities as a function of cobalt content for group B specimens sintered at 1150 and 1175 °C.
Magnetochemistry 11 00044 g007
Figure 8. Power losses measured at 10 MHz as a function of temperature for specimens with varying cobalt content: (a) at 10 mT, (b) at 3 mT.
Figure 8. Power losses measured at 10 MHz as a function of temperature for specimens with varying cobalt content: (a) at 10 mT, (b) at 3 mT.
Magnetochemistry 11 00044 g008
Figure 9. (a) Initial permeabilities and (b) saturation flux densities as a function of temperature for specimens of group B with gradually varying cobalt content.
Figure 9. (a) Initial permeabilities and (b) saturation flux densities as a function of temperature for specimens of group B with gradually varying cobalt content.
Magnetochemistry 11 00044 g009
Figure 10. Final sintered densities as a function of the Ni/Zn molar ratio for group C specimens sintered at 1150 °C and 1175 °C.
Figure 10. Final sintered densities as a function of the Ni/Zn molar ratio for group C specimens sintered at 1150 °C and 1175 °C.
Magnetochemistry 11 00044 g010
Figure 11. Power losses measured at 10 MHz as a function of temperature for specimens of group C with gradually varying Ni/Zn molar ratio: (a) at 10 mT, (b) at 3 mT.
Figure 11. Power losses measured at 10 MHz as a function of temperature for specimens of group C with gradually varying Ni/Zn molar ratio: (a) at 10 mT, (b) at 3 mT.
Magnetochemistry 11 00044 g011
Figure 12. (a) Initial magnetic permeabilities and (b) saturation flux densities as a function of temperature for specimens of group C with gradually varying Ni/Zn molar ratio.
Figure 12. (a) Initial magnetic permeabilities and (b) saturation flux densities as a function of temperature for specimens of group C with gradually varying Ni/Zn molar ratio.
Magnetochemistry 11 00044 g012
Figure 13. Power losses per cycle as a function of frequency for specimens A195/B020, measured at three different temperatures of 25, 100 and 120 °C.
Figure 13. Power losses per cycle as a function of frequency for specimens A195/B020, measured at three different temperatures of 25, 100 and 120 °C.
Magnetochemistry 11 00044 g013
Figure 14. Real and imaginary components of the complex permeability as a function of frequency: (a) for specimens of group A with gradually varying iron content; (b) for specimens of group B with gradually varying cobalt content.
Figure 14. Real and imaginary components of the complex permeability as a function of frequency: (a) for specimens of group A with gradually varying iron content; (b) for specimens of group B with gradually varying cobalt content.
Magnetochemistry 11 00044 g014
Figure 15. Measured power losses of specimens B046 at 10 MHz and 10 mT as a function of temperature, sintered at two distinct temperatures. Inset: corresponding magnetic permeabilities as a function of frequency.
Figure 15. Measured power losses of specimens B046 at 10 MHz and 10 mT as a function of temperature, sintered at two distinct temperatures. Inset: corresponding magnetic permeabilities as a function of frequency.
Magnetochemistry 11 00044 g015
Figure 16. The real and imaginary components of the complex permeability as a function of frequency for specimens of group C with gradually varying Ni/Zn molar ratio.
Figure 16. The real and imaginary components of the complex permeability as a function of frequency for specimens of group C with gradually varying Ni/Zn molar ratio.
Magnetochemistry 11 00044 g016
Table 1. Code names and chemical compositions of prepared NiZn ferrites.
Table 1. Code names and chemical compositions of prepared NiZn ferrites.
Atoms per Unit Cell
Code NameNi/Zn Molar RatioCoFeChemical Formula
A19110.021.91 N i 0.490 Z n 0.490 C o 0.020 F e 1.91 O 4
A19210.021.92 N i 0.490 Z n 0.490 C o 0.020 F e 1.92 O 4
A19410.021.94 N i 0.490 Z n 0.490 C o 0.020 F e 1.94 O 4
A195/B02010.021.95 N i 0.490 Z n 0.490 C o 0.020 F e 1.95 O 4
A19610.021.96 N i 0.490 Z n 0.490 C o 0.020 F e 1.96 O 4
A19810.021.98 N i 0.490 Z n 0.490 C o 0.020 F e 1.98 O 4
B02810.0281.95 N i 0.486 Z n 0.486 C o 0.028 F e 1.95 O 4
B03410.0341.95 N i 0.483 Z n 0.483 C o 0.034 F e 1.95 O 4
B040/C10010.0401.95 N i 0.480 Z n 0.480 C o 0.040 F e 1.95 O 4
B04610.0461.95 N i 0.477 Z n 0.477 C o 0.046 F e 1.95 O 4
B05210.0521.95 N i 0.474 Z n 0.474 C o 0.052 F e 1.95 O 4
C1181.180.0401.95 N i 0.520 Z n 0.440 C o 0.040 F e 1.95 O 4
C1341.340.0401.95 N i 0.550 Z n 0.410 C o 0.040 F e 1.95 O 4
C1511.510.0401.95 N i 0.578 Z n 0.382 C o 0.040 F e 1.95 O 4
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Zaspalis, S.; Kogias, G.; Zaspalis, V.; Kikkinides, E.; Rauchenwald, E.; Vogler, C.; Ouda, K. Development of NiZn Ferrites Doped with Co for Low Power Losses at High Frequencies (10 MHz) and High Temperatures (>80 °C). Magnetochemistry 2025, 11, 44. https://doi.org/10.3390/magnetochemistry11050044

AMA Style

Zaspalis S, Kogias G, Zaspalis V, Kikkinides E, Rauchenwald E, Vogler C, Ouda K. Development of NiZn Ferrites Doped with Co for Low Power Losses at High Frequencies (10 MHz) and High Temperatures (>80 °C). Magnetochemistry. 2025; 11(5):44. https://doi.org/10.3390/magnetochemistry11050044

Chicago/Turabian Style

Zaspalis, Stefanos, Georgios Kogias, Vassilios Zaspalis, Eustathios Kikkinides, Elisabeth Rauchenwald, Christoph Vogler, and Kevin Ouda. 2025. "Development of NiZn Ferrites Doped with Co for Low Power Losses at High Frequencies (10 MHz) and High Temperatures (>80 °C)" Magnetochemistry 11, no. 5: 44. https://doi.org/10.3390/magnetochemistry11050044

APA Style

Zaspalis, S., Kogias, G., Zaspalis, V., Kikkinides, E., Rauchenwald, E., Vogler, C., & Ouda, K. (2025). Development of NiZn Ferrites Doped with Co for Low Power Losses at High Frequencies (10 MHz) and High Temperatures (>80 °C). Magnetochemistry, 11(5), 44. https://doi.org/10.3390/magnetochemistry11050044

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop