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Inorganics, Volume 7, Issue 8 (August 2019)
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Cover Story (view full-size image) In the cover story, the core concept of the coordinating solvent approach (CSA) is described. We [...] Read more. In the cover story, the core concept of the coordinating solvent approach (CSA) is described. We analyzed and studied the effect of coordinating solvents on the final outcome of the self-assembly process towards Cu(II)-4,4′-bipyridine-based coordination polymers. Solvents such as DMA, DMF, and DMSO can compete with the bridging ligand in occupying two or four coordination sites of the metal center. This allowed us to access different coordination polymers. CSA can be used as an effective tool to modulate and control the dimensionality, composition, and network of coordination polymers. View this paper.