- Article
Si-Disordering in MgAl2O4-Spinel under High P-T Conditions, with Implications for Si-Mg Disorder in Mg2SiO4-Ringwoodite
- Liping Liu,
- Xi Liu,
- Xinjian Bao,
- Qiang He,
- Wei Yan,
- Yunlu Ma,
- Mingyue He,
- Renbiao Tao and
- Ruqiang Zou
A series of Si-bearing MgAl2O4-spinels were synthesized at 1500–1650 °C and 3–6 GPa. These spinels had SiO2 contents of up to ~1.03 wt % and showed a substitution mechanism of Si4+ + Mg2+ = 2Al3+. Unpolarized Raman spectra were collected from polishe...

