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Polymers, Volume 9, Issue 11

November 2017 - 86 articles

Cover Story: A new copolymer with a temperature-responsive block and a cationic block was prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization. The temperature-responsive block of di(ethylene glycol) methyl ether methacrylate (DEGMA) and oligo(ethylene glycol) methyl ether methacrylate (OEGMA) has tunable volume phase transition temperature depending on the DEGMA/OEGMA ratio. The cationic block of trimethyl-2-methacroyloxyethylammonium chloride (TMEC) is charged at physiological pH values and was used for binding single strand DNA. The copolymer forms coacervate complexes with the DNA, which were characterized by fluorescence correlation spectroscopy (FCS) and fluorescence spectroscopy. The new materials offer good prospects for application in controlled gene delivery. View the paper here.
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Articles (86)

  • Article
  • Open Access
12 Citations
9,256 Views
16 Pages

Design of Thermochromic Polynorbornene Bearing Spiropyran Chromophore Moieties: Synthesis, Thermal Behavior and Dielectric Barrier Discharge Plasma Treatment

  • Saleh A. Ahmed,
  • Rawda M. Okasha,
  • Khalid S. Khairou,
  • Tarek H. Afifi,
  • Abdel-Aleam H. Mohamed and
  • Alaa S. Abd-El-Aziz

22 November 2017

A new class of thermochromic polynorbornene with pendent spiropyran moieties has been synthesized. Functionalization of norbornene monomers with spirobenzopyran moieties has been achieved using Steglich esterification. These new monomeric materials w...

  • Article
  • Open Access
19 Citations
8,394 Views
15 Pages

22 November 2017

Polyisoprene-silica (PIP-co-RAFT-SiO2) nanoparticles were prepared via reversible addition–fragmentation chain-transfer (RAFT) emulsifier-free emulsion polymerization using water-soluble initiators, 4,4′-Azobis (4-cyanopentanoic acid) (ACP) and 2,2′-...

  • Article
  • Open Access
16 Citations
7,251 Views
11 Pages

22 November 2017

In this study, chemical treatment (CT; oxidation–reduction method) and physical treatment (HP; hot-pressing methods) were applied to improve the performance of silver nanowire (AgNW)-derived electrodes on a glass or flexible polyethylene terephthalat...

  • Article
  • Open Access
3 Citations
4,869 Views
9 Pages

21 November 2017

A series of new fluorenylamido-ligated zirconium complexes bearing an electron-donating adamantyl group on the amido ligand were synthesized and characterized by elemental analysis, 1H NMR, and single crystal X-ray analysis. The coordination mode of...

  • Article
  • Open Access
12 Citations
5,626 Views
12 Pages

Bulk Oriented UHMWPE/FMWCNT Films for Tribological Applications

  • Aleksey V. Maksimkin,
  • Saidkhuja G. Nematulloev,
  • Dilyus I. Chukov,
  • Vladimir D. Danilov and
  • Fedor S. Senatov

19 November 2017

Bulk oriented films based on ultrahigh molecular weight polyethylene (UHMWPE) with a drawing ratio of 35 were prepared by using a low solvent concentration. Bulk oriented films were filled with fluorinated multi-walled carbon nanotubes (FMWCNTs). The...

  • Article
  • Open Access
2 Citations
7,475 Views
11 Pages

17 November 2017

MgCl2-supported titanium Ziegler-Natta catalyst containing CO2-based poly(propylene ether carbonate) diols as a potential internal electron donor (IED) was synthesized and employed for 1-butene polymerization. When compared with the Ziegler-Natta cat...

  • Article
  • Open Access
50 Citations
7,862 Views
10 Pages

The Dynamic Mechanical Analysis of Highly Filled Rice Husk Biochar/High-Density Polyethylene Composites

  • Qingfa Zhang,
  • Hongzhen Cai,
  • Xueyong Ren,
  • Lingshuai Kong,
  • Jianbiao Liu and
  • Xuya Jiang

17 November 2017

In this study, rice husk biochar/high-density polyethylene (HDPE) composites were prepared via melt mixing followed by extrusion. Effects of biochar content and testing temperature on the dynamic mechanical analysis (DMA) of the composites were studi...

  • Article
  • Open Access
14 Citations
4,861 Views
12 Pages

16 November 2017

Wood Plastic Composites (WPCs) are a new generation of green composites that could optimize the use of harvested trees and increase the entire value chain. In this study, the electrical and mechanical properties of WPCs containing carbon blacks (CB),...

  • Article
  • Open Access
10 Citations
10,400 Views
18 Pages

16 November 2017

Polymeric amines are intensively studied due to various valuable properties. This study describes the synthesis of new polymeric amines and ampholytes by the reaction of poly(acryloyl chloride) with trimethylene-based polyamines containing one second...

  • Article
  • Open Access
157 Citations
9,680 Views
15 Pages

16 November 2017

Dye-doped polymer films of Poly(methyl methacrylate) PMMA have been prepared with the use of the conventional solution cast technique. Natural dye has been extracted from environmentally friendly material of green tea (GT) leaves. Obvious Fourier tra...

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Polymers - ISSN 2073-4360