Table of Contents
Crystals, Volume 9, Issue 5 (May 2019) – 51 articles
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Cover Story (view full-size image) The Al- and Fe-oxide-hydroxides systems share many isostructures. While Al10O14(OH)2(akdalaite) and [...] Read more. The Al- and Fe-oxide-hydroxides systems share many isostructures. While Al10O14(OH)2(akdalaite) and Fe10O14(OH)2(ferrihydrite) are indeed isostructural, the former crystallizes from solution while the latter occurs only in nanocrystalline form. A comprehensive study combining total X-ray and neutron scattering, and NMR spectroscopy, reveals the two structures share anomalies in expected bond valence sums, especially at the tetrahedral metal site of the M13Keggin cluster motifs implicated in the NP growth. View this paper