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Crystals, Volume 5, Issue 2

June 2015 - 9 articles

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Articles (9)

  • Article
  • Open Access
6 Citations
6,386 Views
12 Pages

29 May 2015

Five coordination polymers with the stoichiometry CaX2(valine)2(H2O)2 (X = Cl, Br) were obtained from the corresponding calcium halides and either racemic and enantiopure valine. In all cases the zwitterionic amino acid is exclusively O coordinated a...

  • Article
  • Open Access
16 Citations
7,661 Views
9 Pages

Flux Growth and Crystal Structure Refinement of Calcite Type Borate GaBO3

  • Shichao Wang,
  • Ning Ye and
  • Kenneth R. Poeppelmeier

27 May 2015

A single crystal of gallium borate, GaBO3, 4 × 4 × 0.2 mm3 in size has been grown by spontaneous crystallization with a molten flux based on a Bi2O3-3B2O3 solvent. From single crystal X-ray diffraction measurement, GaBO3 was found to crystallize in t...

  • Article
  • Open Access
3 Citations
4,266 Views
8 Pages

22 May 2015

In the square-planar cycloplatinated complex of R–phenylethylamine, both additional substituents, an anionic iodo and a neutral donor ligand, have been replaced by chelating ethylenediamine. A very pronounced trans influence is observed in the cation...

  • Article
  • Open Access
10 Citations
8,437 Views
18 Pages

Novel S = 1/2 Kagome Lattice Materials: Cs2TiCu3F12 and Rb2TiCu3F12

  • Lewis J. Downie,
  • Elena I. Ardashnikova,
  • Chiu C. Tang,
  • Alexandre N. Vasiliev,
  • Peter S. Berdonosov,
  • Valery A. Dolgikh,
  • Mark A. De Vries and
  • Philip Lightfoot

5 May 2015

Two new members of the A2B′Cu3F12 family of kagome-related materials have been prepared, in order to further understand the crystal-chemical relationships, phase transitions and magnetic behaviour within this family of potentially frustrated S = ½ tw...

  • Communication
  • Open Access
9 Citations
7,493 Views
11 Pages

Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand

  • Kenji Nakatani,
  • Kento Himoto,
  • Yuki Kono,
  • Yuuki Nakahashi,
  • Haruho Anma,
  • Takashi Okubo,
  • Masahiko Maekawa and
  • Takayoshi Kuroda-Sowa

29 April 2015

A new mixed-valence Cu(I)–Cu(II) 1D coordination polymer, [CuI4CuIIBr4(Cy2dtc)2]n, with an infinite chain structure is synthesized by the reaction of Cu(Cy2dtc)2 (Cy2dtc− = dicyclohexyl dithiocarbamate, C13H22NS2) with CuBr·S(CH3)2. The as-synthesiz...

  • Article
  • Open Access
4 Citations
6,684 Views
9 Pages

Ferronematics Based on Paramagnetic Nitroxide Radical Liquid Crystal

  • Takuya Akita,
  • Yoshiaki Uchida,
  • Sho Nakagami,
  • Daichi Kiyohara and
  • Norikazu Nishiyama

27 April 2015

We have prepared novel ferronematics based on a paramagnetic liquid crystalline (LC) material. Our ferronematics can disperse a higher volume fraction of magnetic nanoparticles compared to classical ferronematics because paramagnetic nature of the ho...

  • Article
  • Open Access
7 Citations
7,884 Views
13 Pages

Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

  • Carlos Ordonez,
  • Tiffany L. Kinnibrugh,
  • Hongwu Xu,
  • Jennifer Lindline,
  • Tatiana Timofeeva and
  • Qiang Wei

2 April 2015

The solvothermal synthesis of framework isomers was carried out using the hybrid carboxylate and tetrazolate functional ligand, 4-tetrazolyl benzenecarboxylic acid (H2TBC, TBC = 4-tetrazolyl benzenecarboxylate) and zinc. H2TBC was also synthesized wi...

  • Review
  • Open Access
18 Citations
11,217 Views
21 Pages

The Growth and Properties of Lead-Free Ferroelectric Single Crystals

  • Xiaobing Li,
  • Chao Chen,
  • Hao Deng,
  • Haiwu Zhang,
  • Di Lin,
  • Xiangyong Zhao and
  • Haosu Luo

25 March 2015

Much attention is drawn to the preparation, structure and properties investigation of lead-free ferroelectrics for the next generation of piezoelectric devices. (Na0.5Bi0.5)TiO3-BaTiO3 (NBT-BT) lead-free solid solution piezoelectric single crystals w...

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Crystals - ISSN 2073-4352Creative Common CC BY license