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Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand

1
School of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, Japan
2
Japan Science and Technology Agency (JST), Precursory Research for Embryonic Science and Technology (PRESTO), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan
*
Author to whom correspondence should be addressed.
Academic Editor: Glen Deacon
Crystals 2015, 5(2), 215-225; https://doi.org/10.3390/cryst5020215
Received: 6 February 2015 / Revised: 7 April 2015 / Accepted: 20 April 2015 / Published: 29 April 2015
A new mixed-valence Cu(I)–Cu(II) 1D coordination polymer, [CuI4CuIIBr4(Cy2dtc)2]n, with an infinite chain structure is synthesized by the reaction of Cu(Cy2dtc)2 (Cy2dtc = dicyclohexyl dithiocarbamate, C13H22NS2) with CuBr·S(CH3)2. The as-synthesized polymer consists of mononuclear copper(II) units of CuII(Cy2dtc)2 and tetranuclear copper(I) cluster units, CuI4Br4. In the cluster unit, all the CuI ions have distorted trigonal pyramidal coordination geometries, and the CuI–CuI or CuI–CuII distances between the nearest copper ions are shorter than the sum of van der Waals radii for Cu–Cu. View Full-Text
Keywords: copper complex; mixed-valence; coordination polymer copper complex; mixed-valence; coordination polymer
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Nakatani, K.; Himoto, K.; Kono, Y.; Nakahashi, Y.; Anma, H.; Okubo, T.; Maekawa, M.; Kuroda-Sowa, T. Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand. Crystals 2015, 5, 215-225.

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