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Crystals, Volume 3, Issue 1

2013 March - 15 articles

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Articles (15)

  • Article
  • Open Access
7 Citations
10,672 Views
14 Pages

Generation of Light Scattering States in Cholesteric Liquid Crystals by Optically Controlled Boundary Conditions

  • Jonathan P. Vernon,
  • Svetlana V. Serak,
  • Rafael S. Hakobyan,
  • Vincent P. Tondiglia,
  • Timothy J. White,
  • Nelson V. Tabiryan and
  • Timothy J. Bunning

18 March 2013

Circularly polarized light was previously employed to stimulate the reversible and reconfigurable writing of scattering states in cholesteric liquid crystal (CLC) cells constructed with a photosensitive layer. Such dynamic photodriven responses have...

  • Article
  • Open Access
4 Citations
10,132 Views
9 Pages

Iminium Salts by Meerwein Alkylation of Ehrlich’s Aldehyde

  • Carmen Froschauer,
  • Hedda K. Weber,
  • Volker Kahlenberg,
  • Gerhard Laus and
  • Herwig Schottenberger

18 March 2013

4-(Dimethylamino)benzaldehyde is alkylated at the N atom by dialkyl sulfates, MeI, or Me3O BF4. In contrast, ethylation by Et3O BF4 occurs selectively at the O atom yielding a quinoid iminium ion. 4-(Diethylamino)benzaldehyde is alkylated only at O b...

  • Review
  • Open Access
67 Citations
22,306 Views
18 Pages

A Study on Graphene—Metal Contact

  • Wenjun Liu,
  • Jun Wei,
  • Xiaowei Sun and
  • Hongyu Yu

18 March 2013

The contact resistance between graphene and metal electrodes is crucial for the achievement of high-performance graphene devices. In this study, we review our recent study on the graphene–metal contact characteristics from the following viewpoints: (...

  • Review
  • Open Access
69 Citations
18,721 Views
43 Pages

13 March 2013

We present local electrical characterization of epitaxial graphene grown on both Si- and C-faces of 4H-SiC using Electrostatic Force Microscopy and Kelvin Probe Force Microscopy in ambient conditions and at elevated temperatures. These techniques pro...

  • Review
  • Open Access
114 Citations
23,217 Views
28 Pages

6 March 2013

Graphene is a promising electrode material for supercapacitors mainly because of its large specific surface area and high conductivity. In practice, however, several fabrication issues need refinement. The restacking of graphene flakes upon being pac...

  • Review
  • Open Access
65 Citations
10,505 Views
14 Pages

1 March 2013

Photoalignment possesses obvious advantages in comparison with the usually “rubbing” treatment of the substrates of liquid crystal display (LCD) cells. The application of the photoalignment and photopatterning nanotechnology for the new generation of...

  • Article
  • Open Access
2 Citations
7,181 Views
8 Pages

Syntheses and Crystal Structures of Ferrocenoindenes

  • Klaus Wurst,
  • Gerhard Laus,
  • Michael R. Buchmeiser and
  • Herwig Schottenberger

27 February 2013

Ferrocenoindenes display planar chirality and thus represent valuable ligands for asymmetric catalysis. Here, we report on the synthesis of novel 3-(1,1-dibromomethylene)ferroceno[1,2-a]indene, (Z)-3-(1-bromomethylene)-6-iodoferroceno[1,2-a]indene, a...

  • Article
  • Open Access
58 Citations
14,395 Views
21 Pages

The Origin of Raman D Band: Bonding and Antibonding Orbitals in Graphene

  • Ken-ichi Sasaki,
  • Yasuhiro Tokura and
  • Tetsuomi Sogawa

22 February 2013

In Raman spectroscopy of graphite and graphene, the D band at ∼ 1355 cm−1 is used as the indication of the dirtiness of a sample. However, our analysis suggests that the physics behind the D band is closely related to a very clear idea for describing...

  • Communication
  • Open Access
3 Citations
6,933 Views
8 Pages

18 February 2013

The synthesis, crystal structure, and conductivity of a solvent-included ternary charge-transfer salt (BEDT-TTF)2GaCl4(C6H5Cl)0.5 (1) is described and interpreted. Electrochemical oxidation of neutral bis(ethyelenedithio)-tetrathiafulvalene (BEDT-TT...

  • Review
  • Open Access
147 Citations
17,610 Views
33 Pages

Metals on Graphene: Interactions, Growth Morphology, and Thermal Stability

  • Xiaojie Liu,
  • Cai-Zhuang Wang,
  • Myron Hupalo,
  • Hai-Qing Lin,
  • Kai-Ming Ho and
  • Michael C. Tringides

31 January 2013

Graphene, a single atomic layer of graphite, has been a material of recent intensive studies due to its novel electronic and structural properties and its potential applications in the emerging area of carbon-based electronic devices. Metal on graphe...

  • Review
  • Open Access
95 Citations
15,700 Views
30 Pages

30 January 2013

Magnetically-doped graphene systems are potential candidates for application in future spintronic devices. A key step is to understand the pairwise interactions between magnetic impurities embedded in graphene that are mediated by the graphene conduc...

  • Article
  • Open Access
6 Citations
8,525 Views
11 Pages

23 January 2013

The combined effects of an asymmetric (square or V-shaped) notch and uniaxial strain are studied in a zigzag graphene nanoribbon (ZGNR) device using a generalized tight-binding model. The spin-polarization and conductance-gap properties, calculated w...

  • Article
  • Open Access
9 Citations
6,585 Views
14 Pages

Bound States and Supercriticality in Graphene-Based Topological Insulators

  • Denis Klöpfer,
  • Alessandro De Martino and
  • Reinhold Egger

21 January 2013

We study the bound state spectrum and the conditions for entering a supercritical regime in graphene with strong intrinsic and Rashba spin-orbit interactions within the topological insulator phase. Explicit results are provided for a disk-shaped pote...

  • Article
  • Open Access
34 Citations
12,279 Views
10 Pages

Thermostability, Photoluminescence, and Electrical Properties of Reduced Graphene Oxide–Carbon Nanotube Hybrid Materials

  • Fuchi Liu,
  • Yong Cao,
  • Mingdong Yi,
  • Linghai Xie,
  • Wei Huang,
  • Nujiang Tang,
  • Wei Zhong and
  • Youwei Du

21 January 2013

Reduced graphene oxide–carbon nanotube (RGO–CNT) hybrid materials were prepared by a simple catalyst-free route. The thermostability, photoluminescence (PL) and electrical properties of RGO–CNTs were investigated systematically. The results revealed...

  • Article
  • Open Access
8 Citations
8,114 Views
13 Pages

Is the Registry Between Adjacent Graphene Layers Grown on C-Face SiC Different Compared to That on Si-Face SiC

  • Leif I. Johansson,
  • Chao Xia,
  • Jawad Ul Hassan,
  • Tihomir Iakimov,
  • Alexei A. Zakharov,
  • Somsakul Watcharinyanon,
  • Rositza Yakimova,
  • Erik Janzén and
  • Chariya Virojanadara

15 January 2013

Graphene grown on C-face SiC substrates using two procedures, high and low growth temperature and different ambients, was investigated using Low Energy Electron Microscopy (LEEM), X-ray Photo Electron Electron Microscopy (XPEEM), selected area Low En...

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Crystals - ISSN 2073-4352