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Crystals, Volume 15, Issue 4

April 2025 - 95 articles

Cover Story: Ferrocene derivatives and especially those incorporating the amide linkage are of interest across a wide range of scientific areas including bioorganometallic chemistry, molecular recognition and structural sciences. As such, five ferrocenylcarboxamide crystal structures (four of which contain fluorinated aromatic rings), show a diverse range of intermolecular interactions that influence molecular aggregation. Competition is noted between various intermolecular interactions with increasing aromatic fluorine content. This is particularly notable in the N-(ferrocenylmethyl)pentafluorobenzenecarboxamide structure where impressive cooperative amide–amide interactions and 1D columnar (Fc⋯C6F5R⋯)n stacking dominate in the crystal structure. View this paper
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Articles (95)

  • Article
  • Open Access
923 Views
13 Pages

Temperature-Dependent Optical Absorption and DLTS Study of As-Grown and Electron-Irradiated GaSe Crystals

  • Ruslan A. Redkin,
  • Nikolay I. Onishchenko,
  • Alexey V. Kosobutsky,
  • Valentin N. Brudnyi,
  • Xinyang Su and
  • Sergey Yu. Sarkisov

18 April 2025

Optical absorption spectra of 9 MeV electron-irradiated GaSe crystals measured at temperatures in the range from 9.5 to 300 K were analyzed. The absorption spectra with features caused by Ga vacancies in two charge states and direct interband transit...

  • Article
  • Open Access
988 Views
18 Pages

Molecular Structure and GPR35 Receptor Docking of 1,3-Phenylene Bis-Oxalamide Derivatives

  • Juan Saulo González-González,
  • José Martín Santiago-Quintana,
  • José Luis Madrigal-Angulo,
  • Lina Barragán-Mendoza,
  • Nancy E. Magaña-Vergara,
  • Efrén V. García-Báez,
  • Itzia Irene Padilla-Martínez and
  • Francisco Javier Martínez-Martínez

17 April 2025

A series of three 1,3-phenylene bis-oxamides 3a–c, structurally related to the GPR35 receptor-agonist drug lodoxamide, has been synthesized by reacting the 1,3-phenylene bis-oxalamates 2a and 2b with amines. The obtained compounds were characte...

  • Article
  • Open Access
693 Views
14 Pages

17 April 2025

By testing the creep properties of a Re/Ru-containing single-crystal alloy specimen and examining the microstructural evolution of the allow at different stages of creep using scanning electron microscopy (SEM) and transmission electron microscopy (T...

  • Communication
  • Open Access
571 Views
8 Pages

Quantitative Analysis of Shear Texture Evolution in Accumulative Roll Bonded AA 1060 Aluminum Alloy

  • Peng Du,
  • Chao Li,
  • Lei Liu,
  • Bao Chen,
  • Mingyu Li,
  • Zhijie Wang and
  • Sha Liu

17 April 2025

AA 1060 aluminum alloy underwent roll bonding with reductions of 25% and 35%, followed by accumulative roll bonding (ARB) for up to seven cycles at ambient temperature. The evolution of surface layer texture throughout the ARB process was analyzed us...

  • Article
  • Open Access
633 Views
11 Pages

17 April 2025

As an efficient energy storage solution, lithium-ion batteries (LIBs) play a crucial role in the electric vehicle sector, driving innovation and development in the automotive industry. One common strategy to enhance energy density is to manufacture t...

  • Article
  • Open Access
1 Citations
596 Views
18 Pages

Anisotropy of Voltage Sensitivity of Bow-Tie Microwave Diodes Containing 2DEG Layer

  • Algirdas Sužiedėlis,
  • Steponas Ašmontas,
  • Jonas Gradauskas,
  • Aurimas Čerškus,
  • Andžej Lučun,
  • Maksimas Anbinderis and
  • Ihor Zharchenko

17 April 2025

Microwave Bow-Tie Diodes operate across a broad frequency range, including THz radiation detection and THz imaging applications. When fabricated using modulation-doped structures, these diodes exhibit enhanced detection properties that are best chara...

  • Article
  • Open Access
682 Views
15 Pages

17 April 2025

The high sulfur content in kiln slag ceramsites leads to pronounced efflorescence, significantly limiting the application of such solid-waste-derived products in construction engineering. In this study, a sintering experiment of 50 kg ceramsites with...

  • Article
  • Open Access
2 Citations
809 Views
12 Pages

Enhanced Thermoelectric Properties in Cubic Sn0.50Ag0.25Bi0.25Se0.50Te0.50 via MWCNTs Incorporation

  • Zhewen Tan,
  • Zhaowei Zeng,
  • Junliang Zhu,
  • Wenying Wang,
  • Lin Bo,
  • Xingshuo Liu,
  • Changcun Li and
  • Degang Zhao

16 April 2025

Cubic-phase SnSe possesses exceptional crystal structure symmetry while maintaining non-harmonic bond characteristics and ultra-low lattice thermal conductivity, exhibiting superior thermoelectric (TE) application potential compared to its orthorhomb...

  • Review
  • Open Access
7 Citations
3,545 Views
33 Pages

Advances of Low-Dimensional Organic-Inorganic Hybrid Metal Halide Luminescent Materials: A Review

  • Suqin Wang,
  • Hui Zhu,
  • Ming Sheng,
  • Bo Shao,
  • Yu He,
  • Zhuang Liu and
  • Guangtao Zhou

16 April 2025

Low-dimensional organic–inorganic hybrid metal halides (OIMHs) have garnered significant research attention due to their remarkable optical, electrical, and mechanical properties. These materials feature tunable optoelectronic characteristics,...

  • Article
  • Open Access
779 Views
20 Pages

16 April 2025

As an advanced high-temperature structural material, TiAl alloy, is often used in the manufacturing of hot-end components of aviation and aerospace engines. However, it is difficult to increase the strength at high temperature, which limits its wider...

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Crystals - ISSN 2073-4352