Next Article in Journal
Influence of Crystal Plasticity Parameters on the Strain Hardening Behavior of Polycrystals
Next Article in Special Issue
Chitosan/Selenium Nanoparticles Attenuate Diclofenac Sodium-Induced Testicular Toxicity in Male Rats
Previous Article in Journal
Contact-Mediated Nucleation of Subcooled Droplets in Melt Emulsions: A Microfluidic Approach
Previous Article in Special Issue
Evaluation of Strength and Microstructural Properties of Heat Treated High-Molybdenum Content Maraging Steel
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Crystals
Volume 11
Issue 12
10.3390/cryst11121474
crystals-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

One Pot Ultrasonic Assisted {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}-3Cl.5H2O Complex Formation Using Triazine Ligand, XRD/HSA-Interactions, and Spectral and Thermal Investigation

by
Abeer A. AlObaid
1,
Ahmed Boshaala
2,
Younis O. Ben Amer
3,
Abrahem F. Abrahem
2,
Nabil Al-Zaqri
1,
Mohammed Suleiman
4,
Abdelkader Zarrouk
5,
Nawaf Al-Maharik
6,
Hussien A. Khamees
7 and
Ismail Warad
8,*
1
Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
2
Libyan authority for Scientific Research, Tripoli P.O. Box 80045, Libya
3
Chemistry Department, Faculty of Science, Benghazi University, Benghazi P.O. Box 1308, Libya
4
Department of Chemistry, Science College, An-Najah National University, Nablus P.O. Box 7, Palestine
5
Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University in Rabat, Agdal-Rabat, P.O. Box 1014, Rabat 11000, Morocco
6
School of Chemistry, Biomedical Sciences Research Complex, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK
7
Department of Medical Science, Community College—Abs, Abs P.O. Box 1, Yemen
8
Department of Chemistry and Earth Sciences, College of Arts and Sciences, Qatar University, Doha P.O. Box 2713, Qatar
*
Author to whom correspondence should be addressed.
Crystals 2021, 11(12), 1474; https://doi.org/10.3390/cryst11121474
Submission received: 27 October 2021 / Revised: 22 November 2021 / Accepted: 23 November 2021 / Published: 27 November 2021
(This article belongs to the Special Issue New Trends in Crystals at Saudi Arabia)
Browse Figures
Versions Notes

Abstract

Under room temperature ultrasonic conditions, mixing the neutral 2,4,6-tri(pyridin-2-yl)-1,3,5-triazine (tptz) ligand with Ni(II) salt resulted in the preparation of a unique {[Ni(tptz)Cl(H2O)2]-[Ni(tptz)(H2O)3]}3Cl.5H2O complex with two different nickel(II) centers in a high yield. The crystal structure of {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}3Cl.5H2O revealed the existence of distorted octahedral around both Ni(II) centers. The complex structure was further supported by FT-IR, UV-Vis., CHN-EA, TGA and EDX. The computed HSA was also performed to support the XRD interaction types. The existence of the H2O molecules in the crystal lattice was examined by FT-IR and TG/DTG measurements that proved the presence of coordinated and uncoordinated water molecules. Moreover, the thermal stability of the desired complex was evaluated at open atmosphere via TG/DTG and showed stability up to ~400 °C and multistep thermal decomposition.
Keywords: spectral; Ni(II) complex; tptz ligand; crystal structure spectral; Ni(II) complex; tptz ligand; crystal structure
Graphical Abstract

Share and Cite

MDPI and ACS Style

AlObaid, A.A.; Boshaala, A.; Ben Amer, Y.O.; Abrahem, A.F.; Al-Zaqri, N.; Suleiman, M.; Zarrouk, A.; Al-Maharik, N.; Khamees, H.A.; Warad, I. One Pot Ultrasonic Assisted {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}-3Cl.5H2O Complex Formation Using Triazine Ligand, XRD/HSA-Interactions, and Spectral and Thermal Investigation. Crystals 2021, 11, 1474. https://doi.org/10.3390/cryst11121474

AMA Style

AlObaid AA, Boshaala A, Ben Amer YO, Abrahem AF, Al-Zaqri N, Suleiman M, Zarrouk A, Al-Maharik N, Khamees HA, Warad I. One Pot Ultrasonic Assisted {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}-3Cl.5H2O Complex Formation Using Triazine Ligand, XRD/HSA-Interactions, and Spectral and Thermal Investigation. Crystals. 2021; 11(12):1474. https://doi.org/10.3390/cryst11121474

Chicago/Turabian Style

AlObaid, Abeer A., Ahmed Boshaala, Younis O. Ben Amer, Abrahem F. Abrahem, Nabil Al-Zaqri, Mohammed Suleiman, Abdelkader Zarrouk, Nawaf Al-Maharik, Hussien A. Khamees, and Ismail Warad. 2021. "One Pot Ultrasonic Assisted {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}-3Cl.5H2O Complex Formation Using Triazine Ligand, XRD/HSA-Interactions, and Spectral and Thermal Investigation" Crystals 11, no. 12: 1474. https://doi.org/10.3390/cryst11121474

APA Style

AlObaid, A. A., Boshaala, A., Ben Amer, Y. O., Abrahem, A. F., Al-Zaqri, N., Suleiman, M., Zarrouk, A., Al-Maharik, N., Khamees, H. A., & Warad, I. (2021). One Pot Ultrasonic Assisted {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}-3Cl.5H2O Complex Formation Using Triazine Ligand, XRD/HSA-Interactions, and Spectral and Thermal Investigation. Crystals, 11(12), 1474. https://doi.org/10.3390/cryst11121474

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop