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Catalysts, Volume 5, Issue 1

March 2015 - 24 articles

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Articles (24)

  • Article
  • Open Access
18 Citations
8,268 Views
18 Pages

Structural Evolution under Reaction Conditions of Supported (NH4)3HPMo11VO40 Catalysts for the Selective Oxidation of Isobutane

  • Fangli Jing,
  • Benjamin Katryniok,
  • Elisabeth Bordes-Richard,
  • Franck Dumeignil and
  • Sébastien Paul

23 March 2015

When using heteropolycompounds in the selective oxidation of isobutane to methacrolein and methacrylic acid, both the keeping of the primary structure (Keggin units) and the presence of acidic sites are necessary to obtain the desired products. The s...

  • Article
  • Open Access
19 Citations
8,269 Views
18 Pages

Design of Cobalt Nanoparticles with Tailored Structural and Morphological Properties via O/W and W/O Microemulsions and Their Deposition onto Silica

  • Gabriella Di Carlo,
  • Matteo Lualdi,
  • Anna M. Venezia,
  • Magali Boutonnet and
  • Margarita Sanchez-Dominguez

19 March 2015

Cobalt nanostructures with different size and morphology, i.e., spherical nanoparticles, nanorods, and particles arranged into elongated structures, were prepared using micelles and microemulsions as confined reaction media. The syntheses were carrie...

  • Article
  • Open Access
67 Citations
9,289 Views
18 Pages

16 March 2015

Molybdenum carbide was supported on three types of carbon support—activated carbon; multi-walled carbon nanotubes; and carbon nanofibers—using ammonium molybdate and molybdic acid as Mo precursors. The use of activated carbon as support afforded an X...

  • Article
  • Open Access
30 Citations
7,593 Views
14 Pages

13 March 2015

Platinum catalysts supported on carbon xerogel and carbon black (Vulcan) were synthesized with the aim of investigating the influence of the characteristics of the support on the electrochemical performance of the catalysts. Three synthesis methods w...

  • Article
  • Open Access
16 Citations
7,205 Views
18 Pages

Structural Evolution of Molybdenum Carbides in Hot Aqueous Environments and Impact on Low-Temperature Hydroprocessing of Acetic Acid

  • Jae-Soon Choi,
  • Viviane Schwartz,
  • Eduardo Santillan-Jimenez,
  • Mark Crocker,
  • Samuel A. Lewis,
  • Michael J. Lance,
  • Harry M. Meyer and
  • Karren L. More

13 March 2015

We investigated the structural evolution of molybdenum carbides subjected to hot aqueous environments and their catalytic performance in low-temperature hydroprocessing of acetic acid. While bulk structures of Mo carbides were maintained after aging...

  • Review
  • Open Access
56 Citations
13,747 Views
26 Pages

12 March 2015

Perovskite oxides La1−xSrxCo1−yFeyO3–δ (LSCF) have been extensively investigated and developed as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFCs) due to mixed ionic–electronic conductivity and high electrooxygen redu...

  • Article
  • Open Access
15 Citations
9,476 Views
17 Pages

11 March 2015

We here report a computational approach on the mechanism of allylicamination reactions using allyl-alcohols and amines as the substrates and phosphoramidite palladium catalyst 1a, which operates in the presence of catalytic amount of 1,3-diethylurea...

  • Article
  • Open Access
26 Citations
10,423 Views
12 Pages

Ni-CeO2/C Catalysts with Enhanced OSC for the WGS Reaction

  • Laura Pastor-Pérez,
  • Tomás Ramírez Reina,
  • Svetlana Ivanova,
  • Miguel Ángel Centeno,
  • José Antonio Odriozola and
  • Antonio Sepúlveda-Escribano

6 March 2015

In this work, the WGS performance of a conventional Ni/CeO2 bulk catalyst is compared to that of a carbon-supported Ni-CeO2 catalyst. The carbon-supported sample resulted to be much more active than the bulk one. The higher activity of the Ni-CeO2/C...

  • Review
  • Open Access
109 Citations
24,912 Views
39 Pages

6 March 2015

The oxygen reduction reaction (ORR) is the oldest studied and most challenging of the electrochemical reactions. Due to its sluggish kinetics, ORR became the major contemporary technological hurdle for electrochemists, as it hampers the commercializa...

  • Article
  • Open Access
27 Citations
8,184 Views
12 Pages

5 March 2015

An extra-heavy crude oil underground upgrading concept and laboratory experiments are presented which involve the addition of a hydrogen donor (tetralin) to an Orinoco Basin extra-heavy crude oil under steam injection conditions (280–315 °C and resid...

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Catalysts - ISSN 2073-4344