Effect of Ce and Zr Addition to Ni / SiO 2 Catalysts for Hydrogen Production through Ethanol Steam Reforming

A series of Ni/CexZr1−xO2/SiO2 catalysts with different Zr/Ce mass ratios were prepared by incipient wetness impregnation. Ni/SiO2, Ni/CeO2 and Ni/ZrO2 were also prepared as reference materials to compare. Catalysts’ performances were tested in ethanol steam reforming for hydrogen production and characterized by XRD, H2-temperature programmed reduction (TPR), NH3-temperature programmed desorption (TPD), TEM, ICP-AES and N2-sorption measurements. The Ni/SiO2 catalyst led to a higher hydrogen selectivity than Ni/CeO2 and Ni/ZrO2, but it could not maintain complete ethanol conversion due to deactivation. The incorporation of Ce or Zr prior to Ni on the silica support resulted in catalysts with better performance for steam reforming, keeping complete ethanol conversion over time. When both Zr and Ce were incorporated into the catalyst, CexZr1−xO2 solid solution was formed, as confirmed by XRD analyses. TPR results revealed stronger Ni-support interaction in the CexZr1−xO2-modified catalysts than in Ni/SiO2 one, which can be attributed to an increase of the dispersion of Ni species. All of the Ni/CexZr1−xO2/SiO2 catalysts exhibited good catalytic activity and stability after 8 h of time on stream at 600 ◦C . The best catalytic performance in terms of hydrogen selectivity was achieved when the Zr/Ce mass ratio was three.


Introduction
Energy sustainability and reduction of CO 2 emissions will be joined with a decrease in fossil fuel use and the development of green energies.In this sense, hydrogen could be the energy carrier of the future due to its clean and non-polluting nature [1][2][3][4].However, the current hydrogen production routes imply the use of fossil fuel-derived products, like methane, as feedstock and, for this reason, the search of new alternatives for hydrogen production based on renewable resources is essential [5].In line with this, hydrogen production from ethanol steam reforming is an attractive option, since ethanol can be obtained from a wide variety of biomass feedstocks, and therefore, it can minimize CO 2 emissions.In addition, ethanol has a high H/C atomic ratio, low toxicity and can be easily and safely manipulated and transported [6,7].
The ethanol steam reforming process (ESR) can be represented by the following equation: which involves several steps.The main reaction mechanism comprises dehydrogenation or dehydration routes, which implies the formation of intermediates, like acetylene or ethylene, respectively.Coke formation reactions also participate in the reaction pathway leading to catalyst deactivation [8][9][10].
Ethanol steam reforming has been investigated using different catalysts [10,11].In fact, Ni/SiO 2 has been widely used, because it provides good activity and, at the same time, high selectivity to H 2 and CO x at a relatively low cost [12][13][14][15][16][17][18][19].This catalytic behavior cannot only be ascribed to the nickel active phase, since the support also affects catalysts activity and product distribution [11,[15][16][17][18].In this sense, the use of silica in Ni-Cu-supported catalysts gave better results in comparison to other carrier materials, like alumina and MCM-41 [20].Despite the good catalytic performance, the literature also describes that Ni/SiO 2 can be deactivated along time on stream, by metal sintering and coke deposition.
Trying to get over this drawback, a number of attempts have been made to prevent deactivation by modifying catalysts through the addition of different elements [16][17][18].In this sense, increasing attention has been given to CeO 2 or ZrO 2 -CeO 2 mixed oxide, because the oxygen mobility improves catalytic stability through coke gasification [9,11,[21][22][23][24].However, CeO 2 and ZrO 2 -CeO 2 oxides have a very low surface area to be used as catalytic supports.To increase the textural properties, silica has been incorporated to ZrO 2 -CeO 2 [25,26], and the literature also reports how CeO 2 or ZrO 2 -CeO 2 were supported on silica to be used in catalytic applications [27,28].Other researchers describe the addition of ZrO 2 to ceria and silica to increase their thermal resistance and prevent the growth of Ni crystallites [29][30][31].
Based on the above premises, this work proposes the use of Ce-and Zr-oxides as promoters in the synthesis of Ni/SiO 2 catalyst to reduce catalyst deactivation, allowing nickel particles to accommodate on a porous support in order to avoid or minimize the sinterization of the metallic phase.

Ethanol Steam Reforming over Reference Catalysts
Commercial silica, ceria and zirconia with BET surface areas of 276, 64 and 20 m 2 /g, respectively, were used as supports of the reference catalysts.The physicochemical properties of the catalyst obtained after the incorporation of nickel into these supports are summarized in Table 1.The actual nickel content measured by ICP-AES was near the nominal loading.Compared to the supports, the BET surface area of the catalysts decreased, although the trend is maintained, Ni/S >Ni/C >Ni/Z.Since the catalyst acidity can influence the products' distribution in the steam reforming reaction, it was measured by NH 3 -TPD, verifying that only the Ni/Z catalyst exhibited measurable acidity with a desorption peak around 220 • C , corresponding to 0.275 meq-NH 3 /g.
Figure 1 shows the XRD diffractograms of the calcined and reduced catalysts, where peaks corresponding to the carrier materials and those associated with the Ni phase can be observed.For calcined samples, reflections corresponding to the planes (111), ( 200  The TPR analysis of calcined reference catalysts is shown in Figure 2. The profiles show a main peak between 270 and 350 • C , attributed to the reduction of NiO particles to Ni.In the case of the Ni/C and Ni/Z samples, the maximum of the reduction peak is placed at lower temperatures, and also, an additional shoulder can be observed, which is attributed to a fraction of the NiO particles strongly interacting with the support.Finally, in the case of the Ni/C sample, another peak arises around 800 • C , due to the partial reduction of Ce 4+ to Ce 3+ [21].TPR analysis of the supports (not shown) demonstrated that, under our experimental conditions, only ceria may give rise to hydrogen consumption with maxima at 800 • C , corresponding to the diffusion-limited partial reduction of bulk CeO 2 particles.The low reduction temperature of Ni/C and Ni/Z catalysts suggests also a weaker metal support interaction in these two catalysts.Temperature programmed reduction (TPR) profiles of the calcined reference catalysts.
Table 2 summarizes the results obtained for the ethanol steam reforming reaction after 8 h of time on stream (TOS).While the Ni/C sample kept ethanol conversion above 99%, it decreased to 95.0% and 97.1% after 8 h TOS for the Ni/Z and Ni/S samples, respectively.Regarding intermediate products, acetaldehyde can be detected when using Ni/S and Ni/C, while ethylene is found with the Ni/Z sample due to the presence of acid sites, favoring the ethanol dehydration reaction.Methane selectivity decreases as hydrogen selectivity increases, indicating that methane steam reforming is one of the main steps in the ethanol steam reforming reaction mechanism.Thus, a slight hydrogen selectivity is reached by the Ni/S catalyst in comparison with the rest of samples.Based on the above results and taking into account that silica is a porous support that could accommodate Ce an Zr oxides, the next study was the modification of Ni/SiO 2 catalysts by Ce or Zr addition.

Characterization of Ce-or Zr-Modified Silica
For this study, four silica-supported Ni catalysts were prepared and modified by Ce or Zr addition, both before and after the incorporation of Ni.Thus, amorphous silica was used as the support of the Ce and Zr phases, and the XRD patterns of the resulting materials are shown in Figure 3, together with that of the Ni/S sample (described in Section 2.1), where Ce and Zr were later incorporated.
In the case of the CeS sample, the main diffraction peaks characteristic of the planes (111), ( 200), ( 220) and (311) of cubic CeO 2 (JCPDS 89-8436) are observed at 2θ = 28.5 • , 33.0 • , 47.5 • and 56.3 • .On the other hand, in the diffraction pattern corresponding to the ZrS sample, no clear peaks of Zr species can be seen, although a small broad slope appears around 2θ = 30.2• , which may be attributed to the plane (101) of highly dispersed ZrO 2 in the tetragonal phase (JCPDS 80-0784).This suggests that while Ce trends to aggregate into CeO 2 particles [16], Zr trends to form ZrO 2 crystallites too small to be detected by XRD.This fact agrees with the results published by Sánchez-Sánchez et al. [15] with Zr/Al 2 O 3 , where for Zr loadings up to 6.6 µmol Zr/m 2 , Zr ions exists in atomic dispersion.The BET surface area of CeS and ZrS was 267 and 227 m 2 /g, respectively, slightly lower in comparison to the silica used as the support, due to the metals' incorporation.Finally, TPR analysis of CeS and ZrS materials (not shown) evidenced that no detectable hydrogen consumption occurs at the metal loading used in this study (around 10 wt%), in spite of the partial reduction observed for the bulk CeO 2 used as a support in Section 2.1.The physicochemical properties of the prepared Ni catalysts are summarized in Table 3. ICP-AES analysis revealed that silica support was loaded with near the desired amounts of Ni, Ce and Zr.Although the incorporation of a second metal into the previously described materials slightly decreased the value of their textural properties, all of the catalysts exhibited a high BET surface area.The acidity of the materials was measured by NH 3 -TPD and is summarized in Table 3. Ce/NiS and Ni/CeS catalysts show negligible acidity, while Zr incorporation into silica support results in the presence of acid sites, which is more pronounced when Zr is incorporated after Ni, probably due to easier accessibility to these acid sites (not covered by Ni).
The XRD spectra of the calcined and reduced catalysts are shown in  3. Concerning the calcined samples, both Ce-and Zr-modified catalysts have slightly larger NiO crystallites than the unmodified Ni/S sample (Table 1), mainly when Ni is added to catalyst after Ce or Zr.A similar trend is found for the reduced samples.However, while the Ni phase crystallite size increases after the reduction process for the Ce-modified samples, attributed to the thermal effect, the addition of Zr leads even to a slight reduction of the crystallite size, which may be attributed to higher thermal stability together with lattice contraction from NiO to Ni due to the different molar volumes of these phases.The reducibility of these catalysts was determined by H 2 -TPR experiments.The profiles shown in Figure 5 exhibit more than one peak attributed to the direct reduction of Ni 2+ species to Ni, which means the presence of different reducible nickel species depending on the interaction with the support.Quantitative analysis of the TPR profiles revealed total reduction of the Ni 2+ species for all of the samples.As in the case of the Ni/S sample (Figure 2), the peak at the lower temperature is attributed to the typical reduction of NiO to Ni, which may correspond to relatively large NiO particles, while the shoulder at the higher temperature is ascribed to nickel species in close contact with the support [22,23].The Ce/NiS sample presents a lower reduction temperature than Ni/S catalyst, indicating the promotion of Ni reducibility by CeO 2 incorporation, an effect typically found for lanthanide elements [16].On the contrary, reduction of the Zr/NiS sample takes place at higher temperatures, which may indicate an intimate contact between the Ni phase and the promoter due to partial covering of the NiO particles by the highly-dispersed Zr phase added to the Ni/S sample.On the other hand, when Ni was impregnated after Ce or Zr, reduction occurs in a broad temperature range, similarly to the reduction of Ni/S (Figure 2).A shoulder arises in the profile of the Ni/CeS catalyst at slightly lower temperatures than the beginning of the reduction of the Ni/S sample, probably due to the presence of oxygen vacancies in CeO 2 , promoting the reduction of NiO [24,32], an effect facilitated by the small dimensions of the CeO 2 crystallites (Table 3).The profile corresponding to the Ni/ZrS sample reaches higher temperatures, probably due to the easier contact between NiO and ZrO 2 , which is well dispersed over the support, unlike the CeO 2 particles, as the XRD patterns evidenced.The shift of the Zr-modified catalysts profiles to higher reduction temperatures in comparison to the rest of the samples indicates higher thermal stability and accounts for the decrease in the Ni phase crystallite size after the reduction of the catalyst, as previously observed from the XRD results.

Catalytic Results Using Ni/SiO 2 Catalysts Modified by Ce or Zr
The catalytic results obtained by these catalysts after 8 h of TOS on ethanol steam reforming at 600 • C are shown in Table 4. Complete ethanol conversion was maintained over all of the catalysts, except in the case of the Ce/NiS sample, whereas it slightly decreased up to 98.5 after 8 h.On the other hand, hydrogen selectivity is lower for the samples where incorporation of Ni was carried out before the addition of the Ce or Zr, which may be due to some Ni particles covered by the promoters.This effect is more pronounced in the case of the Zr/NiS sample, which reached the lowest hydrogen selectivity, due to the high dispersion of the Zr phase, probably in the form of an overlayer over the Ni particles.However, total ethanol conversion is achieved with this sample, because the acidic nature of this catalyst favors ethanol dehydration to ethylene, as observed from the relatively high C 2 H 4 amount obtained among the products.Ethylene selectivity is smaller for the Ni/ZrS sample, as expected from its lower acidity (Table 3).Therefore, regarding the impregnation order of the different elements, the incorporation of Ce or Zr before Ni on SiO 2 leads to lower selectivity to intermediate products and, consequently, higher selectivity towards the main products (H 2 and CO 2 ).This may be ascribed to the easier accessibility of reactants to the Ni sites.Finally, the CO 2 /CO ratio among the gaseous products is increased by the presence of CeO 2 , since it favors the water-gas shift reaction [33,34].The results shown in Table 4 indicate that coke formation occurs at a much higher rate on Zr-modified catalysts, because, as explained above, the acid sites joined with the presence of Zr promote ethanol dehydration to ethylene, which acts as a hard precursor for carbon deposition [35].Although the highest coke amount was found on the Ni/ZrS sample, no loss of activity was observed for this sample, since carbon was deposited in the form of nanofibers (Figure 6).This type of coke does not embed metal particles [36], keeping the metal surface accessible for reactants, which, together with the high surface area of the silica support to accommodate large amounts of coke, has been described to have a minor effect on catalyst deactivation [37,38].However, high coke formation is not desirable, because it would probably result in reactor plugging.On the other hand, when Ce was added over the Ni/S sample (Ce/NiS), coke formation diminished as a consequence of the enhancement of carbon gasification by CeO 2 [16,22].However, in the case of the Ni/CeS sample, this reduction of the coke amount is not observed, due to the higher Ni particles of the catalyst that favors the growth of carbon nanofibers [39,40].5, where it can be observed that there is a good agreement between the metal contents determined by ICP-AES and the theoretical values.All of the catalysts show a high surface area in comparison to the values corresponding to the Ni/C and Ni/Z catalysts (Table 1), as expected from the use of silica as a support.However, they exhibit lower BET surface areas than the Ni/S sample, with a slight decreasing trend as the Zr content increases (Table 3).As expected, the acidity of the materials measured by NH 3 -TPD increased with the Zr loading, the Ni/ZrS catalyst having the highest number of acid sites.The XRD spectra of the calcined and reduced catalysts are shown in Figure 7, where samples containing both Ce and Zr have a pattern similar to that of Ni/CeS sample (Figure 4), but CeO 2 peaks become less intense and shift to higher 2θ values with increasing Zr loading.This fact has been ascribed to the formation of a Ce x Zr 1−x O 2 solid solution, where the unit cell parameter changes with the Zr/Ce ratio [21,23,26].The size of the CeO 2 crystallites on calcined catalysts were calculated from the width of the (220) characteristic peak.The values displayed in Table 5 show that crystallites found on these catalysts are smaller than those reported for unsupported Ce x Zr 1−x O 2 [21], which evidences that the relatively high surface area of SiO 2 enhances their dispersion, and their sizes become smaller as the Zr/Ce ratio increases.Only a slight increment of these particles sizes (≈ 0.1-0.3nm) was detected after reduction treatment.
Additionally, the peaks characteristic of cubic NiO (JCPDS 78-0643) and those corresponding to metallic Ni (JCPDS 70-1849) can be observed for the calcined and reduced samples, respectively.Concerning the calcined samples, the mean NiO crystallites sizes, calculated by applying the Scherrer equation to the broadening of the (200), are summarized in Table 5.The NiO crystallite size decreases as the Zr content is increased, which has been previously reported for unsupported Ce  The reducibility of these catalysts was determined by H 2 -TPR experiments, and the corresponding profiles shown in Figure 8 evidenced a similarity with those of the Ni/CeS and Ni/ZrS samples.These profiles have a peak at a lower temperature due to the reduction of NiO particles and a shoulder at a higher temperature ascribed to the reduction of nickel species in close contact with the support.Quantitative analysis of the TPR profiles revealed total reduction of the Ni 2+ species for all of the samples.By increasing the ZrO 2 content, the reduction profiles slightly shift towards higher temperatures, and this peak area increases while the area under the low temperature zone decreases.This fact indicates a stronger interaction of Ni 2+ species with the support as ZrO 2 loading increases [15,18,19], which accounts for the hindered sintering of the Ni phase when Zr loading increases, as observed from the difference between the mean size of the nickel phase crystallites before and after reduction (see Table 5).The decrease of the Ce x Zr 1−x O 2 particle size as the Zr loading increases would make it possible for a higher contact between this phase and the NiO, which results in higher metal-support interaction [16].6.All of the catalysts showed complete ethanol conversion after 8 h of TOS.On the other hand, it can be observed how product selectivity depends on the Zr/Ce ratio.The only H-containing intermediate compound found among the reaction products was methane, while neither ethylene nor acetaldehyde could be detected.Besides, as the Zr/Ce ratio is increased, selectivity towards CH 4 decreases, and thus, hydrogen selectivity increases.This may be attributed to both a decrease of Ni crystallite size and an increase of thermal stability when the Zr content increases, as determined by XRD and TPR (Table 5 and Figure 8).Regarding the CO 2 /CO ratio, it is higher for Ni/Ce x Zr 1−x O 2 /SiO 2 catalysts than for the Ni/S sample and increases with the Zr/Ce ratio.An enhanced oxygen storage capacity due to the formation of the Ce x Zr 1−x O 2 solid solution has been reported to favor the water-gas shift reaction [23,26].Finally, Table 6 compares catalysts in terms of coke formation, which decreases as the Zr/Ce mass ratio in the catalyst increases.However, since ceria and zirconia improve oxygen mobility [32,41,42], favoring carbon gasification, coke deposition on promoted catalysts decreased by increasing Zr content in the Ce x Zr 1−x O 2 solution, which agrees with the smaller size of NiO and Ni crystallites found in samples with a higher Zr content.

Catalysts Preparation
A series of catalysts were prepared to study the effect of the addition of Ce and Zr to Ni/SiO 2 catalyst (Ni: 7 wt%).The modified catalysts contain a total loading of Ce and Zr of 10 wt% and Ce/Zr mass ratios of 0, 1/3, 1, 3 and ∞.Moreover, the order of the Ce or Zr incorporation with SiO 2 , before or after Ni addition, was also studied.The addition of metals was accomplished by incipient wetness impregnation of amorphous silica (Ineos, Warrington, UK) with aqueous solutions of the metal precursors: After the incorporation of each metal (Ni, Zr or Ce), the solid sample was air-dried overnight and further calcined at 500 • C for 5 h with a heating rate of 1.8 • C /min.Afterwards, the addition of the other metal, if needed, was carried out by following the same procedure.Ni/SiO 2 , Ni/CeO 2 and Ni/ZrO 2 were prepared as reference materials by impregnation of Ni over commercial silica (Ineos, Warrington, UK), ceria (Riedel-de-Haën, Hanover, Germany) and zirconia (Sigma-Aldrich, St. Louis, MO, USA).Catalyst are denoted as A/BY-x, where A/B are the metals added to the support (A, secondly, and B, firstly added), Y is the support (S: silica, C: ceria and Z: zirconia), and x is the Zr/Ce mass ratio in the final sample.

Catalysts Characterization
X-ray powder diffraction (XRD) analysis was used to find out the crystalline phases and calculate mean crystallite size in the calcined and reduced catalysts.Measurements were carried out on a Phillips (Eindhoven, The Netherlands) X'Pert PRO diffractometer using Cu Kα radiation.The patterns were recorded with a 2θ increment step of 0.020 • and a collection time of 2 s.Mean metallic crystallite diameters were calculated by applying the Scherrer equation.
The inductively-coupled plasma atomic emission spectroscopy (ICP-AES) technique was used to determine the total Ce, Zr and Ni content in the catalysts using a Varian (Palo Alto, CA, USA) VISTA-PRO AX CCD-Simultaneous ICP-AES spectrophotometer.Samples were previously dissolved with an acidic solution (HF and H 2 SO 4 ).
Textural properties of the materials were calculated by nitrogen adsorption-desorption at 77 K in a Micromeritics (Norcross, GA, USA) TRISTAR 2050 sorptometer.Samples were first outgassed under vacuum at 200 • C for 4 h.Surface areas were determined using the BET method.
Acid properties of the catalysts and supports were obtained by ammonia temperature programmed desorption analysis (NH 3 -TPD) in a Micromeritics (Norcross, GA, USA) Autochem 2910 equipment.gasification.Concerning the impregnation order, the incorporation of Ce and Zr prior to nickel on the silica support led to steam reforming catalysts with better performance.When both Zr and Ce were incorporated into Ni/SiO 2 , a Ce x Zr 1−x O 2 solid solution was formed, increasing the Ni-support interaction and producing smaller Ni crystallites as the Zr/Ce mass ratio increased.As a result, complete ethanol conversion and hydrogen selectivity above 84 mol% were reached with the Ni/Ce x Zr 1−x O 2 /SiO 2 catalysts.Concretely, using a Zr/Ce mass ratio of three, a trade-off between high selectivity to the main products, relatively low coke deposition and high thermal stability was achieved.
) and (220) of cubic NiO can be observed at 2θ = 37.3 • , 43.3 • and 62.9 • (JCPDS 78-0643), while peaks attributed to the planes (111) and (200) of metallic Ni appear at 2θ = 44.4• and 51.8 • (JCPDS 70-1849) for the reduced catalysts.The intensity of these reflections is hardly noticeable in the case of the Ni/C sample and overlap with ZrO 2 peaks in the Ni/Z sample.Apart from the diffraction of the Ni phase, the pattern of Ni/S shows only one diffuse reflection around 2θ values of 22.5 • , typical of certain amorphous materials, while diffraction peaks corresponding to cubic cerium (IV) oxide (JCPDS 89-8436; 2θ = 28.5 • , 33.0 • , 47.5 • , 56.3 • , 59.1 • and 69.3 • ) can be clearly observed for Ni/C, and those corresponding to a mixture of monoclinic and tetragonal zirconium (IV) oxide (JCPDS 74-1200 and 80-0784, respectively; main peaks at 2θ = 28.3• , 31.5 • and 50.2 • ) are seen for the Ni/Z catalyst.These analyses were used to calculate the Ni phase crystallites size of the Ni/S sample from the NiO(200) reflection at 2θ = 43.3• and the Ni(111) reflection at 2θ = 44.4

Figure 1 .
Figure 1.XRD patterns of the calcined (a) and reduced (b) reference catalysts.

Figure 2 .
Figure 2.Temperature programmed reduction (TPR) profiles of the calcined reference catalysts.

Figure 3 .
Figure 3. XRD patterns of the Ce-and Zr-modified silica supports.

Figure 4 .
All of the calcined samples exhibit the peaks characteristic of cubic NiO (JCPDS 78-0643) at 2θ = 37.3 • , 43.3 • and 62.9 • , while the reduced samples show the reflections corresponding to metallic Ni (JCPDS 70-1849) at 2θ = 44.4• and 51.8 • .As observed for the corresponding modified support, the main diffraction peaks characteristic of cubic CeO 2 appear in the case of the Ni/CeS and Ce/NiS catalysts, and the broad slope attributed to highly-dispersed ZrO 2 can be seen for the Zr/NiS and Ni/ZrS catalysts.The mean size of the CeO 2 particles, calculated by means of the Scherrer equation, resulted in being higher for the Ce/NiS sample, which indicates that CeO 2 particles are better dispersed on silica than on Ni/S.Regarding the Ni phase, the mean crystallite sizes are summarized in Table

a
ICP-AES measurements; b NH 3 -TPD analysis; c calculated from the (220) reflection of CeO 2 in XRD; d calculated from the (200) reflection of NiO in XRD; e calculated from the (111) reflection of Ni in XRD.

Figure 6 .
Figure 6.TEM image of coke formed on catalysts after being used for ethanol steam reforming for 8 h: (a) Ni/S; (b) Ce/NiS; (c) Ni/ZrS.

x
Zr 1−x O 2 catalysts [15,20].In the case of the reduced samples, the Ni crystallite sizes follow a similar trend.It is noticeable that Ni crystallites of the reduced Ni/CeZrS-1 and Ni/CeZrS-3 catalysts are smaller than the Ni particles of the corresponding calcined samples and even smaller than Ni crystallites of Ni/S catalyst, Ni/CeZrS-3 being the catalyst with the smallest Ni crystallites.

Table 1 .
Physicochemical properties of the reference catalysts.
a ICP-AES; b NH 3 -temperature programmed desorption (TPD) analysis; c calculated from the (200) reflection of NiO in XRD; d calculated from the (111) reflection of Ni in XRD.
• (Table1).However, accurate crystallite diameters could not be calculated, neither for the Ni/C sample, due to the low intensity of the diffraction lines, nor for the Ni/Z sample, where Ni species peaks overlapped with those of ZrO 2 .

Table 3 .
Physicochemical properties of the Ni/SiO 2 catalysts modified by Ce or Zr.Ce a Zr a S BET
a ICP-AES measurements; b NH 3 -TPD analysis; c calculated from the (220) reflection of CeO 2 in XRD; d calculated from the (200) reflection of NiO in XRD; e calculated from the (111) reflection of Ni in XRD.