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Materials, Volume 7, Issue 4

2014 April - 47 articles

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Articles (47)

  • Article
  • Open Access
6 Citations
7,066 Views
18 Pages

Quantitative Study of Porosity and Pore Features in Moldavites by Means of X-ray Micro-CT

  • Giovanni Pratesi,
  • Stefano Caporali,
  • Francesca Loglio,
  • Gabriele Giuli,
  • Lenka Dziková and
  • Roman Skála

24 April 2014

X-ray micro-computer aided tomography (μ-CT), together with optical microscopy and imaging, have been applied to the study of six moldavite samples. These techniques enabled a complete characterization to be made of the textural features of both Muon...

  • Article
  • Open Access
6 Citations
8,451 Views
14 Pages

Limits of ZnO Electrodeposition in Mesoporous Tin Doped Indium Oxide Films in View of Application in Dye-Sensitized Solar Cells

  • Christian Dunkel,
  • Till Von Graberg,
  • Bernd M. Smarsly,
  • Torsten Oekermann and
  • Michael Wark

23 April 2014

Well-ordered 3D mesoporous indium tin oxide (ITO) films obtained by a templated sol-gel route are discussed as conductive porous current collectors. This paper explores the use of such films modified by electrochemical deposition of zinc oxide (ZnO)...

  • Article
  • Open Access
24 Citations
8,526 Views
14 Pages

Distributional Fate of Elements during the Synthesis of Zeolites from South African Coal Fly Ash

  • Pieter W. Du Plessis,
  • Tunde V. Ojumu,
  • Ojo O. Fatoba,
  • Richard O. Akinyeye and
  • Leslie F. Petrik

23 April 2014

The synthesis of zeolites from South African coal fly ash has been deemed a viable solution to the growing economical strain caused by the disposal of ash in the country. Two synthesis routes have been studied thus far namely the 2-step method and th...

  • Article
  • Open Access
13 Citations
5,560 Views
11 Pages

Aggregates of Chemically Functionalized Multiwalled Carbon Nanotubes as Viscosity Reducers

  • Angelo Petriccione,
  • Mauro Zarrelli,
  • Vincenza Antonucci and
  • Michele Giordano

22 April 2014

Confinement and surface effects provided by nanoparticles have been shown to produce changes in polymer molecules affecting their macroscopic viscosity. Nanoparticles may induce rearrangements in polymer conformation with an increase in free volume s...

  • Article
  • Open Access
20 Citations
7,662 Views
12 Pages

22 April 2014

Surface modification with oxide nanostructures is one of the efficient ways to improve physical or biomedical properties of shape memory alloys. This work reports a fabrication of highly ordered Ti-Ni-O nanotube arrays on Ti-Ni alloy substrates throu...

  • Review
  • Open Access
40 Citations
11,567 Views
17 Pages

22 April 2014

Fullerene derivatives have been widely used for conventional acceptor materials in organic photovoltaics (OPVs) because of their high electron mobility. However, there are also considerable drawbacks for use in OPVs, such as negligible light absorpti...

  • Article
  • Open Access
13 Citations
7,291 Views
16 Pages

21 April 2014

Energy-dispersive X-ray microanalysis (EDX) is a technique for determining the distribution of elements in various materials. Here, we report a protocol for high-spatial-resolution X-ray elemental imaging and quantification in plant tissues at subce...

  • Article
  • Open Access
52 Citations
8,632 Views
22 Pages

Corrosion Behavior of Steel Reinforcement in Concrete with Recycled Aggregates, Fly Ash and Spent Cracking Catalyst

  • Hebé Gurdián,
  • Eva García-Alcocel,
  • Francisco Baeza-Brotons,
  • Pedro Garcés and
  • Emilio Zornoza

21 April 2014

The main strategy to reduce the environmental impact of the concrete industry is to reuse the waste materials. This research has considered the combination of cement replacement by industrial by-products, and natural coarse aggregate substitution by...

  • Review
  • Open Access
320 Citations
27,808 Views
53 Pages

21 April 2014

Metal-organic frameworks (MOFs) are a new class of microporous materials that possess framework flexibility, large surface areas, “tailor-made” framework functionalities, and tunable pore sizes. These features empower MOFs superior performances and b...

  • Review
  • Open Access
296 Citations
25,243 Views
30 Pages

Gelatin-Based Materials in Ocular Tissue Engineering

  • James B. Rose,
  • Settimio Pacelli,
  • Alicia J. El Haj,
  • Harminder S. Dua,
  • Andrew Hopkinson,
  • Lisa J. White and
  • Felicity R. A. J. Rose

17 April 2014

Gelatin has been used for many years in pharmaceutical formulation, cell culture and tissue engineering on account of its excellent biocompatibility, ease of processing and availability at low cost. Over the last decade gelatin has been extensively e...

  • Article
  • Open Access
13 Citations
6,817 Views
11 Pages

17 April 2014

Micro cracks occurring in concrete around tensile rebar is well known latent damage phenomenon. These micro cracks develop, and can be detected after reaching the surface of the concrete. Detection of these cracks before they are fully formed is pref...

  • Article
  • Open Access
42 Citations
9,365 Views
13 Pages

Characterization of High-k Nanolayers by Grazing Incidence X-ray Spectrometry

  • Matthias Müller,
  • Philipp Hönicke,
  • Blanka Detlefs and
  • Claudia Fleischmann

17 April 2014

The accurate characterization of nanolayered systems is an essential topic for today’s developments in many fields of material research. Thin high-k layers and gate stacks are technologically required for the design of current and future electronic d...

  • Article
  • Open Access
13 Citations
6,784 Views
16 Pages

15 April 2014

Coagulation of cement particles is an inevitable phenomenon of fresh cement-based materials undergoing solidification. Coagulation can be classified into two types, reversible flocculation and irreversible coagulation, wherein microstructural change...

  • Article
  • Open Access
4 Citations
7,275 Views
19 Pages

15 April 2014

To study the variation of the mechanical behavior of binary aluminum copper alloys with respect to their microstructure, a numerical simulation of their granular structure was carried out. The microstructures are created by a repeated inclusion of so...

  • Article
  • Open Access
23 Citations
15,331 Views
22 Pages

R-HPDC Process with Forced Convection Mixing Device for Automotive Part of A380 Aluminum Alloy

  • Bing Zhou,
  • Yonglin Kang,
  • Mingfan Qi,
  • Huanhuan Zhang and
  • Guoming Zhu

15 April 2014

The continuing quest for cost-effective and complex shaped aluminum castings with fewer defects for applications in the automotive industries has aroused the interest in rheological high pressure die casting (R-HPDC). A new machine, forced convection...

  • Article
  • Open Access
49 Citations
14,702 Views
22 Pages

11 April 2014

To enhance the hemocompatibility of silk fibroin fabric as biomedical material, polyelectrolytes architectures have been assembled through the layer-by-layer (LbL) technique on silk fibroin fabric (SFF). In particular, 1.5 and 2.5 bilayer of opposite...

  • Review
  • Open Access
25 Citations
9,307 Views
24 Pages

11 April 2014

The synthesis of nanostructured anionic-surfactant-templated mesoporous silica (AMS) recently appeared as a new strategy for the formation of nanostructured silica based materials. This method is based on the use of anionic surfactants together with...

  • Article
  • Open Access
31 Citations
7,169 Views
19 Pages

A Procedure to Measure the in-Situ Hygrothermal Behavior of Earth Walls

  • Pierre-Antoine Chabriac,
  • Antonin Fabbri,
  • Jean-Claude Morel,
  • Jean-Paul Laurent and
  • Joachim Blanc-Gonnet

11 April 2014

Rammed earth is a sustainable material with low embodied energy. However, its development as a building material requires a better evaluation of its moisture-thermal buffering abilities and its mechanical behavior. Both of these properties are known...

  • Article
  • Open Access
40 Citations
9,150 Views
13 Pages

11 April 2014

Using liquid crystalline self-assembly of cellulose nanocrystals, we achieve long-range alignment of anisotropic metal nanoparticles in colloidal nanocrystal dispersions that are then used to deposit thin structured films with ordering features highl...

  • Article
  • Open Access
142 Citations
11,816 Views
15 Pages

Physical Characterization of Natural Straw Fibers as Aggregates for Construction Materials Applications

  • Marwen Bouasker,
  • Naima Belayachi,
  • Dashnor Hoxha and
  • Muzahim Al-Mukhtar

11 April 2014

The aim of this paper is to find out new alternative materials that respond to sustainable development criteria. For this purpose, an original utilization of straw for the design of lightweight aggregate concretes is proposed. Four types of straw wer...

  • Article
  • Open Access
37 Citations
9,447 Views
23 Pages

10 April 2014

Anatase nanoparticles synthesized by the sol-gel method were surface-functionalized with long alkyl chain coupling agents as compatibilizers for a nonpolar environment, containing different anchor groups for surface interaction namely phosphonate (d...

  • Review
  • Open Access
161 Citations
29,935 Views
32 Pages

10 April 2014

The current status of High K dielectrics in Very Large Scale Integrated circuit (VLSI) manufacturing for leading edge Dynamic Random Access Memory (DRAM) and Complementary Metal Oxide Semiconductor (CMOS) applications is summarized along with the dep...

  • Communication
  • Open Access
63 Citations
8,332 Views
11 Pages

10 April 2014

A novel strategy to fabricate a hydrogen peroxide (H2O2) sensor was developed by using platinum (Pt) electrodes modified with multi-wall carbon nanotube-platinum nanoparticle nanohybrids (MWCNTs/Pt nanohybrids). The process to synthesize MWCNTs/Pt na...

  • Article
  • Open Access
12 Citations
8,742 Views
20 Pages

Spin Relaxation in GaAs: Importance of Electron-Electron Interactions

  • Gionni Marchetti,
  • Matthew Hodgson,
  • James McHugh,
  • Roy Chantrell and
  • Irene D'Amico

9 April 2014

We study spin relaxation in n-type bulk GaAs, due to the Dyakonov–Perel mechanism, using ensemble Monte Carlo methods. Our results confirm that spin relaxation time increases with the electronic density in the regime of moderate electronic concentrat...

  • Article
  • Open Access
66 Citations
8,887 Views
18 Pages

9 April 2014

This study examines the feasibility of catalytically pretreated biochar derived from the dried exocarp or fruit peel of mangostene with Group I alkali metal hydroxide (KOH). The pretreated char was activated in the presence of carbon dioxide gas flow...

  • Review
  • Open Access
2,242 Citations
136,601 Views
49 Pages

Zinc Oxide—From Synthesis to Application: A Review

  • Agnieszka Kołodziejczak-Radzimska and
  • Teofil Jesionowski

9 April 2014

Zinc oxide can be called a multifunctional material thanks to its unique physical and chemical properties. The first part of this paper presents the most important methods of preparation of ZnO divided into metallurgical and chemical methods. The mec...

  • Article
  • Open Access
4 Citations
6,585 Views
8 Pages

9 April 2014

The high temperature corrosion behavior of sputtered nanocrystalline K38 coating with and without yttrium addition under mixed molten salt film in air was investigated. Accelerated corrosion occurred on the coating without yttrium (Y) addition locall...

  • Article
  • Open Access
25 Citations
8,367 Views
12 Pages

Investigation on the Enhanced Oxidation of Ferritic/Martensitic Steel P92 in Pure Steam

  • Juntao Yuan,
  • Ximao Wu,
  • Wen Wang,
  • Shenglong Zhu and
  • Fuhui Wang

3 April 2014

Oxidation of ferritic/martensitic steel P92 was investigated in pure oxygen and in pure steam at 600–800 °C by thermogravimetric analysis (TGA), optical microscopy (OM), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The results sho...

  • Article
  • Open Access
7 Citations
6,682 Views
11 Pages

Directional Scattering of Semiconductor Nanoparticles Embedded in a Liquid Crystal

  • Braulio García-Cámara,
  • José Francisco Algorri,
  • Virginia Urruchi and
  • José Manuel Sánchez-Pena

3 April 2014

Light scattering by semiconductor nanoparticles has been shown to be more complex than was believed until now. Both electric and magnetic responses emerge in the visible range. In addition, directional effects on light scattering of these nanoparticl...

  • Review
  • Open Access
137 Citations
15,415 Views
25 Pages

2 April 2014

Inorganic/organic hybrid solar cells have attracted a lot of interest due to their potential in combining the advantages of both components. To understand the key issues in association with photoinduced charge separation/transportation processes and...

  • Review
  • Open Access
18 Citations
11,416 Views
28 Pages

31 March 2014

A comprehensive study on the ternary dielectric, LaGdO3, synthesized and qualified in our laboratory as a novel high-k dielectric material for logic and memory device applications in terms of its excellent features that include a high linear dielectr...

  • Review
  • Open Access
117 Citations
21,507 Views
50 Pages

31 March 2014

Evaporation-Induced Self-Assembly (EISA) method for the preparation of mesoporous titanium dioxide materials is reviewed. The versatility of EISA method for the rapid and facile synthesis of TiO2 thin films and powders is highlighted. Non-ionic surfa...

  • Article
  • Open Access
135 Citations
11,216 Views
21 Pages

28 March 2014

In this study, a three-dimensional continuum percolation model was developed based on a Monte Carlo simulation approach to investigate the percolation behavior of an electrically insulating matrix reinforced with conductive nano-platelet fillers. The...

  • Article
  • Open Access
51 Citations
10,617 Views
12 Pages

28 March 2014

We fabricated zinc oxide (ZnO) nanorods (NRs) with Al-doped ZnO (AZO) seed layers and dye-sensitized solar cells (DSSCs) employed the ZnO NRs between a TiO2 photoelectrode and a fluorine-doped SnO2 (FTO) electrode. The growth rate of the NRs was stro...

  • Article
  • Open Access
29 Citations
10,524 Views
27 Pages

Effect of Native Oxide Film on Commercial Magnesium Alloys Substrates and Carbonate Conversion Coating Growth and Corrosion Resistance

  • Sebastián Feliu, Jr.,
  • Alejandro Samaniego,
  • Elkin Alejandro Bermudez,
  • Amir Abdelsami El-Hadad,
  • Irene Llorente and
  • Juan Carlos Galván

28 March 2014

Possible relations between the native oxide film formed spontaneously on the AZ31 and AZ61 magnesium alloy substrates with different surface finish, the chemistry of the outer surface of the conversion coatings that grows after their subsequent immer...

  • Article
  • Open Access
14 Citations
7,669 Views
16 Pages

28 March 2014

The pozzolanic activity of the spent catalyst produced by fluid catalytic cracking (FCC) has been studied by various methods in recent years. However, no quick and easy method has been reported for this activity based on the associated studies. In th...

  • Review
  • Open Access
533 Citations
24,447 Views
16 Pages

28 March 2014

Bismuth telluride and its alloys are widely used as materials for thermoelectric refrigeration. They are also the best materials for use in thermoelectric generators when the temperature of the heat source is moderate. The dimensionless figure of mer...

  • Article
  • Open Access
16 Citations
6,215 Views
12 Pages

Liquid Crystal Lensacons, Logarithmic and Linear Axicons

  • José Francisco Algorri,
  • Virginia Urruchi,
  • Braulio García-Cámara and
  • José Manuel Sánchez-Pena

28 March 2014

Until now, several attempts have been made to obtain axicons by using liquid crystals. Previous results had always a considerable deviation from the linear response and the resulting aperture is square. In addition, classical fabrications methods are...

  • Article
  • Open Access
27 Citations
8,227 Views
26 Pages

28 March 2014

Despite many advances in tissue engineering, there are still significant challenges associated with restructuring, repairing, or replacing damaged tissue in the body. Currently, a major obstacle has been trying to develop a scaffold for cartilage tis...

  • Article
  • Open Access
20 Citations
11,528 Views
19 Pages

Isothermal Time-Temperature-Precipitation Diagram for an Aluminum Alloy 6005A by In Situ DSC Experiments

  • Benjamin Milkereit,
  • Lydia Giersberg,
  • Olaf Kessler and
  • Christoph Schick

28 March 2014

Time-temperature-precipitation (TTP) diagrams deliver important material data, such as temperature and time ranges critical for precipitation during the quenching step of the age hardening procedure. Although the quenching step is continuous, isother...

  • Article
  • Open Access
12 Citations
6,904 Views
19 Pages

Immobilization of Methyltrioxorhenium on Mesoporous Aluminosilicate Materials

  • Martina Stekrova,
  • Radka Zdenkova,
  • Martin Vesely,
  • Eliska Vyskocilova and
  • Libor Cerveny

28 March 2014

The presented report focuses on an in-depth detailed characterization of immobilized methyltrioxorhenium (MTO), giving catalysts with a wide spectra of utilization. The range of mesoporous materials with different SiO2/Al2O3 ratios, namely mesoporous...

  • Review
  • Open Access
70 Citations
12,907 Views
29 Pages

27 March 2014

Polythiophene (PT) is one of the widely used donor materials for solution-processable polymer solar cells (PSCs). Much progress in PT-based PSCs can be attributed to the design of novel PTs exhibiting intense and broad visible absorption with high ch...

  • Article
  • Open Access
22 Citations
14,351 Views
19 Pages

27 March 2014

Propylene is one type of plastic that is widely used in our everyday life. This study focuses on the identification and justification of the optimum process parameters for polypropylene production in a novel pilot plant based fluidized bed reactor. T...

  • Article
  • Open Access
34 Citations
9,883 Views
15 Pages

Preparation of Chitosan-Based Hemostatic Sponges by Supercritical Fluid Technology

  • Hu-Fan Song,
  • Ai-Zheng Chen,
  • Shi-Bin Wang,
  • Yong-Qiang Kang,
  • Shi-Fu Ye,
  • Yuan-Gang Liu and
  • Wen-Guo Wu

27 March 2014

Using ammonium bicarbonate (AB) particles as a porogen, chitosan (CS)-based hemostatic porous sponges were prepared in supercritical carbon dioxide due to its low viscosity, small surface tension, and good compatibility with organic solvent. Fourier...

  • Article
  • Open Access
26 Citations
6,605 Views
16 Pages

27 March 2014

Adequate selection of material constituents and test methods are necessary for workability specifications and performance of hardened concrete. An experimental program was performed to evaluate the suitability of various test methods for workability...

  • Article
  • Open Access
82 Citations
10,124 Views
11 Pages

Field Effect Transistor Biosensor Using Antigen Binding Fragment for Detecting Tumor Marker in Human Serum

  • Shanshan Cheng,
  • Kaori Hotani,
  • Sho Hideshima,
  • Shigeki Kuroiwa,
  • Takuya Nakanishi,
  • Masahiro Hashimoto,
  • Yasuro Mori and
  • Tetsuya Osaka

27 March 2014

Detection of tumor markers is important for cancer diagnosis. Field-effect transistors (FETs) are a promising method for the label-free detection of trace amounts of biomolecules. However, detection of electrically charged proteins using antibody-imm...

  • Article
  • Open Access
19 Citations
6,369 Views
16 Pages

Bioeutectic® Ceramics for Biomedical Application Obtained by Laser Floating Zone Method. In vivo Evaluation

  • Piedad N. De Aza,
  • Jose I. Peña,
  • Zofia B. Luklinska and
  • Luis Meseguer-Olmo

25 March 2014

In this study, the Bioeutectic® blocks were inserted into the critical size defects of eight rabbits, using both tibiae, and the physical and chemical nature of the remodeled interface between the Bioeutectic® implants and the surrounding bone were p...

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Materials - ISSN 1996-1944