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Open AccessArticle

Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions

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PhotoGreen Lab, Department of Chemistry, University of Pavia. Viale Taramelli 12, 27100 Pavia, Italy
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Chemistry Department, College of Science, Salahaddin University-Erbil, Erbil 44001, Iraq
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Chemistry Department, College of Education, Salahaddin University-Erbil, Erbil 44001, Iraq
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Centro Grandi Strumenti (CGS), University of Pavia, V. Bassi 21, 27100 Pavia, Italy
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Authors to whom correspondence should be addressed.
Academic Editor: Alessandro Palmieri
Molecules 2019, 24(11), 2164; https://doi.org/10.3390/molecules24112164
Received: 16 May 2019 / Revised: 3 June 2019 / Accepted: 5 June 2019 / Published: 8 June 2019
Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d8 or in THF-d8/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents. View Full-Text
Keywords: arylazo sulfones; deuteration; visible-light induced processes; photochemistry arylazo sulfones; deuteration; visible-light induced processes; photochemistry
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MDPI and ACS Style

Amin, H.I.M.; Raviola, C.; Amin, A.A.; Mannucci, B.; Protti, S.; Fagnoni, M. Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions. Molecules 2019, 24, 2164.

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