Recent Advances in the Application of SelectfluorTMF-TEDA-BF4 as a Versatile Mediator or Catalyst in Organic Synthesis
1
Laboratory for Organic and Bioorganic Chemistry, “Jožef Stefan” Institute, Jamova 39, 1000 Ljubljana, Slovenia
2
Centre of Excellence CIPKeBiP, Jamova 39, 1000 Ljubljana, Slovenia
Molecules 2011, 16(8), 6432-6464; https://doi.org/10.3390/molecules16086432
Received: 14 June 2011
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Revised: 5 July 2011
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Accepted: 19 July 2011
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Published: 29 July 2011
(This article belongs to the Special Issue Fluorine Chemistry 2016)
SelectfluorTM F-TEDA-BF4 (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo [2.2.2]octane bis(tetrafluoroborate) is not only one of the most efficient and popular reagents for electrophilic fluorination, but as a strong oxidant is also a convenient mediator or catalyst of several “fluorine-free” functionalizations of organic compounds. Its applications as a mediator in transformations of oxidizable functional groups or gold-catalyzed C-C and C-heteroatom oxidative coupling reactions, a catalyst in formation of various heterocyclic rings, a reagent or catalyst of various functionalizations of electron-rich organic compounds (iodination, bromination, chlorination, nitration, thiocyanation, sulfenylation, alkylation, alkoxylation), a catalyst of one-pot-multi-component coupling reactions, a catalyst of regioselective ring opening of epoxides, a deprotection reagent for various protecting groups, and a mediator for stereoselective rearrangement processes of bicyclic compounds are reviewed and discussed.
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MDPI and ACS Style
Stavber, S. Recent Advances in the Application of SelectfluorTMF-TEDA-BF4 as a Versatile Mediator or Catalyst in Organic Synthesis. Molecules 2011, 16, 6432-6464. https://doi.org/10.3390/molecules16086432
AMA Style
Stavber S. Recent Advances in the Application of SelectfluorTMF-TEDA-BF4 as a Versatile Mediator or Catalyst in Organic Synthesis. Molecules. 2011; 16(8):6432-6464. https://doi.org/10.3390/molecules16086432
Chicago/Turabian StyleStavber, Stojan. 2011. "Recent Advances in the Application of SelectfluorTMF-TEDA-BF4 as a Versatile Mediator or Catalyst in Organic Synthesis" Molecules 16, no. 8: 6432-6464. https://doi.org/10.3390/molecules16086432
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