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Volume 14
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10.3390/molecules14104065
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Open AccessArticle

Sulphated Zirconia as an Eco-Friendly Catalyst in Acylal Preparation under Solvent-Free Conditions, Acylal Deprotection Assisted by Microwaves, and the Synthesis of Anhydro-Dimers of o-Hydroxybenzaldehydes

by
Laura Nadxieli Palacios-Grijalva
1,
Deysi Y. Cruz-González
1,
Leticia Lomas-Romero
2,
Eduardo González-Zamora
2,
Gerardo Ulibarri
3 and
Guillermo E. Negrón-Silva
1,*
1
Departamento de Ciencias Básicas, UAM-A, Av. San Pablo, No. 180. C.P. 02200, México, D.F., Mexico
2
Departamento de Química, UAM-I, San Rafael Atlixco, No. 186. C.P. 09340, México, D.F., Mexico
3
Department of Chemistry & Biochemistry, Laurentian University, Sudbury, ON P3E2C6, Canada
*
Author to whom correspondence should be addressed.
Molecules 2009, 14(10), 4065-4078; https://doi.org/10.3390/molecules14104065
Received: 25 August 2009 / Revised: 21 September 2009 / Accepted: 27 September 2009 / Published: 12 October 2009
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Abstract

A solvent-free approach is described for the regioselective synthesis of acylals (1,1-diacetates) in shorter reaction times and higher yields, compared to conventional methodology using solvents. In the protection reaction of the o-hydroxybenzaldehyde the formation of acetyl compounds and anhydro-dimers was observed. The deprotection reaction involves microwave (MW) exposure of diluted reactants in the presence of solid sulphated zirconia (SZ) catalyst that can be easily recovered and reused. The sulphated zirconia was recycled several times without any loss of activity. View Full-Text
Keywords: sulphated zirconia; solvent-free; microwaves; regioselective; diacetates sulphated zirconia; solvent-free; microwaves; regioselective; diacetates
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MDPI and ACS Style

Palacios-Grijalva, L.N.; Cruz-González, D.Y.; Lomas-Romero, L.; González-Zamora, E.; Ulibarri, G.; Negrón-Silva, G.E. Sulphated Zirconia as an Eco-Friendly Catalyst in Acylal Preparation under Solvent-Free Conditions, Acylal Deprotection Assisted by Microwaves, and the Synthesis of Anhydro-Dimers of o-Hydroxybenzaldehydes. Molecules 2009, 14, 4065-4078. https://doi.org/10.3390/molecules14104065

AMA Style

Palacios-Grijalva LN, Cruz-González DY, Lomas-Romero L, González-Zamora E, Ulibarri G, Negrón-Silva GE. Sulphated Zirconia as an Eco-Friendly Catalyst in Acylal Preparation under Solvent-Free Conditions, Acylal Deprotection Assisted by Microwaves, and the Synthesis of Anhydro-Dimers of o-Hydroxybenzaldehydes. Molecules. 2009; 14(10):4065-4078. https://doi.org/10.3390/molecules14104065

Chicago/Turabian Style

Palacios-Grijalva, Laura N.; Cruz-González, Deysi Y.; Lomas-Romero, Leticia; González-Zamora, Eduardo; Ulibarri, Gerardo; Negrón-Silva, Guillermo E. 2009. "Sulphated Zirconia as an Eco-Friendly Catalyst in Acylal Preparation under Solvent-Free Conditions, Acylal Deprotection Assisted by Microwaves, and the Synthesis of Anhydro-Dimers of o-Hydroxybenzaldehydes" Molecules 14, no. 10: 4065-4078. https://doi.org/10.3390/molecules14104065

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