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Keywords = temperature cycling test

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41 pages, 4303 KiB  
Article
Land Use–Future Climate Coupling Mechanism Analysis of Regional Agricultural Drought Spatiotemporal Patterns
by Jing Wang, Zhenjiang Si, Tao Liu, Yan Liu and Longfei Wang
Sustainability 2025, 17(15), 7119; https://doi.org/10.3390/su17157119 - 6 Aug 2025
Abstract
This study assesses future agricultural drought risk in the Ganjiang River Basin under climate change and land use change. A coupled analysis framework was established using the SWAT hydrological model, the CMIP6 climate models (SSP1-2.6, SSP2-4.5, SSP5-8.5), and the PLUS land use simulation [...] Read more.
This study assesses future agricultural drought risk in the Ganjiang River Basin under climate change and land use change. A coupled analysis framework was established using the SWAT hydrological model, the CMIP6 climate models (SSP1-2.6, SSP2-4.5, SSP5-8.5), and the PLUS land use simulation model. Key methods included the Standardized Soil Moisture Index (SSMI), travel time theory for drought event identification and duration analysis, Mann–Kendall trend test, and the Pettitt change-point test to examine soil moisture dynamics from 2027 to 2100. The results indicate that the CMIP6 ensemble performs excellently in temperature simulations, with a correlation coefficient of R2 = 0.89 and a root mean square error of RMSE = 1.2 °C, compared to the observational data. The MMM-Best model also performs well in precipitation simulations, with R2 = 0.82 and RMSE = 15.3 mm, compared to observational data. Land use changes between 2000 and 2020 showed a decrease in forestland (−3.2%), grassland (−2.8%), and construction land (−1.5%), with an increase in water (4.8%) and unused land (2.7%). Under all emission scenarios, the SSMI values fluctuate with standard deviations of 0.85 (SSP1-2.6), 1.12 (SSP2-4.5), and 1.34 (SSP5-8.5), with the strongest drought intensity observed under SSP5-8.5 (minimum SSMI = −2.8). Drought events exhibited spatial and temporal heterogeneity across scenarios, with drought-affected areas ranging from 25% (SSP1-2.6) to 45% (SSP5-8.5) of the basin. Notably, abrupt changes in soil moisture under SSP5-8.5 occurred earlier (2045–2050) due to intensified land use change, indicating strong human influence on hydrological cycles. This study integrated the CMIP6 climate projections with high-resolution human activity data to advance drought risk assessment methods. It established a framework for assessing agricultural drought risk at the regional scale that comprehensively considers climate and human influences, providing targeted guidance for the formulation of adaptive water resource and land management strategies. Full article
(This article belongs to the Special Issue Sustainable Future of Ecohydrology: Climate Change and Land Use)
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17 pages, 2219 KiB  
Article
Assessing Lithium-Ion Battery Safety Under Extreme Transport Conditions: A Comparative Study of Measured and Standardised Parameters
by Yihan Pan, Xingliang Liu, Jinzhong Wu, Haocheng Zhou and Lina Zhu
Energies 2025, 18(15), 4144; https://doi.org/10.3390/en18154144 - 5 Aug 2025
Viewed by 85
Abstract
The safety of lithium-ion batteries during transportation is critically important. However, current standards exhibit limitations, as their environmental testing parameter thresholds fail to fully encompass actual transportation conditions. To enhance both safety and standard applicability, in this study, we focused on four representative [...] Read more.
The safety of lithium-ion batteries during transportation is critically important. However, current standards exhibit limitations, as their environmental testing parameter thresholds fail to fully encompass actual transportation conditions. To enhance both safety and standard applicability, in this study, we focused on four representative environmental conditions: temperature, vibration, shock, and low atmospheric pressure. Field measurements were conducted across road, rail, and air transport modes using a self-developed data acquisition system based on the NearLink communication technology. The measured data were then compared with the threshold values defined in current international and national standards. The results reveal that certain measured values exceeded the upper limits prescribed by existing standards, indicating limitations in their applicability under extreme transport conditions. Based on these findings, we propose revised testing parameters that better reflect actual transport risks, including a temperature cycling range of 72 ± 2 °C (high) and −40 ± 2 °C (low), a shock acceleration limit of 50 gn, adjusted peak frequencies in the vibration PSD profile, and a minimum pressure threshold of 11.6 kPa. These results provide a scientific basis for optimising safety standards and improving the safety of lithium-ion battery transportation. Full article
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21 pages, 6166 KiB  
Article
Effect of Thermal Cycles on the Compressive Properties of 3D-Printed Polymeric Lattice-Reinforced Cement-Based Materials
by Can Tang, Yujie Zhou, Jing Qiao, Humaira Kanwal, Guoqian Song and Wenfeng Hao
Polymers 2025, 17(15), 2137; https://doi.org/10.3390/polym17152137 - 4 Aug 2025
Viewed by 209
Abstract
Existing studies have shown that placing 3D-printed lattices in cement matrices can effectively improve the ductility of cement-based composites. However, the influence of thermal fatigue effect on the mechanical properties of 3D-printed lattice-reinforced cement-based composites during service remains to be studied. In this [...] Read more.
Existing studies have shown that placing 3D-printed lattices in cement matrices can effectively improve the ductility of cement-based composites. However, the influence of thermal fatigue effect on the mechanical properties of 3D-printed lattice-reinforced cement-based composites during service remains to be studied. In this paper, cement-based materials without lattices were used as the control group, and the uniaxial compressive mechanical properties of 3D-printed lattice-reinforced cement-based composites after thermal fatigue treatment under a temperature difference of 60 °C were tested. The number of thermal fatigue cycles was set to 45, 90, and 145 times, respectively. During the test, two non-destructive testing technologies, AE and DIC, were used to analyze the strength degradation and deformation law of 3D-printed lattice-reinforced cement-based composites with the increase in cycles. AE adopted the threshold triggering mode, and the channel threshold was 100 mv. The experiment showed that the compressive strength of the control group after 45, 90, and 145 thermal cycles decreased to 72.47% and 49.44% of that of the specimen after 45 thermal cycles, respectively. The strength of RO lattices decreased to 91.07% and 82.14% of that of the specimen after 45 thermal cycles, respectively, while the strength of SO lattices decreased to 83.27% and 77.96% of that of the specimen after 45 thermal cycles, respectively. The compressive strengths of the two types of lattices were higher than that of the control group after three cycles, indicating that 3D-printed lattices can effectively mitigate the influence of environmental thermal fatigue on the mechanical properties of cement-based materials. Full article
(This article belongs to the Special Issue Polymeric Materials and Their Application in 3D Printing, 2nd Edition)
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13 pages, 4335 KiB  
Article
Mg-Doped O3-Na[Ni0.6Fe0.25Mn0.15]O2 Cathode for Long-Cycle-Life Na-Ion Batteries
by Zebin Song, Hao Zhou, Yin Zhang, Haining Ji, Liping Wang, Xiaobin Niu and Jian Gao
Inorganics 2025, 13(8), 261; https://doi.org/10.3390/inorganics13080261 - 4 Aug 2025
Viewed by 128
Abstract
The O3-type layered oxide materials have the advantage of high specific capacity, which makes them more competitive in the practical application of cathode materials for sodium-ion batteries (SIBs). However, the existing reported O3-type layered oxide materials still have a complex irreversible phase transition [...] Read more.
The O3-type layered oxide materials have the advantage of high specific capacity, which makes them more competitive in the practical application of cathode materials for sodium-ion batteries (SIBs). However, the existing reported O3-type layered oxide materials still have a complex irreversible phase transition phenomenon, and the cycle life of batteries needs, with these materials, to be further improved to meet the requirements. Herein, we performed structural characterization and electrochemical performance tests on O3-NaNi0.6−xFe0.25Mn0.15MgxO2 (x = 0, 0.025, 0.05, and 0.075, denoted as NFM, NFM-2.5Mg, NFM-5.0Mg, and NFM-7.5Mg). The optimized NFM-2.5Mg has the largest sodium layer spacing, which can effectively enhance the transmission rate of sodium ions. Therefore, the reversible specific capacity can reach approximately 148.1 mAh g−1 at 0.2C, and it can even achieve a capacity retention of 85.4% after 100 cycles at 1C, demonstrating excellent cycle stability. Moreover, at a low temperature of 0 °C, it also can keep capacity retention of 86.6% after 150 cycles at 1C. This study provides a view on the cycling performance improvement of sodium-ion layered oxide cathodes with a high theoretical specific capacity. Full article
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25 pages, 6272 KiB  
Article
Research on Energy-Saving Control of Automotive PEMFC Thermal Management System Based on Optimal Operating Temperature Tracking
by Qi Jiang, Shusheng Xiong, Baoquan Sun, Ping Chen, Huipeng Chen and Shaopeng Zhu
Energies 2025, 18(15), 4100; https://doi.org/10.3390/en18154100 - 1 Aug 2025
Viewed by 234
Abstract
To further enhance the economic performance of fuel cell vehicles (FCVs), this study develops a model-adaptive model predictive control (MPC) strategy. This strategy leverages the dynamic relationship between proton exchange membrane fuel cell (PEMFC) output characteristics and temperature to track its optimal operating [...] Read more.
To further enhance the economic performance of fuel cell vehicles (FCVs), this study develops a model-adaptive model predictive control (MPC) strategy. This strategy leverages the dynamic relationship between proton exchange membrane fuel cell (PEMFC) output characteristics and temperature to track its optimal operating temperature (OOT), addressing challenges of temperature control accuracy and high energy consumption in the PEMFC thermal management system (TMS). First, PEMFC and TMS models were developed and experimentally validated. Subsequently, the PEMFC power–temperature coupling curve was experimentally determined under multiple operating conditions to serve as the reference trajectory for TMS multi-objective optimization. For MPC controller design, the TMS model was linearized and discretized, yielding a predictive model adaptable to different load demands for stack temperature across the full operating range. A multi-constrained quadratic cost function was formulated, aiming to minimize the deviation of the PEMFC operating temperature from the OOT while accounting for TMS parasitic power consumption. Finally, simulations under Worldwide Harmonized Light Vehicles Test Cycle (WLTC) conditions evaluated the OOT tracking performance of both PID and MPC control strategies, as well as their impact on stack efficiency and TMS energy consumption at different ambient temperatures. The results indicate that, compared to PID control, MPC reduces temperature tracking error by 33%, decreases fan and pump speed fluctuations by over 24%, and lowers TMS energy consumption by 10%. These improvements enhance PEMFC operational stability and improve FCV energy efficiency. Full article
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24 pages, 11098 KiB  
Article
Fracture Mechanisms of Electrothermally Fatigued 631 Stainless Steel Fine Wires for Probe Spring Applications
by Chien-Te Huang, Fei-Yi Hung and Kai-Chieh Chang
Appl. Sci. 2025, 15(15), 8572; https://doi.org/10.3390/app15158572 (registering DOI) - 1 Aug 2025
Viewed by 188
Abstract
This study systematically investigates 50 μm-diameter 631 stainless steel fine wires subjected to both sequential and simultaneous electrothermomechanical loading to simulate probe spring conditions in microelectronic test environments. Under cyclic current loading (~104 A/cm2), the 50 μm 631SS wire maintained [...] Read more.
This study systematically investigates 50 μm-diameter 631 stainless steel fine wires subjected to both sequential and simultaneous electrothermomechanical loading to simulate probe spring conditions in microelectronic test environments. Under cyclic current loading (~104 A/cm2), the 50 μm 631SS wire maintained electrical integrity up to 0.30 A for 15,000 cycles. Above 0.35 A, rapid oxide growth and abnormal grain coarsening resulted in surface embrittlement and mechanical degradation. Current-assisted tensile testing revealed a transition from recovery-dominated behavior at ≤0.20 A to significant thermal softening and ductility loss at ≥0.25 A, corresponding to a threshold temperature of approximately 200 °C. These results establish the endurance limit of 631 stainless steel wire under coupled thermal–mechanical–electrical stress and clarify the roles of Joule heating, oxidation, and microstructural evolution in electrical fatigue resistance. A degradation map is proposed to inform design margins and operational constraints for fatigue-tolerant, electrically stable interconnects in high-reliability probe spring applications. Full article
(This article belongs to the Special Issue Application of Fracture Mechanics in Structures)
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26 pages, 15885 KiB  
Article
Comparative Analysis of Fully Floating and Semi-Floating Ring Bearings in High-Speed Turbocharger Rotordynamics
by Kyuman Kim and Keun Ryu
Lubricants 2025, 13(8), 338; https://doi.org/10.3390/lubricants13080338 - 31 Jul 2025
Viewed by 215
Abstract
This study presents a detailed experimental comparison of the rotordynamic and thermal performance of automotive turbochargers supported by two distinct hydrodynamic bearing configurations: fully floating ring bearings (FFRBs) and semi-floating ring bearings (SFRBs). While both designs are widely used in commercial turbochargers, they [...] Read more.
This study presents a detailed experimental comparison of the rotordynamic and thermal performance of automotive turbochargers supported by two distinct hydrodynamic bearing configurations: fully floating ring bearings (FFRBs) and semi-floating ring bearings (SFRBs). While both designs are widely used in commercial turbochargers, they exhibit significantly different dynamic behaviors due to differences in ring motion and fluid film interaction. A cold air-driven test rig was employed to assess vibration and temperature characteristics across a range of controlled lubricant conditions. The test matrix included oil supply pressures from 2 bar (g) to 4 bar (g) and temperatures between 30 °C and 70 °C. Rotor speeds reached up to 200 krpm (thousands of revolutions per minute), and data were collected using a high-speed data acquisition system, triaxial accelerometers, and infrared (IR) thermal imaging. Rotor vibration was characterized through waterfall and Bode plots, while jump speeds and thermal profiles were analyzed to evaluate the onset and severity of instability. The results demonstrate that the FFRB configuration is highly sensitive to oil supply parameters, exhibiting strong subsynchronous instabilities and hysteresis during acceleration–deceleration cycles. In contrast, the SFRB configuration consistently provided superior vibrational stability and reduced sensitivity to lubricant conditions. Changes in lubricant supply conditions induced a jump speed variation in floating ring bearing (FRB) turbochargers that was approximately 3.47 times larger than that experienced by semi-floating ring bearing (SFRB) turbochargers. Furthermore, IR images and oil outlet temperature data confirm that the FFRB system experiences greater heat generation and thermal gradients, consistent with higher energy dissipation through viscous shear. This study provides a comprehensive assessment of both bearing types under realistic high-speed conditions and highlights the advantages of the SFRB configuration in improving turbocharger reliability, thermal performance, and noise suppression. The findings support the application of SFRBs in high-performance automotive systems where mechanical stability and reduced frictional losses are critical. Full article
(This article belongs to the Collection Rising Stars in Tribological Research)
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28 pages, 3635 KiB  
Article
Optimizing Energy Performance of Phase-Change Material-Enhanced Building Envelopes Through Novel Performance Indicators
by Abrar Ahmad and Shazim Ali Memon
Buildings 2025, 15(15), 2678; https://doi.org/10.3390/buildings15152678 - 29 Jul 2025
Viewed by 797
Abstract
Over recent decades, phase-change materials (PCMs) have gained prominence as latent-heat thermal energy storage systems in building envelopes because of their high energy density. However, only PCMs that complete a full daily charge–discharge cycle can deliver meaningful energy and carbon-emission savings. This simulation [...] Read more.
Over recent decades, phase-change materials (PCMs) have gained prominence as latent-heat thermal energy storage systems in building envelopes because of their high energy density. However, only PCMs that complete a full daily charge–discharge cycle can deliver meaningful energy and carbon-emission savings. This simulation study introduces a methodology that simultaneously optimizes PCM integration for storage efficiency, indoor thermal comfort, and energy savings. Two new indicators are proposed: overall storage efficiency (ECn), which consolidates heating and cooling-efficiency ratios into a single value, and the performance factor (PF), which quantifies the PCM’s effectiveness in maintaining thermal comfort. Using EnergyPlus v8.9 coupled with DesignBuilder, a residential ASHRAE 90.1 mid-rise apartment was modeled in six warm-temperate (Cfb) European cities for the summer period from June 1 to August 31. Four paraffin PCMs (RT-22/25/28/31 HC, 20 mm thickness) were tested under natural and controlled ventilation strategies, with windows opening 50% when outdoor air was at least 2 °C cooler than indoors. Simulation outputs were validated against experimental cubicle data, yielding a mean absolute indoor temperature error ≤ 4.5%, well within the ±5% tolerance commonly accepted for building thermal simulations. The optimum configuration—RT-25 HC with temperature-controlled ventilation—achieved PF = 1.0 (100% comfort compliance) in all six cities and delivered summer cooling-energy savings of up to 3376 kWh in Paris, the highest among the locations studied. Carbon-emission reductions reached 2254 kg CO2-e year−1, and static payback periods remained below the assumed 50-year building life at a per kg PCM cost of USD 1. The ECn–PF framework, therefore, provides a transparent basis for selecting cost-effective, energy-efficient, and low-carbon PCM solutions in warm-temperate buildings. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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26 pages, 3943 KiB  
Article
Effect of Corrosion-Induced Damage on Fatigue Behavior Degradation of ZCuAl8Mn13Fe3Ni2 Nickel–Aluminum Bronze Under Accelerated Conditions
by Ruonan Zhang, Junqi Wang, Pengyu Wei, Lian Wang, Chihui Huang, Zeyu Dai, Jinguang Zhang, Chaohe Chen and Xinyan Guo
Materials 2025, 18(15), 3551; https://doi.org/10.3390/ma18153551 - 29 Jul 2025
Viewed by 309
Abstract
Corrosion fatigue damage significantly affects the long-term service of marine platforms such as propellers. Fatigue testing of pre-corrosion specimens is essential for understanding damage mechanisms and accurately predicting fatigue life. However, traditional seawater-based tests are time-consuming and yield inconsistent results, making them unsuitable [...] Read more.
Corrosion fatigue damage significantly affects the long-term service of marine platforms such as propellers. Fatigue testing of pre-corrosion specimens is essential for understanding damage mechanisms and accurately predicting fatigue life. However, traditional seawater-based tests are time-consuming and yield inconsistent results, making them unsuitable for rapid evaluation of newly developed equipment. This study proposes an accelerated corrosion testing method for ZCuAl8Mn13Fe3Ni2 nickel–aluminum bronze, simulating the marine full immersion zone by increasing temperature, adding H2O2, reducing the solution pH, and preparing the special solution. Coupled with the fatigue test of pre-corrosion specimens, the corrosion damage characteristics and their influence on fatigue performance were analyzed. A numerical simulation method was developed to predict the fatigue life of pre-corrosion specimens, showing an average error of 13.82%. The S–N curves under different pre-corrosion cycles were also established. The research results show that using the test solution of 0.6 mol/L NaCl + 0.1 mol/L H3PO4-NaH2PO4 buffer solution + 1.0 mol/L H2O2 + 0.1 mL/500 mL concentrated hydrochloric acid for corrosion acceleration testing shows good corrosion acceleration. Moreover, the test methods ensure accuracy and reliability of the fatigue behavior evaluation of pre-corrosion specimens of the structure under actual service environments, offering a robust foundation for the material selection, corrosion resistance evaluation, and fatigue life prediction of marine structural components. Full article
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15 pages, 3222 KiB  
Article
Process Optimization of Thawed Cloudy Huyou Juice Clarification Using a Composite of Carboxymethyl Chitosan and Sodium Alginate
by Peichao Zhang, Liang Zhang, Xiayu Liu, Yuxi Wang, Jiatong Xu, Pengfei Liu and Boyuan Guan
Foods 2025, 14(15), 2658; https://doi.org/10.3390/foods14152658 - 29 Jul 2025
Viewed by 180
Abstract
Cloudy huyou juice is increasingly popular for its unique flavor, but flocculent precipitation after cold storage and thawing affects its sensory quality and increases production costs. This study optimized the clarification of thawed cloudy huyou juice using a composite of carboxymethyl chitosan (CC) [...] Read more.
Cloudy huyou juice is increasingly popular for its unique flavor, but flocculent precipitation after cold storage and thawing affects its sensory quality and increases production costs. This study optimized the clarification of thawed cloudy huyou juice using a composite of carboxymethyl chitosan (CC) and sodium alginate (SA), prepared via ionic and covalent crosslinking. The composite was characterized by SEM, FTIR, and thermal analysis. Transmittance was used to evaluate clarification performance. The effects of dosage, adsorption time, and temperature were first assessed through single-factor experiments, followed by optimization using a Box–Behnken response surface methodology. The composite significantly improved clarity (p < 0.05), reaching 85.38% transmittance under optimal conditions: 22 mg dosage, 80 min time, and 38 °C. The composite dosage and temperature were the most influential factors. Reusability tests showed declining performance, with the transmittance dropping to 57.13% after five cycles, likely due to incomplete desorption of adsorbed compounds. These results suggest that the CC-SA composite is an effective and reusable clarifying agent with potential for industrial applications in turbid fruit juice processing. Full article
(This article belongs to the Section Food Biotechnology)
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21 pages, 2695 KiB  
Article
Thermographic Investigation of Elastocaloric Behavior in Ni-Ti Sheet Elements Under Cyclic Bending
by Saeed Danaee Barforooshi, Gianmarco Bizzarri, Girolamo Costanza, Stefano Paoloni, Ilaria Porroni and Maria Elisa Tata
Materials 2025, 18(15), 3546; https://doi.org/10.3390/ma18153546 - 29 Jul 2025
Viewed by 253
Abstract
Growing environmental concerns have driven increased interest in solid-state thermal technologies based on the elastocaloric properties of shape memory alloys (SMA). This work examines the elastocaloric effect (eCE) in Ni-Ti SMA sheets subjected to cyclic bending, providing quantitative thermal characterization of their behavior [...] Read more.
Growing environmental concerns have driven increased interest in solid-state thermal technologies based on the elastocaloric properties of shape memory alloys (SMA). This work examines the elastocaloric effect (eCE) in Ni-Ti SMA sheets subjected to cyclic bending, providing quantitative thermal characterization of their behavior under controlled loading conditions. The experimental investigation employed passive thermography to analyze the thermal response of Ni-Ti sheets under two deflection configurations at 1800 rpm loading. Testing revealed consistent adiabatic temperature variations (ΔTad) of 4.14 °C and 4.26 °C for the respective deflections during heating cycles, while cooling phases demonstrated efficient thermal homogenization with temperature gradients decreasing from 4.13 °C to 0.13 °C and 4.43 °C to 0.68 °C over 60 s. These findings provide systematic thermal documentation of elastocaloric behavior in bending-loaded Ni-Ti sheet elements and quantitative data on the relationship between mechanical loading parameters and thermal gradients, enhancing the experimental understanding of elastocaloric phenomena in this configuration. Full article
(This article belongs to the Special Issue Technology and Applications of Shape Memory Materials)
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14 pages, 2594 KiB  
Article
Low-Temperature Performance and Thermal Control of Asphalt Modified with Microencapsulated Phase-Change Materials
by Liming Zhang, Junmao Wang, Jinhua Wu, Ran Zhang, Yinchuan Guo, Hongbo Shen, Xinghua Liu and Kuncan Li
Coatings 2025, 15(8), 879; https://doi.org/10.3390/coatings15080879 - 26 Jul 2025
Viewed by 376
Abstract
Conventional asphalt is prone to cracking in cold climates due to its poor flexibility and limited ability to regulate temperature. This study investigates the use of low-temperature microencapsulated phase-change materials (MPCMs) to improve both the thermal storage and low-temperature performance of asphalt. MPCMs [...] Read more.
Conventional asphalt is prone to cracking in cold climates due to its poor flexibility and limited ability to regulate temperature. This study investigates the use of low-temperature microencapsulated phase-change materials (MPCMs) to improve both the thermal storage and low-temperature performance of asphalt. MPCMs were incorporated into asphalt through physical blending at various concentrations. The physical, thermal, and rheological properties of the asphalt were then systematically evaluated. Tests included penetration, softening point, ductility, thermogravimetric analysis (TGA), and dynamic shear rheometer (DSR). The addition of MPCMs increased penetration and ductility. It slightly reduced the softening point and viscosity. These changes suggest improved flexibility and workability at low temperatures. Rheological tests showed reductions in rutting and fatigue factors. This indicates better resistance to thermal and mechanical stresses. Bending Beam Rheometer (BBR) results further confirmed that MPCMs lowered creep stiffness and increased the m-value. These findings demonstrate improved crack resistance under cold conditions. Thermal cycling tests also showed that MPCMs delayed the cooling process and reduced temperature fluctuations. This highlights their potential to enhance both energy efficiency and the durability of asphalt pavements in cold regions. Full article
(This article belongs to the Special Issue Synthesis and Application of Functional Polymer Coatings)
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11 pages, 1161 KiB  
Proceeding Paper
Spatio-Temporal PM2.5 Forecasting Using Machine Learning and Low-Cost Sensors: An Urban Perspective
by Mateusz Zareba, Szymon Cogiel and Tomasz Danek
Eng. Proc. 2025, 101(1), 6; https://doi.org/10.3390/engproc2025101006 - 25 Jul 2025
Viewed by 222
Abstract
This study analyzes air pollution time-series big data to assess stationarity, seasonal patterns, and the performance of machine learning models in forecasting PM2.5 concentrations. Fifty-two low-cost sensors (LCS) were deployed across Krakow city and its surroundings (Poland), collecting hourly air quality data and [...] Read more.
This study analyzes air pollution time-series big data to assess stationarity, seasonal patterns, and the performance of machine learning models in forecasting PM2.5 concentrations. Fifty-two low-cost sensors (LCS) were deployed across Krakow city and its surroundings (Poland), collecting hourly air quality data and generating nearly 20,000 observations per month. The network captured both spatial and temporal variability. The Kwiatkowski–Phillips–Schmidt–Shin (KPSS) test confirmed trend-based non-stationarity, which was addressed through differencing, revealing distinct daily and 12 h cycles linked to traffic and temperature variations. Additive seasonal decomposition exhibited time-inconsistent residuals, leading to the adoption of multiplicative decomposition, which better captured pollution outliers associated with agricultural burning. Machine learning models—Ridge Regression, XGBoost, and LSTM (Long Short-Term Memory) neural networks—were evaluated under high spatial and temporal variability (winter) and low variability (summer) conditions. Ridge Regression showed the best performance, achieving the highest R2 (0.97 in winter, 0.93 in summer) and the lowest mean squared errors. XGBoost showed strong predictive capabilities but tended to overestimate moderate pollution events, while LSTM systematically underestimated PM2.5 levels in December. The residual analysis confirmed that Ridge Regression provided the most stable predictions, capturing extreme pollution episodes effectively, whereas XGBoost exhibited larger outliers. The study proved the potential of low-cost sensor networks and machine learning in urban air quality forecasting focused on rare smog episodes (RSEs). Full article
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20 pages, 7113 KiB  
Article
Effect of Cu Content on Corrosion Resistance of 3.5%Ni Weathering Steel in Marine Atmosphere of South China Sea
by Yuanzheng Li, Ziyu Guo, Tianle Fu, Sha Sha, Bing Wang, Xiaoping Chen, Shujun Jia and Qingyou Liu
Materials 2025, 18(15), 3496; https://doi.org/10.3390/ma18153496 - 25 Jul 2025
Viewed by 291
Abstract
The influence of the copper (Cu) content on the corrosion resistance of 3.5%Ni low-carbon weathering steel was investigated using periodic dry–wet cycle accelerated corrosion tests. The mechanical properties of the steels were assessed via tensile and low-temperature impact tests, while corrosion resistance was [...] Read more.
The influence of the copper (Cu) content on the corrosion resistance of 3.5%Ni low-carbon weathering steel was investigated using periodic dry–wet cycle accelerated corrosion tests. The mechanical properties of the steels were assessed via tensile and low-temperature impact tests, while corrosion resistance was evaluated based on weight loss measurements. Surface oxide layers were characterized using three-dimensional laser confocal microscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and electrochemical methods. Electron probe microanalysis (EPMA) was employed to examine the cross-sectional morphology of the oxide layer after 72 h of accelerated corrosion tests. The results indicate that the solution state of Cu increased the strength of 3.5%Ni steels but significantly damaged the low-temperature toughness. As the Cu content increased from 0.75% to 1.25%, the corrosion rate decreased from 4.65 to 3.74 g/m2 h. However, when there was a further increase in the Cu content to 2.15%, there was little decrease in the corrosion rate. With the increase in the Cu content from 0.75% to 2.15%, the surface roughness of 3.5%Ni weathering steel after corrosion decreased from 5.543 to 5.019 μm, and the corrosion behavior was more uniform. Additionally, the α/γ protective factor of the oxide layer of the surface layer increased from 2.58 to 2.84 with an increase in the Cu content from 0.75% to 1.25%, resulting in the oxide layer of the surface layer being more protective. For 1.25%Cu steel, the corrosion current density of rusted samples is lower (ranging from 1.2609 × 10−4 A/cm2 to 3.7376 × 10−4 A/cm2), and the corrosion potential is higher (ranging from −0.85544 V to −0.40243 V). Therefore, the rusted samples are more corrosion resistant. The Cu in the oxide layer of the surface layer forms CuO and CuFeO2, which are helpful for increasing corrosion resistance, which inhibits the penetration of Cl. Full article
(This article belongs to the Special Issue Advances in Corrosion and Protection of Metallic Materials)
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20 pages, 2497 KiB  
Article
Sustainable Solar Desalination: Experimental Predictive Control with Integrated LCA and Techno-Economic Evaluation
by Mishal Alsehli
Processes 2025, 13(8), 2364; https://doi.org/10.3390/pr13082364 - 25 Jul 2025
Viewed by 302
Abstract
This study experimentally validates a solar-thermal desalination system equipped with predictive feedwater control guided by real-time solar forecasting. Unlike conventional systems that react to temperature changes, the proposed approach proactively adjusts feedwater flow in anticipation of solar variability. To assess environmental and financial [...] Read more.
This study experimentally validates a solar-thermal desalination system equipped with predictive feedwater control guided by real-time solar forecasting. Unlike conventional systems that react to temperature changes, the proposed approach proactively adjusts feedwater flow in anticipation of solar variability. To assess environmental and financial sustainability, the study integrates this control logic with a full Life Cycle Assessment (LCA) and Techno-Economic Analysis (TEA). Field testing in a high-temperature, arid region demonstrated strong performance, achieving a Global Warming Potential (GWP) of 1.80 kg CO2-eq/m3 and a Levelized Cost of Water (LCOW) of $0.88/m3. Environmental impacts were quantified using OpenLCA and ecoinvent datasets, covering climate change, acidification, and eutrophication categories. The TEA confirmed economic feasibility, reporting a positive Net Present Value (NPV) and an Internal Rate of Return (IRR) exceeding 11.5% over a 20-year lifespan. Sensitivity analysis showed that forecast precision and TES design strongly influence both environmental and economic outcomes. The integration of intelligent control with simplified thermal storage offers a scalable, cost-effective solution for off-grid freshwater production in solar-rich regions. Full article
(This article belongs to the Section Sustainable Processes)
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